Search results for "Dye"
showing 10 items of 577 documents
Roughness effect on the correction factor of surface velocity for rill flows
2021
Flow velocity is one of the most important hydrodynamic variables for both channelized (rill and gullies) and interrill erosive phenomena. The dye tracer technique to measure surface flow velocity Vs is based on the measurement of the travel time of a tracer needed to cover a known distance. The measured Vs must be corrected to obtain the mean flow velocity V using a factor αv = V/Vs which is generally empirically deduced. The Vs measurement can be influenced by the method applied to time the travel of the dye-tracer and αv can vary in different flow conditions. Experiments were performed by a fixed bed small flume simulating a rill channel for two roughness conditions (sieved soil, gravel)…
Expanding the chemical scope of RNA:methyltransferases to site-specific alkynylation of RNA for click labeling.
2010
This work identifies the combination of enzymatic transfer and click labeling as an efficient method for the site-specific tagging of RNA molecules for biophysical studies. A double-activated analog of the ubiquitous co-substrate S-adenosyl-l-methionine was employed to enzymatically transfer a five carbon chain containing a terminal alkynyl moiety onto RNA. The tRNA:methyltransferase Trm1 transferred the extended alkynyl moiety to its natural target, the N2 of guanosine 26 in tRNA(Phe). LC/MS and LC/MS/MS techniques were used to detect and characterize the modified nucleoside as well as its cycloaddition product with a fluorescent azide. The latter resulted from a labeling reaction via Cu(I…
ChemInform Abstract: A Highly Active System for the Metal-Free Aerobic Photocyanation of Tertiary Amines with Visible Light: Application to the Synth…
2016
A highly efficient metal-free catalytic system for the aerobic photocyanation of tertiary amines with visible light is reported. The use of air as terminal oxidant offers an improved safety profile compared with pure oxygen, the used compact fluorescent lamp (CFL) light sources are highly economical, and no halogenated solvents are required. This system not only proves to be effective for a wide variety of trialkylamines, pharmaceuticals, and alkaloids but remarkably also allows the lowest catalyst loading (0.00001 mol% or 0.1 ppm) ever reported for an organic dye. Bruylants reactions and C-alkylation/decyanations were performed on the obtained α-aminonitriles to demonstrate the postfunctio…
A synthetic biology approach for the fabrication of functional (fluorescent magnetic) bioorganic–inorganic hybrid materials in sponge primmorphs
2020
During evolution, sponges (Porifera) have honed the genetic toolbox and biosynthetic mechanisms for the fabrication of siliceous skeletal components (spicules). Spicules carry a protein scaffold embedded within biogenic silica (biosilica) and feature an amazing range of optical, structural, and mechanical properties. Thus, it is tempting to explore the low-energy synthetic pathways of spiculogenesis for the fabrication of innovative hybrid materials. In this synthetic biology approach, the uptake of multifunctional nonbiogenic nanoparticles (fluorescent, superparamagnetic) by spicule-forming cells of bioreactor-cultivated sponge primmorphs provides access to spiculogenesis. The ingested nan…
On the interpretation of the Raman spectra of Maya Blue: a review on the literature data
2011
The Raman spectroscopy of Maya Blue (MB), a nanostructured organic–inorganic hybrid material, has received considerable attention. A re-evaluation of the Raman literature data for indigo dye, genuine MB samples and model specimens obtained by the binding of indigo to phyllosilicate clays, such as palygorskite and sepiolite, using chemometric analysis of normalised spectra is reported. Available data present features in support of the following ideas: (1) dehydroindigo accompanies indigo in MB; (2) different topological isomers, i.e. dye molecules attached to different coordinative sites of the palygorskite framework, are involved in MB; and (3) different procedures were probably used for pr…
On the variation of the correction factor of surface velocity with the measurement vertical for shallow flows over rough beds
2023
Considering that water flow energy affects the detachment of soil particles, the transport and deposit of the detached particles, the flow velocity is a key variable governing the soil erosion processes at the hillslope scale. The simple dye-tracer technique for measuring mean flow velocity can be applied in non-controlled field applications for which some measurement difficulties (e.g. due to sediment transport, and shallow flows) can occur. The correction factor is usually obtained as the ratio between the mean velocity, deriving from measurements of flow discharge and water depth, and surface velocity. Alternatively, the possibility of using the velocity profile in a given vertical to de…
NATURAL INDICO FROM ISATIS TINCTORIA L. FOR THE VALORISATION OF SICILIAN CROPS
2012
Isatis tinctoria L. or woad (Brassicaceae) is an upright herbaceous biennal species up to 120 cm in height. It is in Mediterranean counlries, a common plant cultivated through out centuries to produce the blue dye indigo. With increasing concem for sustainability and a demand from consumers for naturally sourced products, there is a revival of interest in naturai indigo as an agricultural crop produci. Indigo is formed after the extraction of indigo precursors in the leaves of these plants: mainly isatans in woad These compounds are extracted by steeping leaves in warm water. With woad, the addition of alkali to the steep water releases free indoxyl, which forms indigo after a vigorous aera…
Nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate: A metal-organic ferromagnetic dye
2012
The new metal organic compound nickel(II) 3,4;9,10-perylenediimide bis-phosphonate pentahydrate, i.e. Ni-2[(PDI-BP)-(H2O)(2)]center dot 3H(2)O (1), has been synthesized and its structural and magnetic properties have been studied. Reaction of 3,4;9,10-perylenediimide bisphosphonate (PDI-BP, hereafter) ligand and nickel chloride in water resulted in the precipitation of a red and poorly crystalline solid (1). As the solid shows a poor crystalline organization of aggregates, the energy dispersive X-ray diffraction analysis (EDXD) technique has been used to obtain short-range order structural information of the single nanoaggregates by radial distribution function analysis. The overall structu…