Search results for "EXCIMER-LASER"

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In situobservation of the generation and annealing kinetics of E ′ centres induced in amorphous SiO2by 4.7 eV laser irradiation

2011

The kinetics of E' centers induced in silica by 4.7eV laser irradiation was investigated observing in situ their optical absorption band at 5.8 eV. After exposure the defects decay due to reaction with diffusing molecular hydrogen of radiolytic origin. Hydrogen-related annealing is active also during exposure and competes with the photo-induced generation of the centers until a saturation is reached. The concentrations of E' and H2 at saturation are proportional, so indicating that the UV-induced generation processes of the two species are correlated. These results are consistent with a model in which E' and hydrogen are generated from a common precursor Si-H.

MECHANISMMaterials scienceHydrogenAnnealing (metallurgy)KineticsHIGH-PURITY SILICAFOS: Physical scienceschemistry.chemical_elementPhotochemistrylaw.inventionDEFECT FORMATIONTRANSIENT ABSORPTIONlawGeneral Materials ScienceIrradiationINDUCED COLOR-CENTERSCondensed Matter - Materials ScienceMaterials Science (cond-mat.mtrl-sci)Condensed Matter PhysicsLaserDIFFUSIONAmorphous solidchemistryAbsorption bandMOLECULAR-HYDROGENGLASSESLUMINESCENCERadiolysisEXCIMER-LASERJournal of Physics: Condensed Matter
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Ultraviolet-induced paramagnetic centers and absorption changes in singlemode Ge-doped optical fibers

2009

We investigated the laser-energy-density dependence of absorption changes and paramagnetic centers induced by a cw Ar+ laser operating at 5.1 eV, in both unloaded and H-2-loaded single mode Ge-doped optical fibers. The induced absorption is measured in the blue and near ultraviolet spectral range by using the 3.1 eV photoluminescence, ascribed to Ge lone pair center (GLPC), as an in situ probe source. We find that the Ge (1) center (GeO4-) is induced upon UV exposure by electron trapping on GeO4 precursors, where the free electrons are most likely produced by ionization of GLPC. Ge (1) is responsible of optical transmission loss of the fiber in the investigated range. Hydrogen loading stron…

Optical fiberMaterials sciencePhotoluminescence060.2290 160.4670 160.4760 300.1030 300.2140 300.6370 300.636002 engineering and technologymedicine.disease_cause01 natural sciences7. Clean energyAbsorptionMECHANISMSlaw.inventionEmissionParamagnetismOpticslawIonization0103 physical sciencesmedicineSILICA010306 general physicsSpectroscopyAbsorption (electromagnetic radiation)defectsESR[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]business.industryDopingGEO2-SIO2 GLASSESPHOTOSENSITIVITY021001 nanoscience & nanotechnologyAtomic and Molecular Physics and OpticsIRRADIATIONFibersDEFECT CENTERSSIO2 GLASSLUMINESCENCEKRF EXCIMER-LASER0210 nano-technologybusinessUltravioletGENERATIONOptics Express
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