6533b7d9fe1ef96bd126c090

RESEARCH PRODUCT

Vibrational population of H 2 + after electroionization of thermal H2

Günter WerthYang WeijunR. Alheit

subject

education.field_of_studyMaterials scienceExcimer lasermedicine.medical_treatmentPopulationPhotodissociationStochastic matrixAtomic and Molecular Physics and OpticsCross section (physics)Physics::Atomic and Molecular ClustersmedicineVibrational energy relaxationMoleculePhysics::Atomic PhysicsIon trapPhysics::Chemical PhysicsAtomic physicseducation

description

In an ion trap experiment we have determined the vibrational population of the lowest 9 vibrational levels of H2+. We used photodissociation of the trapped molecules by 248 nm light from an excimer laser and the dependence of the photodissociation cross section from the vibrational state. Our results are in good agreement to calculations, which are based on the Franck-Condon principle, but include a variation of the internuclear distance in the transition matrix element.

https://doi.org/10.1007/bf01436971