Search results for "Equilibrium"
showing 10 items of 1021 documents
Incentive Mechanism for Edge-Computing-Based Blockchain
2020
Blockchain has been gradually applied to different Internet of Things (IoT) platforms. As the efficiency of the blockchain mainly depends on the network computing capability, how to make sure the acquisition of the computational resources and participation of the devices would be the driving force. In this work, we focus on investigating incentive mechanism for rational miners to purchase the computational resources. A edge computing-based blockchain network is considered, where the edge service provider (ESP) can provide computational resources for the miners. Accordingly, we formulate a two-stage Stackelberg game between the miners and ESP. The aim is to investigate Stackelberg equilibriu…
An Original Approach to Active Climate Control Based on Equilibrium Moisture Content (EMC) as Set Point in a Middle-Age Building in Palermo, Italy
2019
In the frame of a more sustainable approach to climate control, a long term strategy has been developed and is under advanced phase of implementation by technical staff of the University of Palermo in an important building, Palazzo Steri, owned by the University. The monumental room under climate control, the Sala dei Baroni (also known as Sala Magna), has a precious wooden ceiling where the previously loadbearing elements are covered with wooden painted panels. Many of them, painted in the fourteenth c, underwent important restorations in the past due to climate related damage (cracks, warpings, paint layer delamination) and biological infestations. The room is currently undergoing an impo…
On Unstructured File Sharing Networks
2007
We study the interaction among users of unstructured file sharing applications, who compete for available network resources (link bandwidth or capacity) by opening multiple connections on multiple paths so as to accelerate data transfer. We model this interaction with an unstructured file sharing game. Users are players and their strategies are the numbers of sessions on available paths. We consider a general bandwidth sharing framework proposed by Kelly [1] and Mo and Walrand [2], with TCP as a special case. Furthermore, we incorporate the Tit-for-Tat strategy (adopted by BitTorrent [3] networks) into the unstructured file sharing game to model the competition in which a connection can be …
A Bayesian Learning Automata-Based Distributed Channel Selection Scheme for Cognitive Radio Networks
2014
We consider a scenario where multiple Secondary Users SUs operate within a Cognitive Radio Network CRN which involves a set of channels, where each channel is associated with a Primary User PU. We investigate two channel access strategies for SU transmissions. In the first strategy, the SUs will send a packet directly without operating Carrier Sensing Medium Access/Collision Avoidance CSMA/CA whenever a PU is absent in the selected channel. In the second strategy, the SUs implement CSMA/CA to further reduce the probability of collisions among co-channel SUs. For each strategy, the channel selection problem is formulated and demonstrated to be a so-called "Potential" game, and a Bayesian Lea…
Influence of Anion and Cation Structure of Ionic Liquids on Carboxylic Acids Extraction
2019
A recently proposed new mechanism and a model of reactive extraction of carboxylic acids by hydrophobic ionic liquids (ILs) was tested on five systems from published as well as from new equilibrium data on liquid-liquid extraction of butyric and lactic acids (BA and LA) from aqueous solutions. Two phosphonium and one ammonium ILs were used. The model describes experimental data for all systems with a good fit. The mechanism of acid extraction by ILs is very similar for all tested systems. This indicates a more general validity of the developed model. The model allows deeper understanding of regularities in carboxylic acid extraction by hydrophobic ILs. Stability constants of the first acid-…
Rh(I) Coordination Chemistry of Chiral α-Aminophosphine(η6-arene)chromium Tricarbonyl Ligands
2003
The diastereoselective addition of Ph(2)PH to the chiral ortho-substituted eta(6)-benzaldimine complexes (eta(6)-o-X-C(6)H(4)CH=NAr)Cr(CO)(3) (1, X = MeO, Ar = p-C(6)H(4)OMe; 2, X = Cl, Ar = Ph) leads to the formation of the corresponding chiral aminophosphines (alpha-P,N) Ph(2)P-CH(Ar(1))-NHAr(2) (3, Ar(1) = o-C(6)H(4)(OCH(3))[Cr(CO)(3)], Ar(2) = p-C(6)H(4)OCH(3); 4, Ar(1) = o-C(6)H(4)Cl[Cr(CO)(3)], Ar(2) = Ph) in equilibrium with the starting materials. The uncomplexed benzaldimine (o-ClC(6)H(4)CH=NPh), 2', analogously produces an equilibrium amount of the corresponding aminophosphine Ph(2)P-CH(Ar(1))-NHAr(2) (4', Ar(1) = o-C(6)H(4)Cl, Ar(2) = Ph). Depending on the equilibrium constant, t…
Compounds of molybdenum(VI) with aspartic acid: A spectrophotometric and potentiometric study of the formation and interconversion equilibria in aque…
1990
Addition of Na2MoO4 to an excess of aspartic acid (AspH2) can produce any of four different complexes depending on the pH, namely [MoO3(Asp)]2−, [Mo2O5(Asp)2]2−, [Mo2O4(OH)(Asp)2]− and [Mo2O4(Asp)2]. The ranges of formation of these species with pH, the number of equivalents of acid necessary for their formation, and their stoichiometries, condensation degrees and stability constants, have been calculated by potentiometric and spectrophotometric techniques. The aspartic acid acts as a tridentate ligand in all cases.
Thermodynamic Evidence of Cyclodextrin−Micelle Interactions
2002
The enthalpy of transfer (ΔHt) of hydroxypropyl-α-cyclodextrin (HP-α-CD), hydroxypropyl-β-cyclodextrin (HP-β-CD), and β-cyclodextrin (β-CD) from water to the aqueous C6F13CO2Na and C7F15CO2Na solutions were determined in the pre- and post-micellar regions. The behavior of the macrocycles is system specific. Generally, the magnitude of the enthalpy is influenced by several factors: (1) the alkyl chain length of the surfactant, (2) the cyclodextrin cavity and its alkylation, (3) the interactions between the free cyclodextrin and the free surfactant, (4) the host−guest equilibrium constant, (5) the host/guest stoichiometry, and (6) the micelle-cyclodextrin (free and/or complexed) interactions…
Adsorption of triblock copolymers and their homopolymers at laponite clay/solution interface. Role played by the copolymer nature
2009
The adsorption thermodynamics of copolymers, based on ethylene oxide (EO) and propylene oxide ( PO) units, at the laponite (RD) clay/liquid interface was determined at 298 K. The copolymer nature was tuned at molecular level by changing the hydrophilicity, the architecture and the molecular weight (Mw) keeping constant the EO/PO ratio. Polyethylene (PEGs) and polypropylene (PPGs) glycols with varying Mw and their mixture were also investigated to discriminate the role of the EO and the PO segments in the adsorption process. Enthalpies of transfer of RD, at fixed concentration, from water to the aqueous macromolecule solutions as functions of the macromolecule molality were determined. They …
Stability−Charge and Stability−Structure Relationships in the Binding of Dicarboxylic Ligands by Open-Chain Polyammonium Cations
2000
The stability of complexes formed by 5 dicarboxylic ligands with 11 open-chain polyammonium cations (40 systems) was studied potentiometrically, in aqueous solution, at 25 °C. In all the systems ALHr species (A = amine, L = dicarboxylic ligand, r = 1 ... n; diamines n = 3, triamines n = 4, tetraamines n = 4 or 5) were found. Formation constants for the various complexes studied in this work, together with data for the analogous systems previously studied (20 systems), were examined as a function of charges involved in the formation reaction and of the structure of both the dicarboxylic ligand and the polyammonium cation. Structure generally has little effect on stability, while charges play…