Search results for "Entropy"

EDA: EXAFS data-analysis software package

2021

The EXAFS data-analysis software package EDA consists of a suite of programs running under a Windows operating system environment that is designed to perform all steps of conventional EXAFS data analysis such as extraction of the XANES/EXAFS parts of the X-ray absorption coefficient, Fourier filtering and EXAFS fitting using the Gaussian and cumulant models. The package also includes two advanced approaches which allow the reconstruction of the radial distribution function (RDF) from EXAFS based on the regularization-like method and the calculation of configuration-averaged EXAFS using a set of atomic configurations obtained from molecular-dynamics or Monte Carlo simulations.---- / / / ----…

VAPORIZATION CHARACTERISTICS OF ETHANOL AND 1-PROPANOL DROPLETS AT HIGH TEMPERATURES

2012

International audience; A detailed description of the vaporization of an isolated droplet has been carried out in this experimental study aimed at investigating ethanol and another aliphatic alcohol, 1-propanol. The characterization of the vaporization phenomenon is necessary for this liquid fuel to develop efficient design of injection systems for propulsion and power generation. Particularly, the vaporization rates and their dependency on temperature, important features for modeling and design, are explored for both ethanol and 1-propanol at intermediate to high temperatures. The experimental setup consists of a pressure chamber in which the furnace, the droplet formation, the droplet sup…

2018

An analytical model describing the thermoelectric potential production in magnetic nanofluids (dispersions of magnetic and charged colloidal particles in liquid media) is presented. The two major entropy sources, the thermogalvanic and thermodiffusion processes are considered. The thermodiffusion term is described in terms of three physical parameters; the diffusion coefficient, the Eastman entropy of transfer and the electrophoretic charge number of colloidal particles, which all depend on the particle concentration and the applied magnetic field strength and direction. The results are combined with well-known formulation of thermoelectric potential in thermogalvanic cells and compared to …

Fragmenting gadolinium: Mononuclear polyoxometalate-based magnetic coolers for ultra-low temperatures

2012

The polyoxometalate clusters with formula [Gd(W 5O 18) 2] 9- and [Gd(P 5W 30O 110)] 12- each carry a single magnetic ion of gadolinium, which is the most widespread element among magnetic refrigerant materials. In an adiabatic demagnetization, the lowest attainable temperature is limited by the presence of magnetic interactions that bring about magnetic order below a critical temperature. We demonstrate that this limitation can be overcome by chemically engineering the molecules in such a way to effectively screen all magnetic interactions, suggesting their use as ultra-low-temperature coolers. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Thermodynamics of Phase Behavior in PEO/P(EO-b-DMS) Homopolymer and Block Co-Oligomer Mixtures under Pressure

2003

The cloud-point temperatures (T-cl's) of poly(ethylene oxide) (PEO) and poly(ethylene oxide)-block-polydimethylsiloxane (P(EO-b-DMS)) homopolymer and block-oligomer mixtures were determined by turbidity measurements over a range of temperatures (105 to 130degrees), pressures (1 to 800 bar), and compositions (10-40 wt.-% PEO). The system phase separates upon cooling and T-cl was found to decrease with an increase in pressure for a constant composition. In the absence of special effects, this finding indicates negative excess volumes. Special attention was paid to the demixing temperatures as a function of the pressure for the different polymer mixtures and the plots in the T-phi plane (where…

Latent Heat of Spontaneous-Curvature-Induced Lamellar-to-Microemulsion Transitions

1995

Using differential scanning microcalorimetry we examine the latent heat of the temperature-induced structural transition from a lamellar to a microemulsion phase in a H2O/n-octane/C12E5 (n-dodecyl pentanethyleneglycol ether) system. The associated latent heat increases strongly with surfactant concentration yielding heat changes up to 1kB T per surfactant molecule. These large values are quantitatively described by an interfacial model which takes into account the temperature dependence of the spontaneous curvature. The model explains our data points without considering contributions to the free energy by thermal fluctuations, entropy of mixing, undulations of the lamellae and renormalizati…

Depletion-induced percolation in networks of nanorods.

2006

Above a certain density threshold, suspensions of rod-like colloidal particles form system-spanning networks. Using Monte Carlo simulations, we investigate how the depletion forces caused by spherical particles affect these networks in isotropic suspensions of rods. Although the depletion forces are strongly anisotropic and favor alignment of the rods, the percolation threshold of the rods decreases significantly. The relative size of the effect increases with the aspect ratio of the rods. The structural changes induced in the suspension by the depletant are characterized in detail and the system is compared to an ideal fluid of freely interpenetrable rods.

Load match optimisation of a residential building case study: A cross-entropy based electricity storage sizing algorithm

2015

Abstract The EU EPBD recast regulation marked the application of the net zero energy building (Net ZEB) concept in all fields of building construction in Europe as a building able to generate as much energy as it consumes over a selected time frame. A more detailed insight is however needed, as even if a building achieves a long-term energy balance between energy generated and consumed, smaller time scales must also be considered. For example, from the utility’s point of view, if a Net ZEB is a heavy consumer in the winter, it will appear to be quite similar to a conventional building, requiring the use of additional generation. The increase in the generation-load match means reducing the s…

Cross-entropy-based adaptive optimization of simulation parameters for Markovian-driven service systems

2005

Abstract Markov fluid models represent a general description of the process of service request arrivals to service systems. The solution of performance analysis problems incorporating them often calls for a simulation approach, for which a reference methodology is Importance Sampling. However, in this case the appropriate choice of the biasing conditions is a problem in itself. In this paper an iterative method based on the cross-entropy is proposed for this choice. The equations are given that allow to derive the biasing conditions from the simulation itself. The application of the proposed method to three different sample cases, referring to one transient scenario (finite time horizon and…

Hybridizing the cross-entropy method: An application to the max-cut problem

2009

Cross-entropy has been recently proposed as a heuristic method for solving combinatorial optimization problems. We briefly review this methodology and then suggest a hybrid version with the goal of improving its performance. In the context of the well-known max-cut problem, we compare an implementation of the original cross-entropy method with our proposed version. The suggested changes are not particular to the max-cut problem and could be considered for future applications to other combinatorial optimization problems.