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RESEARCH PRODUCT
About the Insoluble to the Soluble Prussian Blue Transformation
Francisco VicenteJerónimo AgrisuelasJosé Juan García-jareñoDavid Giménez-romerosubject
Materials scienceSoluble Prussian blueMotional resistanceAnalytical chemistryChangeoverCoercivityViscoelasticitydescription
Figure 1 shows firstly an increase of the motional resistance during the first scan of the transformation process, denoting an increase of the viscoelasticity of this structure. Soluble Prussian Blue have a localized changeover in the properties of these films just when Fe(III) fraction reaches the characteristic value. Secondly, this Figure shows an increase of motional resistance in zone 2 of the voltammetric scan, proving more evident for the last cycles than for the first ones. The increase of the motional resistance in zone 2 records an increase of the PB coercive field which at the same time, is due to an interesting changeover in the PB physiochemical properties localized at this potential range. Therefore, it is concluded that this localized changeover takes manly place when the soluble PB structure is synthesized.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-03-20 | ECS Transactions |