Search results for "ELEMENT"
showing 10 items of 13601 documents
Tuning the electronic and magnetic properties of 2D g-GaN by H adsorption: An ab-initio study
2019
Abstract We have theoretically studied the structural, electronic and magnetic properties of the hydrogen adsorption on a honeycomb gallium-nitride two-dimensional monolayer (2D g-GaN). Results indicate that the band gap energy can be systematically tuned by the hydrogen coverage on the 2D g-GaN in the diluted limit. In addition, a total magnetic moment can be induced in the 2D g-GaN by hydrogen adsorption due to s-p interaction and band structure effects. Although hydrogen adsorption on top of nitrogen atoms shows the most stable energy in the 2D g-GaN, the most stable ferromagnetism -with a nonzero magnetic moment-is obtained when hydrogen is adsorbed on top of Ga atoms. These results ind…
Zn-substituted iron oxide nanoparticles from thermal decomposition and their thermally treated derivatives for magnetic solid-phase extraction
2020
Abstract Controlled thermal decomposition of zinc and iron acetylacetonates in the presence of oleic acid and oleylamine provided surfactant-capped magnetic nanoparticles with narrow size distribution and the mean diameter of ≈15 nm. The combined study by XRD, XRF and Mossbauer spectroscopy revealed three important features of the as-prepared nanoparticles. First, the actual ratio of Zn:Fe was considerably lower in the product compared to the initial ratio of metal precursors (0.14 vs. 0.50). Second, a pure stoichiometric Zn-doped magnetite system, specifically of the composition Zn0.37Fe2.63O4, with no signatures of oxidation to maghemite was formed. Third, Zn2+ ions were distributed at bo…
A new 18 GHz room temperature electron cyclotron resonance ion source for highly charged ion beams
2020
An innovative 18 GHz HIISI (Heavy Ion Ion Source Injector) room temperature Electron Cyclotron Resonance (ECR) ion source (ECRIS) has been designed and constructed at the Department of Physics, University of Jyväskylä (JYFL), for the nuclear physics program of the JYFL Accelerator Laboratory. The primary objective of HIISI is to increase the intensities of medium charge states (M/Q ≅ 5) by a factor of 10 in comparison with the JYFL 14 GHz ECRIS and to increase the maximum usable xenon charge state from 35+ to 44+ to serve the space electronics irradiation testing program. HIISI is equipped with a refrigerated permanent magnet hexapole and a noncylindrical plasma chamber to achieve very stro…
Evaluation of Vertical Fatigue Cracks by Means of Flying Laser Thermography
2019
The present paper proposes a new procedure to analyze the temperature field distribution during Flying Laser Spot and Laser Line Thermographic scanning (FLST, FLLT) of metallic components, in order to detect vertical surface cracks. The methodology exploits the changes in the temperature field produced by a vertical crack, acting as a barrier towards heat diffusion, when the laser approaches the defect. A number of small regions of interests (ROIs) is placed nearby and around the laser source. The average temperature from each ROI is then monitored during the laser scanning. Vertical cracks can be detected by analyzing and comparing the temperature fluctuations from each ROI when the laser …
Tandem laser-gas metal arc welding joining of 20 mm thick super duplex stainless steel: An experimental and numerical study
2020
The present work covers the topic of strains and stresses prediction in case of welded steel structures. Steel sheets of 20 mm thickness made in UR™2507Cu are welded using a laser and gas metal arc welding processes combination. The focused laser beam leads the arc in a Y-shape chamfer geometry. Both sources are 20 mm apart from each other in order to avoid any synergic effect with each other. In order to predict residual strain, a 3D unsteady numerical simulation has been developed in COMSOL finite element software. A volume heat source has been identified based on the temperature measurements made by 10 K-type thermocouples, implanted inside the workpiece. The 50 mm deep holes are drille…
A Computational Study on Crack Propagation in Bio-Inspired Lattices
2018
A computational preliminary study on the fracture behaviour of two kinds of finite-size bio-inspired lattice configurations is presented. The study draws inspiration from recent investigations aimed at increasing the fracture energy of some materials through small modifications of their microstructure. Nature provides several examples of strategies used to delay or arrest damage initiation and crack propagation. Striking examples are provided by the micro-architecture of several kinds of wood. In this study, the effects on crack propagations induced by architectural alterations inspired by the microstructure of wood are computationally investigated. In an age in which tight control of the m…
Vapor plume and melted zone behavior during dissimilar laser welding of titanium to aluminum alloy
2020
The present study deals with continuous Yb:YAG laser welding of pure titanium to aluminum alloy A5754 performed with different beam offsets to the joint line. Spectroscopic and morphological characterization of vapor plume exiting the keyhole was combined with post-mortem observation and energy-dispersive X-ray spectroscopy (EDX) analysis of the welds. The laser beam centered on the joint line resulted in periodic transversal inclination of a vapor jet on the aluminum side associated with a local increase of melt width and an intense spatter formation. Such behavior can be attributed to the instability of the keyhole wall from the aluminum side. The beam offset on the titanium side led to …
Growth of WC–Cr–N and WC–Al–N coatings in a RF-magnetron sputtering process
2013
Tungsten carbide-based coatings have been used in a wide variety of industrial applications such as high speed cutting tools, extrusion dies, drills, aerospace industries, and more. A few reports on ternary and quaternary coatings of WC with other elements indicate good prospects for these material systems. The present study focuses on the formation of quaternary WCeCreN and WCeAleN coatings during the simultaneous reactive RF-magnetron sputtering of tungsten carbide and Al or Cr targets in an argon/nitrogen gas mixture. The resulting coatings, with thicknesses of 3.5 mme8.2 mm, were characterized by using several analytical techniques including X-ray diffraction, SEM/EDS, AFM, and X-ray ph…
Impact of rolling conditions on the hydriding of grade 2 titanium welded tubes
2020
In this article, we study the impact of rolling conditions on the texture of the commercially pure titanium grade 2. In a previous work, NEOTISS in collaboration with ICB laboratory, shown that the texture highly influences the precipitation of hydrides in Titanium. In order to create different textures, Titanium sheets grade 2 are cold rolled asymmetrically and symmetrically with or without lubricant. The inverse pole figures and direct pole figures obtained allow us to deduce that symmetrical cold rolling does not change the grains orientation but generates a rotation of grains along c-axis (normal to basal plan). However, asymmetrical cold rolling leads to the formation of a new crystall…
Mechanical characterisation of pentagonal gold nanowires in three different test configurations: A comparative study.
2019
Abstract Mechanical characterisation of individual nanostructures is a challenging task and can greatly benefit from the utilisation of several alternative approaches to increase the reliability of results. In the present work, we have measured and compared the elastic modulus of five-fold twinned gold nanowires (NWs) with atomic force microscopy (AFM) indentation in three different test configurations: three-point bending with fixed ends, three-point bending with free ends and cantilevered-beam bending. The free-ends condition was realized by introducing a novel approach where the NW is placed diagonally inside an inverted pyramid chemically etched in a silicon wafer. In addition, all thre…