Search results for "Environmental Monitoring"
showing 10 items of 609 documents
Determination of pharmaceutical residues and assessment of their removal efficiency at the Daugavgriva municipal wastewater treatment plant in Riga, …
2017
Pharmaceutical products (PPs) belong to emerging contaminants that may accumulate along with other chemical pollutants in wastewaters (WWs) entering industrial and/or urban wastewater treatment plants (WWTPs). In the present study, the technique of ultra-high-performance liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (Orbitrap-HRMS) was applied for the analysis of 24 multi-class PPs in WW samples collected at different technological stages of Daugavgriva WWTP located in Riga, Latvia. Caffeine and acetaminophen levels in the range of 7,570–11,403 ng/L and 810–1,883 ng/L, respectively, were the predominant compounds among 19 PPs determined in the WW. The results i…
The influence of rainfall time resolution for urban water quality modelling
2010
The objective of this paper is the definition of a methodology to evaluate the impact of the temporal resolution of rainfall measurements in urban drainage modelling applications. More specifically the effect of the temporal resolution on urban water quality modelling is detected analysing the uncertainty of the response of rainfall–runoff modelling. Analyses have been carried out using historical rainfall–discharge data collected for the Fossolo catchment (Bologna, Italy). According to the methodology, the historical rainfall data are taken as a reference, and resampled data have been obtained through a rescaling procedure with variable temporal windows. The shape comparison between ‘true’…
Occurrence and removal efficiency of pesticides in sewage treatment plants of four Mediterranean River Basins.
2013
Removal of contaminants in the sewage treatment plants (STPs) can be incomplete causing their release to the environment. In this paper, the results of an extensive survey on more than 40 pesticides carried out in 2010 and 2011 in 16 STPs of Ebro, Guadalquivir, Jucar and Llobregat Rivers (Spain) are presented. In 2010, of 43 analytes screened, 29 were detected in influent and 28 in effluent samples, meanwhile in 2011, of 50 analytes, 33 and 34 were detected, respectively. Pesticides were in the range of 0.33 ng L(-1) (terbumeton, 2011)-2526.05 ng L(-1) (diuron, 2010) for influent and 0.25 ng L(-1) (terbumeton, 2011)-2821.12 ng L(-1) (carbendazim, 2011) for effluent. Regarding the sludge sam…
The use of blue tit eggs as a biomonitoring tool for organohalogenated pollutants in the European environment
2010
In the present study, large scale geographical variation in the occurrence of organohalogenated pollutants (OHPs) was investigated throughout Europe using eggs of a terrestrial resident passerine species, the blue tit (Cyanistes caeruleus). Blue tit eggs from 10 sampling locations, involving suburban, rural and remote areas, in 7 European countries were collected and analysed. Sum polychlorinated biphenyl (PCB) levels ranged from 150 ng/g lipid weight (lw) to 2003 ng/g lw. Sum polybrominated diphenyl ethers (PBDEs) ranged from 3.95 ng/g lw to 114 ng/g lw. As expected, PCB and PBDE concentrations were significantly higher in the sampled suburban locations compared to the rural and remote loc…
Biomagnification of organohalogens in Atlantic salmon (Salmo salar) from its main prey species in three areas of the Baltic Sea
2012
Abstract Factors affecting the biomagnification of organohalogens in Baltic salmon from sprat, herring and three-spined stickleback were assessed in three feeding areas. Second sea-year salmon contained (in fresh weight of whole fish) 79–250 ng g− 1 polychlorinated biphenyls (ΣPCB), 0.9–2.7 pg g− 1 dibenzo-p-dioxins (ΣPCDD), 8–19 pg g− 1 dibenzofurans (ΣPCDF), 96–246 pg g− 1 coplanar PCBs, 2.4–3.6 ng g− 1 polybrominated diphenylethers (ΣPBDE), and 39–136 ng g− 1 Σindicator PCB6. The EU limits for WHO toxic equivalent concentrations in fish feed were already exceeded in one-year-old sprat and herring and were exceeded many-fold in older age groups. The differences in the biomagnification rat…
Monitoring WWTP performance using size-exclusion chromatography with simultaneous UV and fluorescence detection to track recalcitrant wastewater frac…
2018
Abstract A trial monitoring of a typical full-scale municipal WWTP in Central Finland was aimed to explore applicability of high performance liquid chromatography – size exclusion chromatography (HPSEC) with simultaneous UV and fluorescence detection as a tool for advanced routine monitoring of wastewater treatment. High, intermediate, and low molecular weight (MW) fractions of untreated wastewater (influent) and treated wastewater (secondary effluent) were characterized in terms of UV absorbance at 254 nm (UVA254) and specific fluorescence representing tyrosine-like, tryptophan-like, and humic/fulvic-like compounds. The activated sludge treatment removed 97 ± 1% of BOD, 93 ± 2% of COD, 71 …
Ecological risk assessment of pesticides in urban streams of the Brazilian Amazon
2022
Abstract The use of pesticides in households and peri-urban areas of the Amazon has increased notably during the last years. Yet, the presence of these contaminants in Amazonian freshwater ecosystems remains unexplored. Here, we assessed the exposure to 18 pesticides and 5 transformation products in the Amazon River and in the urban streams of Manaus, Santarem, Macapa, and Belem (Brazil). Pesticide concentrations were analyzed by liquid and gas chromatography methods. Ecological risks were assessed following a two-tiered approach. First, hazard quotients and an overall hazard index were calculated using toxicity data for standard test species of primary producers, invertebrates, and fish. S…
Polychlorinated organic compounds in the Arctic cod liver: trends and profiles
2000
Polychlorinated organic compounds (POCs) have been measured in Arctic cod liver from Vestertana Fjord for a period of 1987-1998. Significant decrease was observed for DDD (p = 0.043), alpha-HCH (p = 0.001), and gamma-HCH (lindane; p = 0.001). Contents of DDE, 2,3,7,8-tetrachlorodibenzofuran, PCBs, chlordanes, chloronaphthalenes, hexachlorobenzene and polychlorodiphenyl ethers had no significant trend. Contents of three hexa- and two heptachlorodibenzofurans and octachlorodibenzofuran increased slightly from 1987 to 1994, but then at very high rate from 1994 to 1998. Trends of HCHs, profiles of PCBs and levels of chlordanes are in accordance with atmospheric long range transport. The hexa-, …
Patterns of presence and concentration of pesticides in fish and waters of the Júcar River (Eastern Spain).
2013
The Jucar River, in a typical Mediterranean Basin, is expected to suffer a decline in water quality and quantity as a consequence of the climate change. This study is focused on the presence and distribution of pesticides in water and fish, using the first extensive optimization and application of the QuEChERS method to determine pesticides in freshwater fish. Majority pesticides in water - in terms of presence and concentration - were dichlofenthion, chlorfenvinphos, imazalil, pyriproxyfen and prochloraz (associated with a frequent use in farming activities), as well as buprofezin, chlorpyriphos and hexythiazox. In fish, the main compounds were azinphos-ethyl, chlorpyriphos, diazinon, dime…
Transfer of hexazinone and glyphosate through undisturbed soil columns in soils under Christmas tree cultivation.
2004
Abstract Field studies monitoring pesticide pollution in the Morvan region (France) have revealed surface water contamination by some herbicides. The purpose of this study was to investigate in greater detail the transport of two herbicides, used in Christmas tree production in the Morvan, under controlled laboratory conditions. Thus, the leaching of hexazinone (3-cyclohexyl-6-dimethyl-amino-1-methyl-1,3,5-triazine-2,4 (1H,3H) dione) and glyphosate ( N -(phosphono-methyl-glycine)) through structured soil columns was studied using one loamy sand and two sandy loams from sites currently under Christmas tree cultivation in the Morvan. The three soils were cultivated sandy brunisol [Sound refer…