Search results for "ESA"

Collisional Relaxation Processes Studied by Coherent Raman Spectroscopy for Major Species Present in Combustions

1992

The effects of collisional relaxation processes on the Q-branch profile of major species present in combustions have been studied by high resolution stimulated Raman spectroscopy. Particular interest has focused on the following collisional systems: N2-N2, O2-O2, CO2-CO2, O2-N2, N2-CO2 and N2-H2O. For each colliding pair, starting from accurate determinations of line broadening coefficients over a wide temperature range, state-to-state rates for rotational energy transfers have been deduced by using various fitting laws. Among these rate laws, special attention has been paid to the temperature dependence of the energy corrected scaling (ECS) law combined with a hybrid exponential-power law …

Improvement of Raman Spectra of SAPO-5 by Chromium(III)-Induced Luminescence Quenching

1995

Erratum to ‘A Robust Forward-Displacement Analysis of Spherical Parallel Robots’ [Mech. Mach. Theory, 2009, 44(12), pp. 2204–2216]

2012

Singular tori as attractors of four-wave-interaction systems

2009

We study the spatiotemporal dynamics of the Hamiltonian four-wave interaction in its counterpropagating configuration. The numerical simulations reveal that, under rather general conditions, the four-wave system exhibits a relaxation process toward a stationary state. Considering the Hamiltonian system associated to the stationary state, we provide a global geometrical view of all the stationary solutions of the system. The analysis reveals that the stationary state converges exponentially toward a pinched torus of the Hamiltonian system in the limit of an infinite nonlinear medium. The singular torus thus plays the role of an attractor for the spatiotemporal wave system. The topological pr…

Impulsive excitation of high vibrational states in I2–Xe complex on the electronic ground state

2010

Abstract High vibrational states, up to ν  = 22, are excited and investigated on the ground electronic state of a 1:1 I 2 –Xe complex isolated in solid Kr using femtosecond CARS technique and spontaneous resonant Raman measurements. The results show that this system is a promising candidate for investigations of coherent control of bimolecular reactions by using vibrational wavepackets on the ground electronic state.

The Homogeneous Poisson Point Process

2008

The Poisson Point Process

2020

Poisson point processes can be used as a cornerstone in the construction of very different stochastic objects such as, for example, infinitely divisible distributions, Markov processes with complex dynamics, objects of stochastic geometry and so forth.

A Continuous Approach to FETI-DP Mortar Methods: Application to Dirichlet and Stokes Problem

2013

In this contribution we extend the FETI-DP mortar method for elliptic problems introduced by Bernardi et al. [2] and Chacon Vera [3] to the case of the incompressible Stokes equations showing that the same results hold in the two dimensional setting. These ideas extend easily to three dimensional problems. Finally some numerical tests are shown as a conclusion. This contribution is a condensed version of a more detailed forthcoming paper. We use standard notation, see for instance [1].

On the biradicaloid nature of long quinoidal oligothiophenes: experimental evidence guided by theoretical studies.

2007

ChemInform Abstract: Assignment of the Absolute Configuration and Total Synthesis of (+)-Caripyrin.

2015

The antifungal secondary metabolite (+)-caripyrin was studied by vibrational circular dichroism spectroscopy. Analysis of the recorded data, with the Boltzmann weighted-average of the spectra calculated at the B3LYP/6-311G(d,p) level of theory for all relevant conformers, unequivocally proved the (R,R)-configuration for the dextrorotatory natural product. Based on this finding, a short enantioselective synthesis of (+)-caripyrin was developed.