Search results for "ELECTRONICS"
showing 10 items of 4340 documents
A simple method for measuring OLEDs efficiency
2015
External quantum efficiency (EQE) of organic light emitting diodes (OLEDs) is among the most important parameters for devices assessment and for comparing OLEDs performance. The EQE is the ratio of the total number of photons emitted by the OLED in all directions to the number of electrons injected.
DC lifetime of encapsulated organic light emitting diodes
2016
Organic light emitting diodes (OLEDs) are ideal sources for chemical and biological optical sensors, due to their simplicity, low cost (disposable applications) and possibility to be integrated on chip and fabricated in the form of large 2D arrays (microarray fluorescence) even on flexible plastic substrates. OLEDs with lifetimes of a few hundreds of hours at initial luminance values in the range (500÷1000) cd/m 2 are suitable for the above applications, but these lifetimes can be achieved only by a proper encapsulation. Fast, simple and inexpensive encapsulation methods are highly desirable to keep the low cost profile and for this reasonwe report two different encapsulation structures and…
Anodized Ti-Si Alloy as Gate Oxide of Electrochemically-Fabricated Organic Field-Effect Transistors
2013
Organic field-effect transistors were fabricated using an electrochemical route. The dielectric oxide was grown by anodization of a Ti:Si alloy, while 3,4-polyethylenedioxythiophene has been employed as a semiconducting polymer. OutputI-Vcharacteristics showed a transistor effect dependent on dielectric thickness. Fitting between I-V measurements and theoretical simulations in the triode region confirmed the presence of a conduction path through the polymer which degrades the electrical characteristics of the devices.
Rational computing of energy levels for organic electronics: the case of 2-benzylidene-1,3-indandiones
2016
Device engineering in organic electronics, an active area of research, requires knowledge of the energy levels of organic materials (traditionally but ambiguously denoted as HOMO and LUMO). These can be effectively determined by electrochemical investigation, but yet more effective would be quantum chemical (QC) computation of these quantities. However, there is no consensus on the computational method in the research community. Ongoing discussions often focus on choosing the right density functional method, but neglect other model parameters, in particular, the basis set. This study considers comparison of various methodologies and parameters for predicting ionization energy I and electron…
(o-Phenyleno)naphthalene diimides: a pink fluorescent chromophore
2017
(o-Phenyleno)naphthalene dianhydride 7 was synthesized by a six-step reaction. Imidizations of 7 led to various diimides 8. Their optical and electrochemical properties hold promise for organic electronics.
Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines
2012
In this paper, we studied the effect of humidity on the response of cobalt phthalocyanine-containing resistors to ammonia, in the ppm range. We pointed out the fact that, when alternating exposure periods with recovery periods, the humidity effect had to be carefully studied, in correlation with the flow variation. Thus, for a sulfonated cobalt phthalocyanine, the effect of NH(3) was totally screened as soon as the relative humidity (RH) was above 10%. On the contrary, when using unsubstituted cobalt phthalocyanine (CoPc) as sensing material, the sensors' response to NH(3) appears to be quite stable in a wide RH range, allowing a discrimination between 12, 25 and 50 ppm of NH(3) over the 10…
Liquid Crystalline Ordering and Charge Transport in Semiconducting Materials
2009
Organic semiconducting materials offer the advantage of solution processability into flexible films. In most cases, their drawback is based on their low charge carrier mobility, which is directly related to the packing of the molecules both on local (amorphous versus crystalline) and on macroscopic (grain boundaries) length scales. Liquid crystalline ordering offers the possibility of circumventing this problem. An advanced concept comprises: i) the application of materials with different liquid crystalline phases, ii) the orientation of a low viscosity high temperature phase, and, iii) the transfer of the macroscopic orientation during cooling to a highly ordered (at best, crystalline-like…
Dicopper(II) Metallacyclophanes with Electroswitchable Polymethyl-Substitutedpara-Phenylene Spacers
2013
Double-stranded anionic dinuclear copper(II) metallacyclic complexes of the paracyclophane type [Cu2L2]4- have been prepared by the CuII-mediated self-assembly of different para-phenylenebis(oxamato) bridging ligands with either zero-, one-, or four-electron-donating methyl substituents (L=N,N′-para- phenylenebis(oxamate) (ppba; 1), 2-methyl- N,N′-para-phenylenebis(oxamate) (Meppba; 2), and 2,3,5,6-tetramethyl- N,N′-para-phenylenebis(oxamate) (Me4ppba; 3)). These complexes have been isolated as their tetra-n-butylammonium (1 a-3 a), lithium(I) (1 b-3 b), and tetraphenylphosphonium salts (1 c-3 c). The X-ray crystal structures of 1 a and 3 c show a parallel-displaced π-stacked conformation w…
Humidity Insensitive Conductometric Sensors for Ammonia Sensing
2014
Interest in molecular materials has been driven in large part by their various and prosperous applications, especially in the domain of organic electronics, where they offer many advantages as well as alternative approaches compared to their inorganic counterparts. Most of conductometric transducers are resistors[[ and transistors[[[, but rarely diodes[6]. In our laboratory, we designed and characterized new molecular material based devices. Molecular Semiconductor Doped Insulator (MSDI) heterojunctions were built around a heterojunction between a Molecular Semiconductor (MS) and a Doped Insulator (DI)[7][8]. This new device exhibits interesting electronic properties that allow ammonia sens…
Electrochemical fabrication of metal/oxide/conducting polymer junction
2011
After discovery of conducting polymers and the possibility to modify their electrical properties from insulating to metallic like behavior by doping and a careful choice of the processing conditions, a large amount of research effort has been devoted to the theoretical understanding of their solid state properties as well as to exploit the possible application of conducting polymers in many technological fields including large area organic electronics, polymer photovoltaic cell, and sensors. 1-4 Organic thin film transistors appear very promising devices for the development of low cost, flexible, and disposable plastic electronics. In order to reduce the operating voltage it has been sugges…