Search results for "ESR"

Pulsed EPR analysis of tooth enamel samples exposed to UV and gamma-radiations

2011

Abstract The electron paramagnetic resonance (EPR) spectroscopy is widely applied for retrospective dosimetric purposes by means of quantitative detection of radicals in tooth enamel and bone samples. In this work we report a study by cw and pulsed EPR on two samples of human tooth enamel respectively irradiated by UV (254 nm) and γ-exposed. The continuous wave (cw) EPR spectra have shown the usual presence in both samples of two types of CO 2 − radicals, with axial and orthorombic g tensors. We have obtained the electron spin echo detected EPR (ED-EPR) spectra at 80 K of the two samples, and we have shown that they are suitable to mark the difference between the effects produced by the dif…

Watch glasses exposed to 6 MV photons and 10 MeV electrons analysed by means of ESR technique: A preliminary study

2011

Abstract In this work we report a case study of the ESR response of watch glasses exposed to 6 MV photons and to 10 MeV electrons. The choice of watch glasses is justified by the fact that watch glasses are very close to the exposed individual. For both types of radiation beams, the absorbed doses belong to the range between 1 and 20 Gy. The samples have been irradiated in water-equivalent plastic phantom with a linear accelerator used for radiotherapy. After exposure watch glass samples have been cut in small strip-shaped pieces with suitable size to be put into the quartz tube for ESR measurements. The signal induced by radiation (RIS) lies in the g ∼ 2 region and must be discriminated fr…

Irradiation detection of herbal ingredients used in plant food supplements by Electron Spin Resonance on samples pre-treated with alcoholic extraction

2020

Abstract This study aimed to verify the applicability of the EN 1787 method for the detection of irradiation in herbal ingredients used in Plant Food Supplements (PFSs). In matrices such as herbs and spices the main limit of the method is the presence of intrinsic radicals responsible for spurious signals leading to complex ESR spectra. To overcome this limit, before ESR measurement a treatment with alcohol has been proposed (Delincee and Soika, 2002; Ahn et al., 2012, 2014). As reported in the literature, this treatment is expected to reduce/eliminate the confounding signals so that the samples may be correctly classified. In this study the efficacy of the pre-treatment was tested on raw h…

Un 'halcón' paradigmático

2007

Determinazione della componente fotonica all’interno della colonna termica del reattore TRIGA mediante letture ESR di dosimetri di alanina

2014

Phenol compounds for Electron Spin Resonance dosimetry of gamma and neutron beams

2014

Analisi dei vetri di orologi tramite risonanza paramagnetica elettronica (EPR) e termoluminescenza (TL) per dosimetria retrospettiva

2016

Negli ultimi anni è cresciuto il rischio di esposizioni radiologiche non controllate della popolazione, sia a causa di incidenti associati ad applicazioni industriali e mediche delle radiazioni ionizzanti sia in seguito ad incidenti legati all’abbandono o alla dismissione di sorgenti ma anche ad un uso criminale di materiale radioattivo [1–3]. Gli effetti biologici prodotti dalle radiazioni ionizzanti dipendono fortemente dalla quantità di energia impartita per unità di massa (dose assorbita) [4]. Pertanto, nell’ambito di un incidente radiologico, disporre di procedure di ricostruzione della dose assorbita da un individuo può contribuire oltre che ad identificare i membri della popolazione …

Sviluppo e Applicazioni di nuovi materiali per la dosimetria delle radiazioni ionizzanti

The Research Activities carried out during the Three-year International PhD Course in Applied Physics of the candidate Salvatore Gallo had two main topics related to dosimetry of ionizing radiations (IR): the analysis of 3D gel dosimeters and the analysis of solid state dosimeters through electron spin resonance. Both these activities are focused on a careful study of new materials for the IR Dosimetry, both in terms of physical characterization of these new materials and of the optimization of readout methods for dosimetric measurements. The study performed through various techniques such as UV-Vis absorption spectroscopy, NMR Relaxometry, Magnetic Resonance Imaging (MRI) and Electron Spin…

Defects in graphenic materials by EPR and DFT methods

2016

We have used EPR to characterize a series of defects, which are characterized by tipical g-tensors, linewidths, intensity as function of the temperature. Mostly, signals arises from the presence of conduction electrons, and of so-called "edge states", that are unpaired electrons located at the edges of graphenic flakes; the relative molecular orbitals are not very muche extended as for low-lying orbitals, and are located within few atomic rows from edges with zig-zag topology. All the relative EPR signals are naturally and intrinsically generated by all graphitic materials. We now extend our study to the defects that are formed inside the graphenic structure. There is a full zoo of possible…

Characterization of phenolic pellets for ESR dosimetry in photon beam radiotherapy.

2017

We report a study of the dosimetric features of phenolic compounds for applications in radiation therapy dosimetry of clinical photon beams by using ESR spectroscopy. After the optimization of the ESR readout parameters, basic dosimetric properties (such as intra-batch reproducibility, dose-response, sensitivity, linearity, dose rate dependence, tissue-equivalence and signal stability) of laboratory-made phenolic dosimeters in form of pellets were investigated. Furthermore, these dosimeters were tested for measuring the depth dose profile of a 6 MV clinical photon beam. The results reported show that these dosimeters are promising materials for ESR dosimetric applications in radiation thera…