Search results for "Elements"
showing 10 items of 799 documents
Magnetic and magneto-optical properties of nickel hexacyanoferrate/chromate thin films
2017
One of the most important challenges of modern science and technology is the quest for novel and tuneable materials, the properties of which can be widely controlled by chemical modifications or external stimuli. Simultaneously, an interest in the development of magnetic thin films also gains significant attention. In the current paper we bring together both these challenges and present a study of a new type of low-dimensional nickel hexacyanoferrate/chromate system. Thin films were obtained by the "layer by layer" deposition technique, where the ratio of Fe/Cr was controlled by the dipping sequence. The scope of this work is a comprehensive analysis of structural, spectroscopic and magneti…
Thermal optimization of the Helium-Cooled Lithium Lead breeding zone layout design regarding TBR enhancement
2017
Abstract Within the framework of EUROfusion R&D activities, CEA-Saclay has carried out an investigation of the thermal and mechanical performances of alternative designs intended to enhance the Tritium Breeding Ratio (TBR) of the Helium-Cooled Lithium Lead (HCLL) Breeding Blanket (BB) for DEMO. Neutronic calculations performed on the 2014 DEMO HCLL baseline predicted a value of TBR equal to 1.07, lower than the required value of 1.1, necessary to ensure the tritium self-sufficiency of the breeding blanket taking into account uncertainties. In order to reach the TBR target, the strategy of the steel amount reduction inside the HCLL module breeding zone (BZ) has been followed by suppressing s…
First successful ionization of Lr (Z = 103) by a surface-ionization technique.
2013
We have developed a surface ionization ion-source as part of the JAEA-ISOL (Isotope Separator On-Line) setup, which is coupled to a He/CdI2 gas-jet transport system to determine the first ionization potential of the heaviest actinide lawrencium (Lr, Z = 103). The new ion-source is an improved version of the previous source that provided good ionization efficiencies for lanthanides. An additional filament was newly installed to give better control over its operation. We report, here, on the development of the new gas-jet coupled surface ion-source and on the first successful ionization and mass separation of 27-s (256)Lr produced in the (249)Cf + (11)B reaction.
Novel Functionality of Lithium-Impregnated Titania as Nanocatalyst
2019
The present work incorporates the synthesis of a multifunctional catalyst for the transesterification of waste cooking oil (WCO) to biodiesel and recovery of rare earth elements (REEs). For this purpose, TiO2 nanoparticles and TiO2 doped with lithium ions were prepared. The influence of lithium ions on the catalytic performance of TiO2 was attained by impregnation of the different molar ratios of lithium hydroxide to bare TiO2. Then each catalyst was screened for catalytic conversion of WCO to fatty acid methyl ester (FAME) and also for REEs recovery. All synthesized materials were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Transmission electron microsc…
Modelling of the fracture toughness anisotropy in fiber reinforced concrete
2015
Steel fiber reinforced concrete is potentially very promising material with unique properties, which currently is widely used in some applications, such as floors and concrete pavements. However, lack of robust and reliable models of fiber reinforced concrete fracture limits its application as structural material. In this work a numerical model is proposed for predicting the crack growth in fiber reinforced concrete. The mixing of the steel fibers with the concrete usually creates nonuniform fibers distribution with more fibers oriented in horizontal direction, than in vertical. Simple numerical models of fiber reinforced concrete require a priori knowledge of the crack growth direction in …
Laser-induced time-resolved luminescence in analysis of rare earth elements in apatite and calcite
2021
Laser-induced time-resolved luminescence was used to study rare earth element (REE) containing natural apatite and calcite minerals. The luminescence from 400 nm to 700 nm in the minerals was analyzed with excitation ranges 210–340 nm and 405–535 nm. As an outcome, several useful excitation wavelengths to detect one or more REE from apatite and calcite are reported. The feasibility of selected excitations in e.g. avoiding the disturbance of intense Mn2+ luminescence band, results was demonstrated with a non-gated detector. peerReviewed
Monotonic solution of flow and transport problems in heterogeneous media using Delaunay unstructured triangular meshes
2013
Transport problems occurring in porous media and including convection, diffusion and chemical reactions, can be well represented by systems of Partial Differential Equations. In this paper, a numerical procedure is proposed for the fast and robust solution of flow and transport problems in 2D heterogeneous saturated media. The governing equations are spatially discretized with unstructured triangular meshes that must satisfy the Delaunay condition. The solution of the flow problem is split from the solution of the transport problem and it is obtained with an approach similar to the Mixed Hybrid Finite Elements method, that always guarantees the M-property of the resulting linear system. The…
Biased Modern Heuristics for the OCST Problem
2011
Biasing modern heuristics is an appropriate possibility in designing problem-specific and high-quality modern heuristics. If we have knowledge about a problem we can bias the design elements of modern heuristics, namely the representation and search operator, fitness function, the initial solution, or even the search strategy. This chapter presents a case study on how the performance of modern heuristics can be increased by biasing the design elements towards high-quality solutions. Results show that problem-specific and biased modern heuristics outperform standard variants and even for large problem instances high-quality solutions can be found.
A finite element formulation for large deflection of multilayered magneto-electro-elastic plates
2014
An original finite element formulation for the analysis of large deflections in magneto-electro-elastic multilayered plates is presented. The formulation is based on an equivalent single-layer model in which first order shear deformation theory with von Karman strains and quasi-static behavior for the electric and magnetic fields are assumed. To obtain the plate model, the electro-magnetic state is firstly determined and condensed to the mechanical primary variables, namely the generalized displacements. In turn, this result is used to obtain laminate effective stiffness coefficients that allow to express the plate mechanical stress resultants in terms of the generalized displacements and a…
Chronological records of metal deposition in sediments from the Strait of Sicily, central Mediterranean: assessing natural fluxes and anthropogenic a…
2010
Abstract Sediment box-cores were recovered from the Strait of Sicily along two onshore–offshore transects in water depths of 29–500 m. Samples were dated by 210 Pb and analysed for major and trace elements. Inspections of chronological profiles integrated with application of statistical algorithms to the geochemical dataset and supported by in situ hydrological observations were used to assess factors driving element distributions. Mineralogical and chemical variability of sediments offshore of the southwestern Sicily coast reflect the irregular sea floor morphology of the Adventure Bank. Anthropogenic inputs explain enrichments with respect to background values for Sb, As, Pb, and Hg, that…