Search results for "Emission spectroscopy"
showing 10 items of 180 documents
Bulk spin polarization of magnetite from spin-resolved hard x-ray photoelectron spectroscopy
2021
Physical review / B 104(4), 045129 (1-10) (2021). doi:10.1103/PhysRevB.104.045129
Magnetic dichroism in photoemission with unpolarized light.
1994
A magnetic dichroism in photoemission from ferromagnets induced by unpolarized light is observed for the first time in the valence band region as well as for surface states. The study was carried out with magnetized Fe(110), Co(0001), and Gd(0001) films grown epitaxially on W(110). This phenomenon leads to an intensity asymmetry for opposite directions of the sample magnetization. It can be easily used for a routine laboratory diagnostic of magnetic behavior. A simple theoretical interpretation of the phenomenon based on the atomic model is given.
Production of hydrogen negative ions in an ECR volume source: balance between vibrational excitation and ionization
2018
International audience; The operation of an ECR-driven (2.45 GHz) hydrogen negative ion source is studied. Electron densities and temperatures are investigated with electrostatic probes and negative ion densities are measured with laser photodetachment. Vacuum ultraviolet irradiance measurements are focused on molecular transitions to the ground state while high-resolution visible emission spectroscopy is used to study the transitions between excited states for both molecules and atoms. The standalone operation of the source is found to be more efficient in higher pressures (12 mTorr) where negative ion densities are as high as 4×109 cm−3. Further investigation on the operation of the sou…
Soft X-ray emission spectroscopy used for the characterization of a-C and CNx thin films
2015
Abstract We present the results of a soft X-ray emission spectroscopy study of a-C and CNx films on a Si(100) substrate. Also for the characterization of the homogeneity in depth of these films electron energy loss spectroscopy measurements with localization better than 4 nm were carried out. In case of CNx films the highest diamond-like modification occurs in the region close to the Si(100) substrate. The film density decreases with increasing distance from the substrate and becomes almost constant in range of thicknesses more than ~ 2 nm.
Thermal and infrared spectroscopic characterization of historical mortars
1998
Abstract The characterization of historical mortars was performed by thermal analysis (TG-DTG), simultaneous infrared spectroscopy (TG-FTIR) and inductively coupled plasma atomic emission spectrometry (ICP-AES). The samples were taken from St. John Church (Tartu, Estonia), built in the 13th–14th centuries. The analyses are important for the restoration of the church. In reality, mortar is a very difficult system, the lime is accompanied with different hydraulic components. TG-DTG analysis and FTIR methods can be used to identify various components of mortar and to observe the reactions associated with the controlled heating at 25–900°C in dynamic air and nitrogen atmosphere. The elemental c…
ECRIS plasma spectroscopy with a high resolution spectrometer
2020
Electron Cyclotron Resonance Ion Source (ECRIS) plasmas contain high-energy electrons and highly charged ions implying that only noninvasive methods such as optical emission spectroscopy are reliable in their characterization. A high-resolution spectrometer (10 pm FWHM at 632 nm) enabling the detection of weak emission lines has been developed at University of Jyväskylä, Department of Physics (JYFL) for this purpose. Diagnostics results probing the densities of ions, neutral atoms, and the temperature of the cold electron population in the JYFL 14 GHz ECRIS are described. For example, it has been observed that the cold electron temperature drops from 40 eV to 20 eV when the extraction volta…
The effect of microwave power on the Ar9+ and Ar13+ optical emission intensities and ion beam currents in ECRIS
2018
The production of Ar9+ and Ar13+ ions in an ECRIS plasma and the efficiency of the ion beam extraction and transport of the resulting Ar9+ and Ar13+ ion beams have been studied with the JYFL 14 GHz ECRIS by using optical emission spectroscopy and measurement of the m/q analyzed beam currents. The relative changes in both the optical emission and the ion beam current in CW mode as function of microwave power and in amplitude modulation (AM) operation mode are reported. The results indicate a discrepancy between the parametric dependence of high charge state ion densities in the core plasma and their extracted beam currents. The observation implies that in CW mode the ion currents could be li…
Detection of deuterium retention by LIBS at different background pressures
2017
ITER plans foresee the quantitative diagnostics of fuel retention in reactor walls at near-atmospheric pressures. Using laser induced breakdown spectroscopy (LIBS) for this purpose assumes a reliable resolving of Balmer α-lines of hydrogen isotopes in spectra of plasma produced by focused laser radiation onto the target surface. To develop LIBS for quantitative diagnostics of fuel retention during the maintenance breaks of ITER, the effect of background gas pressure on the laser-induced plasma characteristics has been studied. The background pressure limits the expansion rate of plasma and as a result it leads to higher plasma concentrations. At the same time the limiting factor of the reso…
Properties of the quaternary half-metal-type Heusler alloyCo2Mn1−xFexSi
2006
This paper reports on the bulk properties of the quaternary Heusler alloy Co2Mn1�xFexSi with the Fe concentration x =0,1/2,1. All samples, which were prepared by arc melting, exhibit L21 long-range order over the complete range of Fe concentration. The structural and magnetic properties of the Co2Mn1�xFexSi Heusler alloys were investigated by means of x-ray diffraction, high- and low-temperature magnetometry, Mossbauer spectroscopy, and differential scanning calorimetry. The electronic structure was explored by means of highenergy photoemission spectroscopy at about 8 keV photon energy. This ensures true bulk sensitivity of the measurements. The magnetization of the Fe-doped Heusler alloys …
Interface properties of magnetic tunnel junctionLa0.7Sr0.3MnO3/SrTiO3superlattices studied by standing-wave excited photoemission spectroscopy
2010
The chemical and electronic-structure profiles of magnetic tunnel junction (MTJ) La0.7Sr0.3MnO3/SrTiO3 (LSMO/STO) superlattices have been quantitatively determined via soft and hard x-ray standing-wave excited photoemission, x-ray absorption and x-ray reflectivity, in conjunction with x-ray optical and core-hole multiplet theoretical modeling. Epitaxial superlattice samples consisting of 48 and 120 bilayers of LSMO and STO, each nominally four unit cells thick, and still exhibiting LSMO ferromagnetism, were studied. By varying the incidence angle around the superlattice Bragg condition, the standing wave was moved vertically through the interfaces. By comparing experiment to x-ray optical c…