Search results for "Electrode"
showing 10 items of 950 documents
Charge carrier transport mechanisms in CdZnTe detectors grown by the vertical Bridgman technique
2016
In this work, we report on the results of electrical characterization of CdZnTe (CZT) detectors, with gold electroless contacts, grown by the boron oxide encapsulated vertical Bridgman technique (B-VB), currently produced at IMEM-CNR (Parma, Italy). The detectors, with different thicknesses (1 and 2.5 mm), have the same electrode layout: the anode is a central electrode (2 x 2 mm(2)) surrounded by a guard ring electrode. The cathode is a planar electrode covering the detector surface (4.1 x 4.1 mm(2)). Current-voltage (I-V) characteristics were measured at different temperatures in order to study the charge transport and the electrical properties. These detectors were compared with the trav…
Investigation of electrode material – redox couple systems for reverse electrodialysis processes. Part II: Experiments in a stack with 10–50 cell pai…
2013
Abstract The performances of reverse electrodialysis depend on several factors, including the nature of the electrode material and of the redox processes adopted to make possible the conversion between chemical potential and electric power. In this paper the possible utilization of various redox processes (reduction/oxidation of iron species, oxidation and reduction of water, oxidation of chlorine and reduction of water) was studied in a stack equipped with 10–50 cell pairs and by focused electrolyses in a three compartment cell. The effect of selected redox processes on power density output and eventual contamination of saline solutions flowing in the stack was evaluated in detail. The eff…
Polarographische Untersuchungen an monomeren und polymeren N-Chlorcarbonamiden
1979
The polarographic reduction of low molecular and high molecular N-chlorocarboxamides at the dropping mercury electrode proceeds in two one-electron-transfer steps, which are highly irreversible. In the case of the low molecular models 1 and 2 the reaction is diffusion-controlled, whereas in the case of the poly(N-chloroamide) 3 the reaction is adsorption-controlled. Reduction of several poly(N-chloroamide)s shows always two reduction waves with a distance of 0,5 V. There is, however, no relation between the polyamide-type and the position of the half-wave potentials. The polarographic reduction can be used as an analytical method for quantitative determination of N-chlorocarboxamide groups …
Anodic Dissolution of Nickel across Two Consecutive Electron Transfers
2007
The analysis of the electrochemical quartz crystal microbalance and electrochemical impedance spectroscopy results are consistent with a nickel electrodissolution process limited by the passage of Ni(I) to Ni(II), when chloride ions are present in the acid sulfate medium, or by the passage of Ni(II) to Ni 2+ in solution, in absence of chloride. This interpretation allows an explanation of the potential evolution of Fdm/dQ values in both experimental conditions by assuming the formation of a new phase on the electrode surface with a gel-like structure placed between the metal and the solution. Ni(I) surface concentration is calculated from the instantaneous mass/charge Fdm/dQ values.
Sensing properties of ZnO nanostructured layers
2017
Nanostructured ZnO layers have been deposited onto SiO 2 /Si substrates by spray pyrolysis, with previously patterned interdigitated gold electrodes. We have then measured the capacitive and resistive response against ambient parameters such as relative humidity and illumination.
Relationship between physiological excitatory and inhibitory measures of excitability in the left vs. right human motor cortex and peripheral electro…
2017
Abstract The current study was aimed at investigating the relationships of excitatory and inhibitory circuits of the left vs. right primary motor cortex with peripheral electrodermal activity (EDA). Ten healthy subjects participated in two experimental sessions. In each session, EDA was recorded for 10 min from the palmar surface of the left hand. Immediately after EDA recording, Transcranial Magnetic Stimulation (TMS) was used to probe excitatory and inhibitory circuits of the left or right primary motor cortex using two protocols of stimulation: the input-output curve for recording of motor evoked potentials, for testing excitatory circuits; the long-interval cortical inhibition (LICI) pr…
Eh and pH gradients in Camembert cheese during ripening: Measurements using microelectrodes and correlations with texture
2007
International audience; This study investigated the use of microelectrodes to continuously and simultaneously monitor pH and redox potential (Eh) gradients in Camembert cheeses from the rind to the core, as a function of ripening time (15 and 35 days). Cheeses were shown to be heterogeneous throughout their mass. An Eh gradient existed from the rind to the core. The surface was oxidizing (+330 to +360 mV) and the core was reducing and became more so in the course of ripening (−300 to −360 mV). A relationship between firmness and Eh was shown. pH gradients were in line with those previously described in the literature and related to ammonium and lactate gradients. Gradients evolved from the …
Development of electrodes materials for SOFC fed by natural gas / biogas. Applications to "pre-reforming" and "single-chamber" concepts
2010
Solid Oxide Fuel Cell is a device for “clean” electricity production from chemical energy. The new configuration called “single-chamber” seems to be very attractive with several advantages over bi-chamber conventional configuration: easier manufacturing, lowering of working temperature, possible use of hydrocarbons as fuel… Such configuration involves the development of new electrode materials satisfying new requirements. The evaluation of 7 potential cathode materials through several characterizations has shown that a compromise has to be found since one material does not exhibit all the requested features. A library of 15 supported catalysts (3 metals and 5 supports) was developed. These …
Influence of mobile ions on the electroluminescence characteristics of methylammonium lead iodide perovskite diodes
2016
In this work, we study the effect of voltage bias on the optoelectronic behavior of methylammonium lead iodide planar diodes. Upon biasing the diodes with a positive voltage, the turn-on voltage of the electroluminescence diminishes and its intensity substantially increases. This behavior is reminiscent of that observed in light-emitting electrochemical cells (LECs), single-layer electroluminescent devices in which the charge injection is assisted by the accumulation of ions at the electrode interface. Because of this mechanism, performances are largely independent from the work function of the electrodes. The similarities observed between planar perovskite diodes and LECs suggest that mobi…
Development of a process for the treatment of synthetic wastewater without energy inputs using the salinity gradient of wastewaters and a reverse ele…
2019
Abstract Electrochemical processes are considered very effective methods for the treatment of wastewater contaminated by organics resistant to conventional biological processes and various inorganic pollutants. Large sites that treat wastewaters usually deal with a large number of waters often characterized by different salinity contents, that could be potentially used to provide the energy necessary for the electrochemical remediation. Hence, in this work a reverse electrodialysis (RED) process for the treatment of synthetic wastewaters contaminated by organics, without energy inputs, using the salinity gradient of different wastewaters, was studied, for the first time. It was found that t…