Search results for "Elasticity"
showing 10 items of 736 documents
Polybutadiene model networks —synthesis, mechanical characterization and comparison with rubber elasticity models
1995
Model networks of defined crosslink density are prepared via nonradical statistical crosslinking of polybutadiene in bulk and concentrated solution using a masked bistriazolinedione as crosslinker. The kinetics of crosslinking is monitored by FT-IR-spectroscopy. The reaction follows pseudo-1st-order reaction kinetics. The activation parameter of the crosslinking reaction is estimated from crosslinking at various temperatures. Networks of deuterated polybutadiene are prepared by this reaction in a wide range of crosslink densities. The stress strain behavior is analyzed according to the Junction Constraint-Theory of rubber elasticity (JCT) and to the approach introduced by Graessley accounti…
Dislocation interaction with C in α-Fe: a comparison between atomic simulations and elasticity theory
2008
International audience; The interaction of C atoms with a screw and an edge dislocation is modelled at an atomic scale using an empirical Fe-C interatomic potential based on the Embedded Atom Method (EAM) and molecular statics simulations. Results of atomic simulations are compared with predictions of elasticity theory. It is shown that a quantitative agreement can be obtained between both modelling techniques as long as anisotropic elastic calculations are performed and both the dilatation and the tetragonal distortion induced by the C interstitial are considered. Using isotropic elasticity allows to predict the main trends of the interaction and considering only the interstitial dilatatio…
Thermomechanical Analysis of Isora Nanofibril Incorporated Polyethylene Nanocomposites
2021
The research on cellulose fiber-reinforced nanocomposites has increased by an unprecedented magnitude over the past few years due to its wide application range and low production cost. However, the incompatibility between cellulose and most thermoplastics has raised significant challenges in composite fabrication. This paper addresses the behavior of plasma-modified polyethylene (PE) reinforced with cellulose nanofibers extracted from isora plants (i.e., isora nanofibrils (INFs)). The crystallization kinetics of PE&ndash
Intrinsic mechanisms limiting the use of carbon fiber composite pressure vessels
2016
International audience; The viscoelastic properties of the resins used in carbon fiber composite pressure vessels introduce time effects which allow damage processes to develop during use under load. A detailed understanding of these processes has been achieved through both experimental and theoretical studies on flat unidirectional specimens and with comparisons with the behavior of pressure vessels. Under steady pressures, the relaxation of the resin in the vicinity of earlier fiber breaks gradually increases the sustained stress in neighboring intact fibers and some eventually break. The rate of fiber failure has been modeled based only on physical criteria and shown to accurately predic…
Rheological Percolation Threshold in High-Viscosity Polymer/CNTs Nanocomposites
2017
AbstractPolystyrene (PS)/multi-walled carbon nanotubes (CNT) nanocomposites have been prepared through melt mixing processing aiming at obtaining a uniform and homogeneous dispersion of the used nanoparticles within the polymeric matrix. Optical and scanning electron microscopy has been employed to determine the dispersion and distribution of CNTs at different length scales. Furthermore, the linear viscoelastic behavior of formulated nanocomposites has been deeply investigated. As a result of CNTs added, the nanocomposites experience a transition from liquid-like to solid-like rheological behavior, and a disappearance of relaxation processes at low frequency can be noticed. By plotting G’ v…
Investigation on Application of Basalt Materials as Reinforcement for Flexural Elements of Concrete Bridges
2015
Basalt polymers are rather new materials for civil engineering; therefore, identification of peculiarities and limitations of application of such polymers in concrete structures (particularly bridges) is of vital importance. This paper experimentally investigates deformation behaviour and cracking of flexural elements, which are predominant parameters governing serviceability of the bridges. Unlike a common practice, the present study is not limited by the analysis of concrete beams reinforced with the polymer bars; it also considers effectiveness of basalt fibre reinforced polymer sheets for repairing the beams. The analysis has revealed that a combination of the high strength and elastici…
Structural model of gelation processes of a sodium silicate sol destabilized by calcium ions: combination of SAXS and rheological measurements
2005
This study deals with the physico-chemical processes involved in the formation of basic fractal silica gels derived from a sodium silicate sol destabilized by calcium ions. Using small-angle X-ray scattering and dynamic rheological measurements, structural and viscoelastic properties have been investigated in situ during aggregation and gelation processes. The experimental results lead to a consistent model that describes the structural features and aggregation mechanisms involved in the formation of these gels.
About the Insoluble to the Soluble Prussian Blue Transformation
2009
Figure 1 shows firstly an increase of the motional resistance during the first scan of the transformation process, denoting an increase of the viscoelasticity of this structure. Soluble Prussian Blue have a localized changeover in the properties of these films just when Fe(III) fraction reaches the characteristic value. Secondly, this Figure shows an increase of motional resistance in zone 2 of the voltammetric scan, proving more evident for the last cycles than for the first ones. The increase of the motional resistance in zone 2 records an increase of the PB coercive field which at the same time, is due to an interesting changeover in the PB physiochemical properties localized at this pot…
Effect of the loading rate on ultimate strength of composites. Application: Pressure vessel slow burst test
2013
International audience; The strength of unidirectional elastic fibre composites is shown to depend on the loading rate as the viscoelastic nature of the matrix results in a fall in breaking load as the rate is reduced. The simulation of the accumulation of fibre breaks leading to failure, takes into account all physical phenomena involved fibre failure, including the stochastic nature of fibre strength, stress transfer through the matrix between reinforcements, interfacial debonding and the viscoelastic nature of the matrix. The kinetics of composite failure are seen to involve the initial formation of random fibre breaks which at higher loads coalesce into clusters of broken fibres. The ra…
Viscoelasticity of pore-spanning polymer membranes derived from giant polymersomes
2010
We show how the viscoelastic properties of membranes formed from poly(butadiene)-block-poly(ethylene oxide) (PB130-b-PEO66) block copolymers can be locally accessed by atomic force microscopy. Polymer membranes are spread on microstructured porous silicon substrates from PB130-b-PEO66 vesicles by decreasing the osmotic pressure of the solution. Local viscoelastic properties of the pore-spanning polymer membranes were obtained from site-specific indentation experiments. Elastic moduli of these membranes were in the order of few MPa, while the elastic moduli of cross-linked membranes considerably increased to few GPa. Furthermore, the energy dissipation and velocity dependence of the hysteres…