Search results for "Diss"
showing 10 items of 2500 documents
Silica-coated calcium pectinate beads for colonic drug delivery
2013
The aim of this work is to develop novel organic-inorganic hybrid beads for colonic drug delivery. For this purpose, calcium pectinate beads with theophylline are prepared by a cross-linking reaction between amidated low-methoxyl pectin and calcium ions. The beads are then covered with silica, starting from tetraethyoxysilane (TEOS), by a sol-gel process. The influence of TEOS concentration (0.25, 0.50, 0.75 and 1.00 M) during the process is studied in order to modulate the thickness of the silica layer around the pectinate beads and thus to control the drug release. The interactions between the silica coating and the organic beads are weak according to the physicochemical characterizations…
Electrochemical Behaviour and Galvanic Effects of Titanium Implants Coupled to Metallic Suprastructures in Artificial Saliva
2018
The aim of the present study is to analyze the electrochemical behavior of five different dental alloys: two cobalt-chromium alloys (CoCr and CoCr-c), one nickel-chromium-titanium alloy (NiCrTi), one gold-palladium alloy (Au), and one titanium alloy (Ti6Al4V), and the galvanic effect when they are coupled to titanium implants (TiG2). It was carried out by electrochemical techniques (open circuit measurements, potentiodynamic curves and Zero-Resistance Ammetry) in artificial saliva (AS), with and without fluorides in different acidic conditions. The studied alloys are spontaneously passivated, but NiCrTi alloy has a very narrow passive domain and losses its passivity in presence of fluorides…
Energy of dendritic avalanches in thin-film superconductors
2018
A method for calculating stored magnetic energy in a thin superconducting film based on quantitative magneto-optical imaging is developed. Energy and magnetic moment are determined with these calculations for full hysteresis loops in a thin film of the superconductor NbN. Huge losses in energy are observed when dendritic avalanches occur. Magnetic energy, magnetic moment, sheet current and magnetic flux distributions, all extracted from the same calibrated magneto-optical images, are analyzed and discussed. Dissipated energy and the loss in moment when dendritic avalanches occur are related to each other. Calculating these losses for specific spatially-resolved flux avalanches is a great ad…
Microwave photoassisted dissipation and supercurrent of a phase-biased graphene-superconductor ring
2021
Irradiating normal-superconducting junctions with microwave photons produce spectacular effects, such as Shapiro steps and photoinduced modifications of the dc supercurrent. Moreover, microwave irradiation can also have other, hitherto unexplored consequences, such as a photoassisted dissipation which is phase dependent. Here we present a finite-frequency measurement of both the dissipation and the supercurrent of a phase-biased graphene-superconductor junction in response to microwave photons. We find that, while the supercurrent response is well described by existing theory, the dissipation exhibits unexpected effects which need new theoretical elucidation. Especially with high frequency …
A Simple Model for Ac Impedance Spectra in Bipolar Membranes
1996
A new model accounting for the ac impedance spectra of synthetic ion-exchange bipolar membranes is presented. The theoretical approach is based on the Nernst−Planck and Poisson equations and applies some of the concepts used in the semiconductor pn junctions to the case of a bipolar membrane. The results presented are the current−voltage curves and the impedance spectra at electric currents above the limiting current. It is shown that the model is able to identify the main contributions to the bipolar membrane impedance and gives valuable information about the bipolar junction structure and its influence on the characteristic parameters involved in the field-enhanced water dissociation phen…
Distributed Resource Allocation in Underlay Multicast D2D Communications
2021
Multicast device-to-device communications operating underlay with cellular networks is a spectral efficient technique for disseminating data to nearby receivers. However, due to the critical challenge of having an intelligent interference coordination between multicast groups along with the cellular network, it is necessary to judiciously perform resource allocation for the combined network. In this work, we present a framework for a joint channel and power allocation strategy to maximize the sum rate of the combined network while guaranteeing minimum rate to individual groups and cellular users. The objective function is augmented by an austerity function that penalizes excessive assignmen…
Reliable Multicast D2D Communication Over Multiple Channels in Underlay Cellular Networks
2020
Multicast device-to-device (D2D) communications operating underlay with cellular networks is a spectral efficient technique for disseminating data to the nearby receivers. However, due to critical challenges such as, mitigating mutual interference and unavailability of perfect channel state information (CSI), the resource allocation to multicast groups needs significant attention. In this work, we present a framework for joint channel assignment and power allocation strategy to maximize the sum rate of the combined network. The proposed framework allows access of multiple channels to the multicast groups, thus improving the achievable rate of the individual groups. Furthermore, fairness in …
Numerical study of shock formation in the dispersionless Kadomtsev-Petviashvili equation and dispersive regularizations
2013
The formation of singularities in solutions to the dispersionless Kadomtsev-Petviashvili (dKP) equation is studied numerically for different classes of initial data. The asymptotic behavior of the Fourier coefficients is used to quantitatively identify the critical time and location and the type of the singularity. The approach is first tested in detail in 1+1 dimensions for the known case of the Hopf equation, where it is shown that the break-up of the solution can be identified with prescribed accuracy. For dissipative regularizations of this shock formation as the Burgers' equation and for dispersive regularizations as the Korteweg-de Vries equation, the Fourier coefficients indicate as …
A thermodynamics-based formulation of gradient-dependent plasticity
1998
Abstract A nonlocal thermodynamic theoretical framework is provided as a basis for a consistent formulation of gradient-dependent plasticity in which a scalar internal variable measuring the material isotropic hardening/softening state is the only nonlocal variable. The main concepts of this formulation are: i) the ‘regularization operator’, of differential nature, which governs the relation between the above nonlocal variable and a related local variable (scalar measure of plastic strain) and confers a unified character to the proposed formulation (this transforms into a formulation for nonlocal plasticity if the regularization operator has an integral nature); ii) the ‘nonlocality residua…
A unified residual-based thermodynamic framework for strain gradient theories of plasticity
2011
Abstract A unified thermodynamic framework for gradient plasticity theories in small deformations is provided, which is able to accommodate (almost) all existing strain gradient plasticity theories. The concept of energy residual (the long range power density transferred to the generic particle from the surrounding material and locally spent to sustain some extra plastic power) plays a crucial role. An energy balance principle for the extra plastic power leads to a representation formula of the energy residual in terms of a long range stress, typically of the third order, a macroscopic counterpart of the micro-forces acting on the GNDs (Geometrically Necessary Dislocations). The insulation …