Search results for "ENERGY RELAXATION"
showing 7 items of 17 documents
Relaxation processes of point defects in vitreous silica from femtosecond to nanoseconds
2008
We studied ultrafast relaxation of localized excited states at Ge-related oxygen deficient centers in silica using femtosecond transient-absorption spectroscopy. The relaxation dynamics exhibits a biexponential decay, which we ascribe to the departure from the Frank-Condon region of the first excited singlet state in 240 fs, followed by cooling in ∼10 ps. At later times, a nonexponential relaxation spanning up to 40 ns occurs, which is fitted with an inhomogeneous distribution of nonradiative relaxation rates, following a chi-square distribution with one degree of freedom. This reveals several analogies with phenomena such as neutron reactions, quantum dot blinking, or intramolecular vibrat…
SPECTROSCOPY AND NON-EQUILIBRIUM DISTRIBUTION OF VIBRATIONALLY EXCITED METHANE IN A SUPERSONIC JET
1998
Abstract High-resolution spectra of supersonic jets of vibrationally excited methane have been recorded by diode laser in the 8 μm region. A formalism for the description of energy distribution is proposed. It allows to estimate populations of vibrational polyads. Under these non-equilibrium conditions, translational temperature is also measured from line profiles. For relaxation, it is shown that vibrational relaxation between polyads is negligible whereas strong redistribution of population arises inside each polyad. Spectroscopically, observed lines involving the first four excited polyads allows cross-checked tests for energy level analysis.
Vibrational and rotational collisional relaxation in CO2–Ar and CO2–He mixtures studied by stimulated Raman-infrared double resonance
1999
0021-9606; The collisional relaxation among vibrational levels of the Fermi dyad of CO2 mixed with Ar and He (10% CO2, 90% rare gas) has been studied at room temperature with a double resonance experiment. Stimulated Raman effect from the ground state achieved the pumping process with a Nd:YAG laser and a pulse amplified dye laser. After pumping the v(1) or 2v(2)(Sigma(+)g) level, a cw CO2 laser was used to probe either the depopulation rates of the pumped levels (vibrationally or rotationally resolved) or the energy transfer rates to neighboring states. The vibrational energy relaxation has been studied from experimental depopulation of v(1) and population of 2v(2) levels through a five-le…
Electron–phonon coupling in degenerate silicon-on-insulator film probed using superconducting Schottky junctions
2002
Abstract Energy flow rate in degenerate n-type silicon-on-insulator (SOI) film is studied at low temperatures. The electrons are heated above the lattice temperature by electric field and the electron temperature is measured via semiconductor–superconductor quasiparticle tunneling. The energy flow rate in the system is found to be proportional to T 5 , indicating that electron–phonon relaxation rate and electron–phonon phase breaking rate are proportional to T 3 . The electron–phonon system in the SOI film is in the “dirty limit” where the electron mean free path is smaller than the inverse of the thermal phonon wave vector.
Vibrational relaxation of matrix-isolated carboxylic acid dimers and monomers.
2009
Femtosecond mid-IR transient absorption spectroscopy was used to probe the vibrational dynamics of formic acid and acetic acid isolated in solid argon following excitation of the fundamental transition of the carbonyl stretching mode. Carboxylic acids form extremely stable H-bonded dimers, hindering the study of the monomeric species at equilibrium conditions. The low-temperature rare-gas matrix isolation technique allows for a unique control over aggregation enabling the study of the monomer vibrational dynamics, as well as the dynamics of two distinct dimer structures (cyclic and open chain). This study provides insight into the role of the methyl rotor and hydrogen bonding in the vibrati…
Vibrational population of H 2 + after electroionization of thermal H2
1993
In an ion trap experiment we have determined the vibrational population of the lowest 9 vibrational levels of H2+. We used photodissociation of the trapped molecules by 248 nm light from an excimer laser and the dependence of the photodissociation cross section from the vibrational state. Our results are in good agreement to calculations, which are based on the Franck-Condon principle, but include a variation of the internuclear distance in the transition matrix element.
Ultrafast electronic relaxation and vibrational cooling dynamics of Au 144(SC2H4Ph)60 nanocluster probed by transient mid-IR spectroscopy
2014
Energy relaxation dynamics of a gold nanocluster with atomically precise composition, Au144(SC2H4Ph)60, is studied by transient mid-IR spectroscopy. The experiment is designed to simultaneously pro...