Search results for "Diss"
showing 10 items of 2500 documents
Ionic Liquids: Media for Better Molecular Catalysis
2004
Ionic liquids (ILs) are more and more suggested as substitutes for traditional solvents in organic synthesis and catalysis. They are suitable candidates for the dissolution of ionic complexes. They can activate and retain them in a polar state: in fact, they act as sequestrands, opening the route to two-phase processes and easier catalyst recovery. This paper reviews authors' results with the development of new syntheses of ILs and applications in carbon–carbon bond formation (dimerisation of methyl acrylate) and redistribution (ring closing metathesis) reactions using ionic precatalysts.
Mass Spectrometric Investigation of Noncovalent Complexation between a Tetratosylated Resorcarene and Alkyl Ammonium Ions
2004
Noncovalent complexation between tetratosylated tetraethyl resorcarene (1) and primary, secondary, and tertiary alkyl ammonium ions (mMe, dMe, tMe, mEt, dEt, tEt, dBu, and dHex) was studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Interactions of the noncovalent complexes were investigated by means of competition experiments, collision-induced dissociation (CID) experiments, ion-molecule reactions with tripropylamine and gas phase H/D-exchange reactions with deuteroammonia. Gas phase ion-molecule reactions gave especially valuable information about the structure and properties of the complexes. Resorcarene 1 formed relatively stable…
Dissolution‐corrosion measurements with limestone and gypsum tablets in active sulphuric acid caves of southern Italy
2022
Dissolution‐corrosion (DC) represents an important factor for speleogenesis, and can be measured monitoring weight variation over time of carbonate and gypsum tablets exposed in underground environments. The oxidation of H2S produces H2SO4, which in carbonate host rock induces the surface of carbonate tablets to be rapidly corroded by sulphuric acid, whereby CaCO3 is replaced by CaSO4∙2H2O, producing a significant weight gain. We describe preliminary results of DC monitoring in four still‐active SAS systems, including Ninfe Cave and Terme Sibarite (Calabria), Fetida Cave (Apulia), and Acqua Fitusa Spring Cave (Sicily). The tablets have been set inside the caves, in three different condition…
On relation between J-integral and heat energy dissipation at the crack tip in stainless steel specimens
2019
In this paper, an experimental procedure to evaluate the elastic-plastic J-integral at the tip of a fatigue crack is presented. According to this new approach, the elastic component of the J-integral is derived from Thermoelastic Stress Analysis, while the plastic component of the J-integral is derived from the heat energy loss. An analytical link is proposed to apply this new experimental technique. Therefore, the elastic-plastic J-integral range was evaluated starting from infrared temperature maps measured in situ during crack propagation tests of AISI 304L stainless steel specimens. It was found that the range of the infrared thermography-based J-integral correlated well the crack growt…
Nonlinear relaxation phenomena in metastable condensed matter systems
2016
Nonlinear relaxation phenomena in three different systems of condensed matter are investigated. (i) First, the phase dynamics in Josephson junctions is analyzed. Specifically, a superconductor-graphene-superconductor (SGS) system exhibits quantum metastable states, and the average escape time from these metastable states in the presence of Gaussian and correlated fluctuations is calculated, accounting for variations in the the noise source intensity and the bias frequency. Moreover, the transient dynamics of a long-overlap Josephson junction (JJ) subject to thermal fluctuations and non-Gaussian noise sources is investigated. Noise induced phenomena are observed, such as the noise enhanced s…
Stylistic analysis of headlines in science journalism: A case study ofNew Scientist
2016
This article explores science journalism in the context of the media competition for readers’ attention. It offers a qualitative stylistic perspective on how popular journalism colonizes science communication. It examines a sample of 400 headlines collected over the period of 15 months from the ranking of five ‘most-read’ articles on the website of the international magazine New Scientist. Dominant lexical properties of the sample are first identified through frequency and keyness survey and then analysed qualitatively from the perspective of the stylistic projection of newsworthiness. The analysis illustrates various degrees of stylistic ‘hybridity’ in online popularization of scientific r…
Keratinocytes Determine Th1 Immunity during Early Experimental Leishmaniasis
2010
Experimental leishmaniasis is an excellent model system for analyzing Th1/Th2 differentiation. Resistance to Leishmania (L.) major depends on the development of a L. major specific Th1 response, while Th2 differentiation results in susceptibility. There is growing evidence that the microenvironment of the early affected tissue delivers the initial triggers for Th-cell differentiation. To analyze this we studied differential gene expression in infected skin of resistant and susceptible mice 16h after parasite inoculation. Employing microarray technology, bioinformatics, laser-microdissection and in-situ-hybridization we found that the epidermis was the major source of immunomodulatory mediat…
Influence of cryogenic grinding on properties of a self-emulsifying formulation
2003
Abstract Recently, self-emulsifying drug delivery systems (SEDDS) have been developed as a method to deliver lipophilic drugs. Gelucire® 44/14 is an excipient, from the lauroyl macrogolglycerides family, producing a fine oil-in-water emulsion when introduced into an aqueous phase under gentle agitation as SEDDS, improving thereby solubility of poorly water-soluble drugs and their bioavailability. The aims of this study were to process Gelucire® 44/14 into a powder by cryogenic grinding to produce solid oral dosage forms and to investigate influence of this process on different properties of a formulation made of Gelucire® 44/14 and ketoprofen (90/10). Cryogenic grinding produced Gelucire® 4…
Disseminating scientific research: a double-edged sword?
2017
Practitioners rarely have the time or propensity to read scientific research, and scholarly researchers seldom write for non-academic audiences. Nevertheless, both groups would probably agree that researchers could solve many problems faced by practitioners and that research is important to guide practice. This article acknowledges scientists’ failure to communicate successfully with practitioners, and discusses the main differences between academic and practitioner-oriented journals in management and business related disciplines. Author guidelines of the most prominent journals that appeal to both academics and practitioners are reviewed and discussed. A thorough literature review is also …
Barriers to exchanging healthcare information in inter-municipal healthcare services: a qualitative case study
2018
Abstract Background In recent years, inter-municipal cooperation in healthcare services has been an important measure implemented to meet future demographic changes in western countries. This entails an increased focus on communication and information sharing across organisational borders. Technology enables efficient and effective solutions to enhance such cooperation. However, the systems in the healthcare sector tend not to communicate with one another. There is a lack of literature focusing on communication and information sharing in inter-municipal healthcare services. The aim of this article is to investigate both the characteristics of communication and information sharing, and the f…