Search results for "EES"
showing 10 items of 2276 documents
Intelligent solutions for real-life data-driven applications
2017
The subject of this thesis belongs to the topic of machine learning or, specifically, to the development of advanced methods for regression analysis, clustering, and anomaly detection. Industry is constantly seeking improved production practices and minimized production time and costs. In connection to this, several industrial case studies are presented in which mathematical models for predicting paper quality were proposed. The most important variables for the prediction models are selected based on information-theoretic measures and regression trees approach. The rest of the original papers are devoted to unsupervised machine learning. The main focus is developing advanced spectral cluster…
Pd2Au36(SR)(24) cluster: structure studies
2015
The location of the Pd atoms in Pd2Au36(SC2H4Ph)(24), is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.
Behind the scenes of artificial intelligence: a study of micro-work platforms in France
2019
Este artículo es una versión resumida del informe “Le Micro-travail en France. Derrière l’automatisation de nouvelles précarités au travail?» This article is a summarized version of the report "Le Micro-travail en France. Derrière l’automatisation de nouvelles précarités au travail?" .; International audience; Micro-work internet services allocate small, standardized tasks of data generation and annotation to crowds of providers. The outputs are mainly used to produce artificial intelligence solutions. It is an exemplary instance of the “platformization” of the economy, and of the transformations of labour that digital technologies bring about. To uncover the conditions under which micro-wo…
Phenomenology of low-scale Seesaw Models
2016
All the observed particles are well accommodated in the Standard Model, together with the basic forces. However, there are both experimental and theoretical hints that the Standard Model can not be a complete theory and that New Physics is needed. Some of the theoretical problems are: i) The flavor-puzzle, i.e., why are there three copies of particles differing only by their mass. Most of the free parameters in the Standard Model are linked to this puzzle. They have been measured, but their values do not follow any clear pattern and their origin remains elusive. ii) The strong CP problem, that is, why the CP symmetry is conserved in the strong interactions in the Standard Model, which is no…
Praktyki zawodowe w kształceniu nauczycieli
2018
Contemporary conceptions of educating teachers underline the vital role and significance of professional traineeship. Education of teachersis directed not only at eąuipping prospective teachers with general and specialist knowledge, but also at developing competences which are indispensable for everyday didactic-rearing work. Therefore professional traineeship is an important element of educating teachers.
From’Innov: a new technology to obtain aroma in solubilized soft-cheese
2023
The dairy platform of the STLO, Rennes, developed an innovative technology and more sustainable cheese making process (INRAE patent, From’Innov, WO2016108024). This technology consists of mixing a texture matrix obtained by ultrafiltration with one or more aromatic matrix. The latter is innovative: it allows obtaining a maximum of aroma in a short time, less than a few days. The principle is to grow each of microorganisms in an optimized middle with essential nutrients, optimal pH and temperature, and O2 if necessary. After adjusting the pH and temperature of the mix, we proceed with the coagulation then the molding, and the next day the demolding. The cheese is ready and contains the expec…
Czy gęsi są głupie? O ptasiej filozofii Mikołaja Reja słów kilka
2017
The article is an attempt to solve the enigma on the potential advantages of the Polish language that comes from the line to the person who will read from Zwierzyniec Mikołaj Rej. The author reviews the most famous and popular meanings of the symbols geese from antiquity to the Renaissance times. Indicated is a long road traveled by this positively associated theme until symbol geese has become synonymous mindless chatter. The opposite of the “idle talk” is the work of Miko³aj Rej, who was the father of Polish literature, hoisted our national culture to new heights.
Thiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions
2017
The new compounds (5-methyl-2-thiophene-2-pyridyl(R))imine [R = methyl (L1); R = ethyl (L2)] and (5-bromo-2-thiophene-2-pyridyl(R)imine [R = methyl (L3); R = ethyl (L4)] were successfully synthesized via Schiff base condensation reaction and obtained in good yields. These potential ligands were reacted with [PdCl2(COD)] and [PdClMe(COD)] to give the corresponding complexes [PdCl2(L)] (L = L1-L4; 1–4) and [PdClMe(L)] (L = L1-L4; 5–8). All compounds were characterized by IR, 1H and 13C NMR spectroscopy, elemental analysis and mass spectrometry. The molecular structures of 1, 2, 6 and 8 were confirmed by X-ray crystallography. The complexes were evaluated as catalyst precursors for standard He…
Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement
2017
The condensation reaction of 2-aminobenzenethiols and 3-aminopyrazinethiols with 2-amino-6-fluoro-N-methylpyridinium triflate afforded thioether derivatives that were found to undergo Smiles rearrangement and cyclocondensation with sulphur monochloride to yield new hybrid 1,4-thiazine-1,2,3-dithiazolylium cations. The synthesized cations were readily reduced to the corresponding stable neutral radicals with spin densities delocalized over both 1,4-thiazinyl and 1,2,3-dithiazolyl moieties. peerReviewed
Towards Controlled Synthesis of Water-Soluble Gold Nanoclusters : Synthesis and Analysis
2019
Water-soluble gold nanoclusters with well-defined molecular structures and stability possess particular biophysical properties making them excellent candidates for biological applications as well as for fundamental spectroscopic studies. The currently existing synthetic protocols for atomically monodisperse thiolate-protected gold nanoclusters (AuMPCs) have been widely expanded with organothiolates, yet the direct synthesis reports for water-soluble AuMPCs are still deficient. Here, we demonstrate a wet-chemistry pH-controlled synthesis of two large water-soluble nanoclusters utilizing p-mercaptobenzoic acid (pMBA), affording different sizes of plasmonic AuMPCs on the preparative scale (∼7 …