Search results for "ESOL"
showing 10 items of 2444 documents
Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties
2020
The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geometry. Two new iron(II) complexes (C1 and C2), prepared from pyridylNHC and pyridylquinoline type ligands, respectively, have a near-perfect octahedral coordination of the metal. The photophysics of the complexes have been further investigated by means of ultrafast spectroscopy and TD-DFT modeling. For C1, it is shown that&mdash
High-resolution far-infrared synchrotron FTIR spectroscopy and analysis of the ν 7 , ν 19 and ν 20 bands of trioxane
2022
Rovibrational bands spectra of three ν20, ν7 and ν19 bands of 1, 3, 5 – trioxane (H2CO)3 were recorded in the 50–650 cm−1 range using a long path absorption cell coupled to a high resolution Fourier transform spectrometer and synchrotron radiation at the AILES beamline of the SOLEIL synchrotron. More than 16 000 lines were assigned with a dRMS better than 0.17 × 10−3 cm−1. Two different formalisms (tensorial and Watson) were used to derive accurate rotational and quartic parameters for the three bands and for the first time, a precise determination of Coriolis parameter and q+ l−doubling constant for both ν20 and ν19 perpendicular bands was obtained. Last, each set of spectroscopic paramete…
Bridging Sensing and Decision Making in Ambient Intelligence Environments
2009
Context-aware and Ambient Intelligence environments represent one of the emerging issues in the last decade. In such intelligent environments, information is gathered to provide, on one hand, autonomic and easy to manage applications, and, on the other, secured access controlled environments. Several approaches have been defined in the literature to describe context-aware application with techniques to capture and represent information related to a specified domain. However and to the best of our knowledge, none has questioned the reliability of the techniques used to extract meaningful knowledge needed for decision making especially if the information captured is of multimedia types (image…
A Study on Patch-Based Progressive Coding Schemes of Semi-Regular 3D Meshes for Local Wavelet Compression and View-Dependent Transmission
2010
International audience; This paper firstly introduces a wavelet-based segmentation for three-dimensional (3D) Semi-Regular (SR) meshes, as a pre-processing step, in a region-independent progressive coding algorithm. The proposed segmentation process aims at producing homogeneous regions with respect to their frequency amplitudes on the mesh surface, in other words: patches with different degrees of roughness. We have then studied the behavior of the wavelets, obtained during the independent coding of each region, especially close to the patch boundaries. The main contribution of this paper consists in considering three different possible wavelet decompositions, close to the region borders, …
Development of new techniques for super-resolution video sequences : Towards a real-time implementation on Smart Camera
2020
These thesis works are part of an european project aiming to design a very hight resolution (8k) video camera. Within this project our team had the task of working on two technological aspects: (1) the design of a demonstrator carrying out a realtime deconvolution of a video stream coming from a very high resolution camera created by the consortium , (2) the design of a prototype allowing to increase the resolution and the level of detail of video streams from an input resolution of 4k to 8k using Super Resolution (SR) methods. This manuscript mainly presents the work related to the creation of the prototype realizing a Super Resolution method. In order to be able to assess the qualitative …
Local monomialization of generalized real analytic functions
2011
Generalized power series extend the notion of formal power series by considering exponents ofeach variable ranging in a well ordered set of positive real numbers. Generalized analytic functionsare defined locally by the sum of convergent generalized power series with real coe cients. Weprove a local monomialization result for these functions: they can be transformed into a monomialvia a locally finite collection of finite sequences of local blowingsup. For a convenient frameworkwhere this result can be established, we introduce the notion of generalized analytic manifoldand the correct definition of blowing-up in this category.
Measurement of the Depth of Maximum of Extensive Air Showers above 10(18) eV
2010
We describe the measurement of the depth of maximum, Xmax, of the longitudinal development of air showers induced by cosmic rays. Almost four thousand events above 10¹⁸ eV observed by the fluorescence detector of the Pierre Auger Observatory in coincidence with at least one surface detector station are selected for the analysis. The average shower maximum was found to evolve with energy at a rate of (106⁺³⁵₋₂₁) g/cm²/decade below 1018.24 ± 0.05 eV and (24 ± 3) g/cm²/decade above this energy. The measured shower-to-shower fluctuations decrease from about 55 to 26 g/cm². The interpretation of these results in terms of the cosmic ray mass composition is briefly discussed.
Identifying clouds over the Pierre Auger Observatory using infrared satellite data
2013
We describe a new method of identifying night-time clouds over the Pierre Auger Observatory using infrared data from the Imager instruments on the GOES-12 and GOES-13 satellites. We compare cloud. identifications resulting from our method to those obtained by the Central Laser Facility of the Auger Observatory. Using our new method we can now develop cloud probability maps for the 3000 km(2) of the Pierre Auger Observatory twice per hour with a spatial resolution of similar to 2.4 km by similar to 5.5 km. Our method could also be applied to monitor cloud cover for other ground-based observatories and for space-based observatories. (C) 2013 Elsevier B.V. All rights reserved.
LOFT: the Large Observatory For X-ray Timing
2012
The LOFT mission concept is one of four candidates selected by ESA for the M3 launch opportunity as Medium Size missions of the Cosmic Vision programme. The launch window is currently planned for between 2022 and 2024. LOFT is designed to exploit the diagnostics of rapid X-ray flux and spectral variability that directly probe the motion of matter down to distances very close to black holes and neutron stars, as well as the physical state of ultra-dense matter. These primary science goals will be addressed by a payload composed of a Large Area Detector (LAD) and a Wide Field Monitor (WFM). The LAD is a collimated (<1 degree field of view) experiment operating in the energy range 2-50 keV,…
Infrared Spectroscopy of Ruthenium Tetroxide and High-resolution analysis of the v3 band
2015
International audience