Search results for "Energy engineering"
showing 10 items of 1099 documents
Heat and mass transfer analysis in single cell of PEFC using different PEM and GDL at higher temperature
2019
Abstract According to the H2 and fuel cell road map in Japan, the target operating temperature of polymer electrolyte fuel cell (PEFC) should be 90 °C from 2020 to 2025. In this study, the impact of polymer electrolyte membrane (PEM) and gas diffusion layer (GDL)'s thickness on heat and mass transfer characteristics as well as power generation performance of PEFC is investigated at operating temperature of 90 °C. The in-plane temperature distributions on anode and cathode separator are also measured using thermograph. As a result, it is observed that the increase in power from 1 W to 5 W at the current density of 0.80 A/cm2 as well as even temperature distribution within 1 °C can be obtaine…
Molecular design of the diketopyrrolopyrrole-based dyes with varied donor units for efficient dye-sensitized solar cells
2014
Abstract Three types of novel diketopyrrolopyrrole-based organic dyes ( Type 1 – 3 ) with phenyl unit as an additional π -bridge and triphenylamine or phenothiazine as the donors are designed and synthesized for dye-sensitized solar cells (DSSCs). Type 1 dyes incorporating the donor segment directly to the diketopyrrolopyrrole core lead to a better electron communication between the donor and acceptor, allowing an efficient charge transfer process. Type 2 and Type 3 dyes with a phenyl unit between the donor and diketopyrrolopyrrole unit show lower delocalization of the excited state. Compared with Type 3 dyes, Type 1 dyes exhibit higher conjugated skeleton co planarity and shorter electron …
Graphene in lithium ion battery cathode materials: A review
2013
Abstract Graphene is a relatively new and promising material, displaying a unique array of physical and chemical properties. Although considered to be especially promising for the use in energy storage applications, graphene has only recently been implemented as an electron conducting additive for lithium ion battery cathode materials. In current studies graphene is found to significantly improve cathode electrochemical performance. As the charge capacity, rate capability and cyclability of lithium ion batteries are still in ever-remaining need of improvement, this article examines the prospects of graphene implementation into lithium ion battery cathodes to meet such demands. The existing …
Nanoconfined mixed Li and Mg borohydrides as materials for solid state hydrogen storage
2012
Abstract Several mixtures of LiBH4 and Mg(BH4)2 borohydrides in different stoichiometric ratios (1:0, 2:1, 1:1, 1:2, 0:1), prepared by high energy ball milling, have been investigated with X-ray powder diffraction and thermal programmed desorption (TPD) volumetric analysis to test the dehydrogenation kinetics in correlation with the physical mixture composition. Afterwards mixed and unmixed borohydrides were dispersed on high specific surface area ball milled graphite by means of the solvent infiltration technique. BET and statistical thickness methods were used to characterize the support surface properties, and SEM micrographs gave a better understanding of the preparation techniques. It …
Partial Discharges Diagnostics Along Medium Voltage Cables
2018
In the last years different partial discharge (PD) measuring techniques have been developed because PD diagnostic is the most widely tool to evaluate the insulation condition of a power cable. Recently non-conventional methods and sensors have been used in order to reach improved results in PD measurements. New sensors based on wireless technology were developed in order to simplify PD measurement especially for on-line, on-site diagnosis. The purpose of this work is to perform measurements that allow to study the variation of pulses when they travel along a medium voltage cable and characterize a new smart PD source detector and locator, named Wings sensor. For these purposes, internal PD …
Vacuum-Deposited 2D/3D Perovskite Heterojunctions
2019
Low-dimensional (quasi-) 2D perovskites are being extensively studied in order to enhance the stability and the open-circuit voltage of perovskite solar cells. Up to now, thin 2D perovskite layers on the surface and/or at the grain boundaries of 3D perovskites have been deposited solely by solution processing, leading to unavoidable intermixing between the two phases. In this work, we report the fabrication of 2D/3D/2D perovskite heterostructures by dual-source vacuum deposition, with the aim of studying the interaction between the 3D and 2D phases as well as the charge transport properties of 2D perovskites in neat 2D/3D interfaces. Unlike what is normally observed in solution-processed 3D…
Non-linear inductor modelling for a DC/DC buck converter
2017
The paper is focused on the modelling of an inductor to exploit its non-linear behaviour in the roll-off region when it is employed in a DC/DC converter. The model is set up on the basis of experimental data measured in operating conditions, which are fitted to a polynomial curve describing the inductance variations. The analysis of the buck converter, performed by including the proposed model, is validated by experimental tests.
Assigning ionic properties in perovskite solar cells; a unifying transient simulation/experimental study
2021
Kinetic modelling has proven to be essential to understand the time and spatial dependence of charge carriers in solar cells. Traditional drift–diffusion simulations have generally been employed to describe static steady-state conditions, whereas recently the transient counterpart has been able to reveal more detailed information regarding carrier kinetics. In addition to customary electron and hole dynamics, perovskite materials are known to also be strongly affected by the displacement of lattice vacancies, charged atoms or even entire molecules. Such ionic motion transpires on vastly different time scales compared to free charges and are generally not straightforward to simultaneously ac…
Photovoltaic facade: Comparison of actual technologies
2017
This article aims to establish the economic contribution of a photovoltaic system placed on a façade of a building, replacing traditional elements such as windows and glass-cement walls with active elements. The aim is to compare the behavior of next-generation systems, which favor architectonical integration, with traditional ones. Two novel systems have been taken into account: a dye sensitized solar cell (DSSC) and blue and grey thin film silicon panels. Different generation systems have been tested and compared in terms of efficiency and fill factor.
A Test Circuit for GaN HEMTs Dynamic Ron Characterization in Power Electronics Applications
2019
Wide bandgap devices such as GaN HEMTs are a promising technology in the field of Power Electronics. Due to the physical properties of the Gallium nitride and the device design, they can outperform their Silicon counterparts for the design of highly efficient power switching converters. However, its design should face certain effects that can diminish its performance. One of such effect is the degradation mechanism known as dynamic onresistance (dynamic RON,), being its mitigation one of the main objectives in the design of the device. In this paper, a circuit is proposed for assessing if this effect is present in GaN transistors in power electronics applications. The circuit allows testing…