Search results for "Dynamic"
showing 10 items of 12329 documents
H-2 vibrational spectral signatures in binary and ternary mixtures: theoretical model, simulation and application to CARS thermometry in high pressur…
2001
International audience; A summary of the main results obtained by the two groups in the field of H-2 vibrational spectral line signatures for various mixtures. in connection with CARS diagnostics of H-2-O-2 combustion systems, is presented. H-2-X Systems may have specific large inhomogeneous spectral features, due to the dependence of the line broadening and line shifting on the (H-2) radiator speed, particularly at high temperature. Thus, careful attention has to be paid to rigorously analyze such features, both from the experimental point of view (Dijon) and from the theoretical one (Besancon). Applications of the present results to high-pressure H-2/air flame thermometry are also briefly…
Quantum dynamics of the oxygen isotopic exchange : lifetimes of metastable states of the ozone intermediate complex
2021
This thesis aims to describe the ozone dynamics during the isotopic exchange reactions of oxygen of type xO + yO zO (xO yO zO)* xO yO + zO, where x, y and z are the atomic masses of the stable oxygen isotopes (16, 17, 18). Firstly, we analyze several methods of accurate description of the atom interactions and numerical schemes to obtain the observables for the collision. Then, in a full-quantum hyperspherical formalism, we study the actual dynamics of the reactive process O + O2 -> O3* -> O2 + O. The metastable ozone created can then either decompose into oxygen by the inverse reaction, or relax into stable ozone by exchanging energy with the environment, typically N2 or O2 molecules. Thes…
Les interactiones de Casimir hors d'équilibre : effets dynamiques et thermiques
2016
In this thesis, after an introduction where we briefly present the general context of Casimir physics, we present the results obtained during the PhD. At first, we show our work about the van der Waals/Casimir-Polder interactions between two atoms in an out-of-equilibrium condition due to their uniformly accelerated motion. We study the system of two uniformly accelerated atoms in vacuum space, when they are in their ground-state and when they are in a correlated state (one excited and one ground-state atom). We analyze this system both with an heuristic semiclassical model and with a more rigorous method, based on a separation of radiation reaction and vacuum fluctuations contributions, th…
The 2014 Magnetism Roadmap
2014
Magnetism is a very fascinating and dynamic field. Especially in the last 30 years it has experienced many major advances in the full range from novel fundamental phenomena to new products. Applications such as hard disk drives and magnetic sensors are part of our daily life, and new applications, such as in non-volatile computer random access memory, are expected to surface shortly. Thus it is timely for describing the current status, and current and future challenges in the form of a Roadmap article. This 2014 Magnetism Roadmap provides a view on several selected, currently very active innovative developments. It consists of 12 sections, each written by an expert in the field and addressi…
Low-cost viscometer based on energy dissipation in viscous liquids
2001
We describe a new type of low-cost easy-to-use viscometer based on the temperature elevation in a liquid under shear flow. After calibration, this instrument can be used to measure the apparent steady state viscosity for both Newtonian and non-Newtonian liquids with no yield stress. We compute the rise in temperature due to viscous dissipation in a Couette cell and compare it to experimental results for different fluids. We show that the variation of the temperature with shear rate can be used to characterize the rheological behaviour of viscous fluids and to evaluate their viscosity in a large domain, from typically a few cP up to more than 10 P, with an accuracy of about ±5%. In contrast …
Charge-transfer driven by ultrafast spin-transition in a CoFe Prussian blue analogue
2020
Photoinduced charge-transfer is an important process in nature and technology and is responsible for the emergence of exotic functionalities, such as magnetic order for cyanide-bridged bimetallic coordination networks. Despite its broad interest and intensive developments in chemistry and material sciences, the atomic-scale description of the initial photoinduced process, which couples intermetallic charge-transfer and spin transition, has been debated for decades; it has been beyond reach due to its extreme speed. Here we study this process in a prototype cyanide-bridged CoFe system by femtosecond X-ray and optical absorption spectroscopies, enabling the disentanglement of ultrafast electr…
THERMODYNAMIC ANALYSIS OF HIGH-PRESSURE SONOREACTOR IMPACT OF CHOSEN TECHNICS IN EFFICIENCY AND HEAT RELEASE PROBLEM
2016
International audience
Optimal Robust Quantum Control by Inverse Geometric Optimization
2020
International audience; We develop an inverse geometric optimization technique that allows the derivation of optimal and robust exact solutions of low-dimension quantum control problems driven by external fields: we determine in the dynamical variable space optimal trajectories constrained to robust solutions by Euler-Lagrange optimization; the control fields are then derived from the obtained robust geodesics and the inverted dynamical equations. We apply this method, referred to as robust inverse optimization (RIO), to design optimal control fields producing a complete or half population transfer and a NOT quantum gate robust with respect to the pulse inhomogeneities. The method is versat…
Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks
2021
<p>Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd<sup>3+</sup>-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.</p>
Weeds sampling for map reconstruction: a Markov random field approach
2012
In the past 15 years, there has been a growing interest for the study of the spatial repartition of weeds in crops, mainly because this is a prerequisite to herbicides use reduction. There has been a large variety of statistical methods developped for this problem ([5], [7], [10]). However, one common point of all of these methods is that they are based on in situ collection of data about weeds spatial repartition. A crucial problem is then to choose where, in the eld, data should be collected. Since exhaustive sampling of a eld is too costly, a lot of attention has been paid to the development of spatial sampling methods ([12], [4], [6] [9]). Classical spatial stochastic model of weeds cou…