Search results for "Electrode"

Nanostructured CdO thin films for water treatments

2016

Abstract CdO was the very first transparent conducting metal oxide discovered. CdO thin films show electrical and optical properties of interest as photosensitive anode materials for photochemical cells, phototransistors, photodiodes, window electrodes in liquid crystal displays, IR detectors, antireflection coatings, gas sensors and in other solar energy applications. In the present study we report on the spectroscopic, microscopic, electrical and photo-catalytic properties of CdO thin films prepared by a metal organic chemical vapor method. The degenerate semiconducting CdO thin films are useful as photocatalysts for water treatments.

Theoretical and experimental study of the kinetics of particle chains near electrodes in dielectrophoretic devices

2014

Using a three dimensional coupled Monte Carlo-Poisson algorithm and experimental results we studied the role of the particle-particle dipole interaction on the kinetics of a system of human cells suspended in a static liquid medium under the action of an oscillating non-uniform electric field generated by polynomial electrodes. We found that the kinetics of the cells during negative/repulsive dielectrophoresis depends on the local distribution of particles. If the cells have generated long chains during positive/attractive dielectrophoresis, such chains can hinder subsequent detachment resulting in a reduction of the separation/manipulation efficiency of dielectrophoretic device. This effec…

Preparation of Highly Porous Carbonous Electrodes by Selective Laser Sintering

2019

Selective laser sintering (SLS) 3D printing was utilized to fabricate highly porous carbonous electrodes. The electrodes were prepared by using a mixture of fine graphite powder and either polyamide-12, polystyrene, or polyurethane polymer powder as SLS printing material. During the printing process the graphite powder was dispersed uniformly on the supporting polymer matrix. Graphite’s concentration in the mixture was varied between 5 and 40 wt % to find the correlation between the carbon content and conductivity. The graphite concentration, polymer matrix, and printing conditions all had an impact on the final conductivity. Due to the SLS printing technique, all the 3D printed electrodes …

Novel Methodologies to Model Charge Transport in Metal-Air Batteries

2018

On multi-objective optimal reconfiguration of MV networks in presence of different grounding

2015

The present work faces the traditional multi-objective optimal reconfiguration problem of a distribution grid including the safety issue in the objective functions. Actually, in many medium voltage networks still transformers with ungrounded neutral and with resonant grounded neutral coexist in the same area. This may be sometimes cause of problems during a single-line-to-ground fault if the ground electrodes of one or more cabins, initially designed for satisfying the safety conditions in a resonant grounded neutral network, after the reconfiguration are in a grounded neutral one or vice versa. In the paper a safety objective function is defined and the Non dominated Sorting Genetic Algori…

Electron-phonon heat transport in arrays of Al islands with submicrometer-sized tunnel junctions.

1996

We present experimental evidence of the effect of electrode volume and its shape on thermalization of small metallic islands for single electron tunneling. We have investigated the power law and the magnitude of the thermal transport and found that it obeys the common ${T}^{5}$ law for electron-phonon coupling only for the smallest islands studied, and in other cases considered, with cooling fins attached to the islands, the coupling per unit volume is weaker and it rather follows a law $\ensuremath{\propto}{T}^{p}$, where $pl5$. We attribute this to local hot electrons adjacent to the tunnel junctions.

ChemInform Abstract: Metal- and Reagent-Free Highly Selective Anodic Cross-Coupling Reaction of Phenols.

2014

Boron-doped diamond electrodes allow the direct anodic cross-coupling of phenols in hexafluoroisopropanol without using leaving functions or protecting groups.

From Microorganism-Based Amperometric Biosensors towards Microbial Fuel Cells

2021

This review focuses on the overview of microbial amperometric biosensors and microbial biofuel cells (MFC) and shows how very similar principles are applied for the design of both types of these bioelectronics-based devices. Most microorganism-based amperometric biosensors show poor specificity, but this drawback can be exploited in the design of microbial biofuel cells because this enables them to consume wider range of chemical fuels. The efficiency of the charge transfer is among the most challenging and critical issues during the development of any kind of biofuel cell. In most cases, particular redox mediators and nanomaterials are applied for the facilitation of charge transfer from a…

Possibility of Wastewater Treatment Using MFC with Ni-Co Catalyst of Fuel Electrode

2016

Abstract One of the problems with microbial fuel cells is a low current density of those energy sources. Nonetheless, it is possible to increase the current density by using the catalyst for fuel electrode (anode) - as long as a low cost catalyst can be found. The possibility of wastewater treatment using the Ni-Co alloy as catalyst for MFC’s is presented in this paper. The alloys were obtained with different concentrations of Co (15 and 50% of Co). The increase of current density with Ni-Co catalyst is approximately 0,1 mA/cm2. So, a fundamental possibility wastewater treatment using the Ni-Co alloy as catalyst for microbial fuel cells was presented.

Special applications of reverse electrodialysis

2016

Reverse electrodialysis (RED) is a process for direct electricity production from salinity gradients, based on the use of suitable exchange membranes. To develop the RED process on an applicative scale and to add value to the overall process, a key role is entrusted to the selection of electrodic system, redox species, and electrode materials. In particular, it was shown that a proper selection of redox processes allows the use of a RED cell for the wastewater treatment of organic and inorganic pollutants resistant to conventional biological methods and for the synthesis of chemicals without energy supply. The utilization of microbial reverse electrodialysis cells was also proposed to incre…