Search results for "Electron Spectra"
showing 10 items of 20 documents
Stoichiometry-related Auger lineshapes in titanium oxides: Influence of valence-band profile and of Coster-Kronig processes
2004
International audience; The ability to determine the nature and the occurrence of defects is a central need of ceramic surface chemistry. In titanium oxides, the Ti-LMV Auger decays line shape is very sensitive to the titanium degree of oxidation, and has long been empirically used as a qualitative probe of the stoichiometry. In the present work, resonant Auger and resonant valence-band measurements at the Ti-L2,3 edges in TiO2, TiO2–x and metallic titanium provide a clear evidence that the evolutions of the Ti-LMV Auger line shape are due to drastic changes in the valence-band profile and in the probability of L2L3V Coster-Kronig decay processes when a fraction of titanium ions is reduced.…
A combined theoretical and experimental determination of the electronic spectrum of acetone
1996
A combined ab initio and experimental investigation has been performed of the main features of the electronic spectrum of acetone. Vertical transition energies have been calculated from the ground to the ny→π∗, π→π∗, σ→π∗, and the n=3 Rydberg states. In addition, the 1A1 energy surfaces have been studied as functions of the CO bond length. The 1A1 3p and 3d states were found to be heavily perturbed by the π→π∗ state. Resonant multiphoton ionization and polarization‐selected photoacoustic spectra of acetone have been measured and observed transitions were assigned on internal criteria. The calculated vertical transition energies to the ny→π∗ and all Rydberg states were found to be in agreeme…
gA -driven shapes of electron spectra of forbidden β decays in the nuclear shell model
2017
The evolution of the shape of the electron spectra of 16 forbidden ${\ensuremath{\beta}}^{\ensuremath{-}}$ decays as a function of ${g}_{\mathrm{A}}$ was studied using the nuclear shell model in appropriate single-particle model spaces with established, well-tested nuclear Hamiltonians. The $\ensuremath{\beta}$ spectra of $^{94}\mathrm{Nb}({6}^{+})\ensuremath{\rightarrow}\phantom{\rule{0.16em}{0ex}}^{94}\mathrm{Mo}({4}^{+})$ and $^{98}\mathrm{Tc}({6}^{+})\ensuremath{\rightarrow}\phantom{\rule{0.16em}{0ex}}^{98}\mathrm{Ru}({4}^{+})$ were found to depend strongly on ${g}_{\mathrm{A}}$, which makes them excellent candidates for the determination of the effective value of ${g}_{\mathrm{A}}$ wit…
Second-forbidden nonunique β− decays of Na24 and Cl36 assessed by the nuclear shell model
2020
We have performed a systematic study of the $logft$ values, shape factors, and electron spectra for the second-forbidden nonunique ${\ensuremath{\beta}}^{\ensuremath{-}}$ decays of $^{24}\mathrm{Na}({4}^{+})\ensuremath{\rightarrow}^{24}\mathrm{Mg}({2}^{+})$ and $^{36}\mathrm{Cl}({2}^{+}){\ensuremath{\rightarrow}}^{36}\mathrm{Ar}({0}^{+})$ transitions under the framework of the nuclear shell model. We have performed the shell model calculations in the $sd$ model space, using more recent microscopic effective interactions such as Daejeon16, chiral N3LO, and JISP16. These interactions are derived from the no-core shell model wave functions using Okubo-Lee-Suzuki transformation. For comparison,…
Spectrum-shape method and the next-to-leading-order terms of the β-decay shape factor
2017
Effective values of the axial-vector coupling constant ${g}_{\mathrm{A}}$ have lately attracted much attention due to the prominent role of ${g}_{\mathrm{A}}$ in determining the half-lives of double $\ensuremath{\beta}$ decays, in particular their neutrinoless mode. The half-life method, i.e., comparing the calculated half-lives to the corresponding experimental ones, is the most widely used method to access the effective values of ${g}_{\mathrm{A}}$. The present paper investigates the possibilities offered by a complementary method: the spectrum-shape method (SSM). In the SSM, comparison of the shapes of the calculated and measured $\ensuremath{\beta}$ electron spectra of forbidden nonuniq…
Electron spectra in forbidden β decays and the quenching of the weak axial-vector coupling constant gA
2017
Evolution of the electron spectra with the effective value of the weak axial-vector coupling constant ${g}_{\mathrm{A}}$ was followed for 26 first-, second-, third-, fourth- and fifth-forbidden ${\ensuremath{\beta}}^{\ensuremath{-}}$ decays of odd-$A$ nuclei by calculating the involved nuclear matrix elements (NMEs) in the framework of the microscopic quasiparticle-phonon model (MQPM). The next-to-leading-order terms were included in the $\ensuremath{\beta}$-decay shape factor of the electron spectra. The spectrum shapes of third- and fourth-forbidden nonunique decays were found to depend strongly on the value of ${g}_{\mathrm{A}}$, while first- and second-forbidden decays were mostly unaff…
Forbidden nonuniqueβdecays and effective values of weak coupling constants
2016
Forbidden nonunique $\ensuremath{\beta}$ decays feature shape functions that are complicated combinations of different nuclear matrix elements and phase-space factors. Furthermore, they depend in a very nontrivial way on the values of the weak coupling constants, ${g}_{\mathrm{V}}$ for the vector part and ${g}_{\mathrm{A}}$ for the axial-vector part. In this work we include also the usually omitted second-order terms in the shape functions to see their effect on the computed decay half-lives and electron spectra ($\ensuremath{\beta}$ spectra). As examples we study the fourth-forbidden nonunique ground-state-to-ground-state ${\ensuremath{\beta}}^{\ensuremath{-}}$ decay branches of $^{113}\ma…
Double β Decay and the Axial Strength
2019
Quenching of the weak axial strength gA is discussed and relations of this quenching to the nuclear matrix elements of double beta decays are highlighted. An analysis of Gamow-Teller transitions in the mass range A = 62 − 142 is presented and its results are compared with those of many previous works. The enhancement of the axial charge is discussed for first-forbidden pseudoscalar β transitions. Higher-forbidden β transitions are introduced and their role in determining the effective value of gA is examined, in particular from the point of view of the β-decay half-lives and the shapes of electron spectra of forbidden non-unique β transitions. peerReviewed
A theoretical study of the electronic spectrum of bithiophene
1995
The electronic spectrum of bithiophene in the energy range up to 6.0 eV has been studied using multiconfigurational second order perturbation theory (CASPT2) and a basis set of ANO type, with split valence quality and including polarization functions on all heavy atoms. Calculations were performed at a planar (trans) and twisted geometry. The calculated ordering of the excited singlet states is 1Bu, 1Bu, 1Ag, 1Ag, and 1Bu with 0–0 transition energies: 3.88, 4.15, 4.40, 4.71, and 5.53 eV, respectively. The first Rydberg transition (3s) has been found at 5.27 eV. The results have been used in aiding the interpretation of the experimental spectra, and in cases where a direct comparison is poss…
Electron spectra in forbidden β decays and the quenching of the weak axial-vector coupling constant gA
2017
Evolution of the electron spectra with the effective value of the weak axial-vector coupling constant gA was followed for 26 first-, second-, third-, fourth- and fifth-forbidden β− decays of odd-A nuclei by calculating the involved nuclear matrix elements (NMEs) in the framework of the microscopic quasiparticle-phonon model (MQPM). The next-to-leading-order terms were included in the β-decay shape factor of the electron spectra. The spectrum shapes of third- and fourth-forbidden nonunique decays were found to depend strongly on the value of gA, while first- and second-forbidden decays were mostly unaffected by the tuning of gA. The gA-driven evolution of the normalized β spectra was found t…