Search results for "Electrode"

Zinc oxide and indium tin oxide thin films for the growth and characterization ofShewanella loihicaPV-4 electroactive biofilms

2011

Transition metal oxides (TMO) electrodes provide a suitable platform for spectroscopy- and microscopy-based investigation of viable electroactive biofilms (EABs). Commercially available TMOs, such as indium titanium oxide (ITO), are produced from rare and expensive elements. Thus, there is a significant need to explore alternative technology to meet the demand. ZnO-based TMOs are low-cost and have excellent electrochemical properties. In this study, we report for the first time a model EAB of Shewanella loihica PV-4 on ZnO films deposited on perspex substrates via pulsed laser deposition (PLD). Commercially available ITO electrodes were also used for comparison. 480 Virulence Volume 2 Issue…

Influence of growth, measuring conditions, and cell types on oxygen tensions in multicell tumor spheroids determined by microelectrodes

1981

Polarographic and voltammetric methods for the determination of elements

1978

Measurements of the correlations between current, voltage and time, when microelectrodes are used, yield qualitative and quantitative information on the elemental composition of the solution investigated, if the method of measurement is properly chosen. Instrumental development today makes it possible, even at electrodes which make measurement difficult, such as the classical dropping mercury electrode, to obtain more reliable information on detection limits and number of elements detectable, by taking into account the functional interdependence of interference parameters and signal generation. Simultaneous determination of several components is possible, especially with non-linear a. c. po…

Local H2-Clearance and PO2-Measurements in Microareas of the Brain Tissue in Rats

1969

Lubbers [5], as well as others, measured the oxygen partial pressure of the exposed cerebral cortex by means of small platinum microelectrodes. They registered low pO2 values between 1 and 3 mmHg in certain areas of the cortex, despite the fact that the EEG was of normal pattern. In order to decide whether these low pO2 values are a result of low rCBF, or high local oxygen consumption of brain tissue, we developed a new method. Using the same platinum needle, we measured both local pO2 values and H2-clearance curves in microareas of the brain tissue. Cater and Silver [2], Lubbers [4, 5], and others used glass-insulated platinum microelectrodes to measure local pO2. Further, Aukland, Bower a…

Liquid crystal lens array for 3D microscopy and endoscope application

2016

In this paper, we demonstrate two liquid crystal (LC) lens array devices for 3D microscope and 3D endoscope applications respectively. Compared with the previous 3D biomedical system, the proposed LC lens arrays are not only switchable between 2D and 3D modes, but also are able to adjust focus in both modes. The multi-function liquid crystal lens (MFLC-lens) array with dual layer electrode has diameter 1.42 mm, which is much smaller than the conventional 3D endoscope with double fixed lenses. The hexagonal liquid crystal micro-lens array (HLC-MLA) instead of fixed micro-lens array in 3D light field microscope can extend the effective depth of field from 60 um to 780 um. To achieve the LC le…

Pathophysiological approaches to identifying tumor hypoxia in patients

1991

The present report summarizes observations of the authors on tumor oxygenation and on techniques for characterizing tumor hypoxia in patients. Cryospectrophotometric measurements of HbO2 saturations in tumor microvessels allow for estimates of the proportion of well oxygenated tissue regions. Labeling of tissue areas at oxygen (O2) tensions (pO2) less than 10 mm Hg with misonidazole may be used for a general characterization of the oxygenation status in patient tumors rather than for the determination of the radiobiologically hypoxic cell fraction. Quantitative bioluminescence and single photon imaging make it possible to determine ATP concentrations in absolute terms with a spatial resolut…

Biomimetic oxygen reduction by cofacial porphyrins at a liquid-liquid interface.

2012

Oxygen reduction catalyzed by cofacial metalloporphyrins at the 1,2-dichlorobenzene−water interface was studied with two lipophilic electron donors of similar driving force, 1,1'-dimethylferrocene (DMFc) and tetrathiafulvalene (TTF). The reaction produces mainly water and some hydrogen peroxide, but the mediator has a significant effect on the selectivity, as DMFc and the porphyrins themselves catalyze the decomposition and the further reduction of hydrogen peroxide. Density functional theory calculations indicate that the biscobaltporphyr- in, 4,5-bis(5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethylporphyrinyl))-9,9-dimethylxanthene, Co2(DPX), actually catalyzes oxygen reduction to hydrogen p…

Solubility of NH3 and apparent pK of NH4+ in human plasma, isotonic salt solutions and water at 37 degrees C.

1998

The solubility of ammonia, alphaNH3 (mM/mmHg), was determined at 37 degrees C and low ammonia partial pressure (0.02-1 mmHg) in pure water (n =24) as 46.70+/-0.40; aqueous isotonic salt solutions (n = 7) as 46.8+/-0.81; and human plasma (n = 5) as 42.0+/-0.66. The last figure increases to 45.3+/-0.63 if expressed in molal units (mmol/kg plasma water x mmHg) instead of molarity with respect to the water content of the plasma (mean from four healthy and fasting donors: 0.908+0.005 kg H2O/kg plasma; mean density at 37 degrees C: 1.020+/-0.002 kg/l). In pure water, the solubility value is the mean of three different methods: (a) extrapolation of the salting-out effect of ammonia in aqueous NaOH…

Diversity-Oriented Synthesis of Polycyclic Scaffolds by Modification of an Anodic Product Derived from 2,4-Dimethylphenol

2010

Electroburning of few-layer graphene flakes, epitaxial graphene, and turbostratic graphene discs in air and under vacuum

2015

Graphene-based electrodes are very promising for molecular electronics and spintronics. Here we report a systematic characterization of the electroburning (EB) process, leading to the formation of nanometer-spaced gaps, on different types of few-layer graphene (namely mechanically exfoliated graphene on SiO2, graphene epitaxially grown on the C-face of SiC and turbostratic graphene discs deposited on SiO2) under air and vacuum conditions. The EB process is found to depend on both the graphene type and on the ambient conditions. For the mechanically exfoliated graphene, performing EB under vacuum leads to a higher yield of nanometer-gap formation than working in air. Conversely, for graphene…