Search results for "Entropy production"
showing 10 items of 24 documents
Polymer solutions: Equilibrium clusters versus shear clusters
2021
Abstract Polymer solutions are inhomogeneous on mesoscopic scales as a result of chemical bonds linking their monomeric units. This situation leads to polymer clusters within which the polymer concentration c cluster is only a small fraction of the overall concentration c. The ratio c/ c cluster (overlap parameters Ω ) quantifies the number of clusters that need to overlap to yield c. Equilibrium clusters (minimization of Gibbs energy) and shear clusters (minimization of entropy production) differ fundamentally where Ω equil ≥ Ω shear . Only in the vicinity of the glass transition temperature and at high concentration the opposite is the case. Experimental information on Ω equil as a functi…
Transport properties of 2F = F2 in a temperature gradient as studied by molecular dynamics simulations
2007
International audience; We calculate transport properties of a reacting mixture of F and F2 from results of nonequilibrium molecular dynamics simulations. The reaction investigated is controlled by thermal diffusion and is close to local chemical equilibrium. The simulations show that a formulation of the transport problem in terms of classical non-equilibrium thermodynamics theory is sound. The chemical reaction has a large effect on the magnitude and temperature dependence of the thermal conductivity and the interdiffusion coefficient. The increase in the thermal conductivity in the presence of the chemical reaction, can be understood as a response to an imposed temperature gradient, whic…
A Theoretical Model to Describe the Motion of Aerosol Particles Due to the Combined Action of Inertia, Brownian Diffusion and Phoretic and Electric F…
1978
Abstract General principles of non-equilibrium thermodynamics are used to formulate a model which describes the motion of aerosol particles affected simultaneously by Brownian diffusion, inertial impaction, electric forces and phoretic forces. The theory presented applies to an ideal mixture consisting of dry air, water vapor and aerosol particles where temperature, pressure as well as vapor and particle concentration inhomogeneities are to be considered. In addition, the system is subjected to the earth's gravity, to an external electric field as well as to a Coulomb force due to a charged collecting water drop. The basic model assumptions are as follows: 1) the diffusive kinetic energy of…
Thermodynamic Approach to the Self-Diffusiophoresis of Colloidal Janus Particles
2019
Most available theoretical predictions for the self-diffusiophoretic motion of colloidal particles are based on the hydrodynamic thin boundary layer approximation in combination with a solvent body force due to a self-generated local solute gradient. This gradient is enforced through specifying boundary conditions, typically without accounting for the thermodynamic cost to maintain the gradient. Here, we present an alternative thermodynamic approach that exploits a direct link between dynamics and entropy production: the local detailed balance condition. We study two cases: First, we revisit self-propulsion in a demixing binary solvent. At variance with a slip velocity, we find that propuls…
Entropy signature of the running cosmological constant
2007
Renormalization group (RG) improved cosmologies based upon a RG trajectory of Quantum Einstein Gravity (QEG) with realistic parameter values are investigated using a system of cosmological evolution equations which allows for an unrestricted energy exchange between the vacuum and the matter sector. It is demonstrated that the scale dependence of the gravitational parameters, the cosmological constant in particular, leads to an entropy production in the matter system. The picture emerges that the Universe started out from a state of vanishing entropy, and that the radiation entropy observed today is essentially due to the coarse graining (RG flow) in the quantum gravity sector which is relat…
Centrality dependence of multiplicity, transverse energy, and elliptic flow from hydrodynamics
2001
The centrality dependence of the charged multiplicity, transverse energy, and elliptic flow coefficient is studied in a hydrodynamic model, using a variety of different initializations which model the initial energy or entropy production process as a hard or soft process, respectively. While the charged multiplicity depends strongly on the chosen initialization, the p_t-integrated elliptic flow for charged particles as a function of charged particle multiplicity and the p_t-differential elliptic flow for charged particles in minimum bias events turn out to be almost independent of the initial energy density profile.
Entropy development in ideal relativistic fluid dynamics with the Bag Model equation of state
2010
We consider an idealized situation where the Quark-Gluon Plasma (QGP) is described by a perfect, (3 + 1)-dimensional fluid dynamic model starting from an initial state and expanding until a final state where freeze-out and/or hadronization takes place. We study the entropy production with attention to effects of (i) numerical viscosity, (ii) late stages of flow where the Bag Constant and the partonic pressure are becoming similar, (iii) and the consequences of final freeze-out and constituent quark matter formation.
A full picture of large lepton number asymmetries of the Universe
2017
A large lepton number asymmetry of (0.1−1) at present Universe might not only be allowed but also necessary for consistency among cosmological data. We show that, if a sizeable lepton number asymmetry were produced before the electroweak phase transition, the requirement for not producing too much baryon number asymmetry through sphalerons processes, forces the high scale lepton number asymmetry to be larger than about 03. Therefore a mild entropy release causing (10-100) suppression of pre-existing particle density should take place, when the background temperature of the Universe is around T = (10−2-102) GeV for a large but experimentally consistent asymmetry to be present today. We also …
Thermodynamics based on the principle of least abbreviated action: Entropy production in a network of coupled oscillators
2006
We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by their evolution in time when the system is nonintegrable. We propose dynamical definitions for the equilibrium temperature and entropy as well as an expression for the nonequilibrium entropy valid for isolated systems with many degrees of freedom. This entropy is shown to increase in the relaxation to equilibrium of macroscopic systems with short-range interactions, which constitutes a dynamical justification of the Second Law of Thermodynamics. Several e…
Fluctuation theorems for non-Markovian quantum processes
2013
Exploiting previous results on Markovian dynamics and fluctuation theorems, we study the consequences of memory effects on single realizations of nonequilibrium processes within an open system approach. The entropy production along single trajectories for forward and backward processes is obtained with the help of a recently proposed classical-like non-Markovian stochastic unravelling, which is demonstrated to lead to a correction of the standard entropic fluctuation theorem. This correction is interpreted as resulting from the interplay between the information extracted from the system through measurements and the flow of information from the environment to the open system: Due to memory e…