Search results for "Eris"

showing 10 items of 3451 documents

A novel approach for parameters determination in four lumped PV parametric model with operative range evaluations

2013

The paper presents a novel numerical approach for the parameters determination of crystalline silicon PV models four lumped parameters equivalent circuit. The novel approach basically deals with a new method, alternative to the iterative one known in literature, to calculate the series resistance. Particularly, it allows the evaluation of the lumped parameters on the basis of the manufacturer’s datasheet. The new approach has been validated both in the Maximum Power Point (MPP) and close to it by comparing values and curves obtained by means of the model implementation in Matlab/Simulink environment with those related to some five parameters models and manufacturer curves. Results show that…

Settore ING-IND/32 - Convertitori Macchine E Azionamenti Elettricifive lumped parameters model four lumped parameters model I-V characteristic curves Maximum Power Point silicon photovoltaic modules
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Synthesis, Anti-Inflammatory Activity, and in Vitro Antitumor Effect of a Novel Class of Cyclooxygenase Inhibitors: 4-(Aryloyl)phenyl Methyl Sulfones

2010

Following our previous research on anti-inflammatory drugs (NSAIDs), we report on the design and synthesis of 4-(aryloyl)phenyl methyl sulfones. These substances were characterized for their capacity to inhibit cyclooxygenase (COX-1 and COX-2) isoenzymes. Molecular modeling studies showed that the methylsulfone group of these compounds was inserted deep in the pocket of the human COX-2 binding site, in an orientation that precludes hydrogen bonding with Arg120, Ser353, and Tyr355 through their oxygen atoms. The N-arylindole 33 was the most potent inhibitor of COX-2 and also the most selective (COX-1/COX-2 IC(50) ratio was 262). The indole derivative 33 was further tested in vivo for its ant…

Models MolecularIndolesMolecular modelCell SurvivalStereochemistrymedicine.drug_classAntineoplastic AgentsAnti-inflammatoryStructure-Activity RelationshipIn vivoCell Line TumorDrug DiscoverymedicineAnimalsHumansCyclooxygenase InhibitorsSulfonesBinding siteIC50Cell ProliferationIndole testCyclooxygenase 2 InhibitorsbiologyChemistryStereoisomerismSettore CHIM/08 - Chimica FarmaceuticaIn vitroRats4-(Aryloyl)phenyl methyl sulfones anti-inflammatory activity antitumor effect COX-1/COX-2 selectivityCyclooxygenase 1biology.proteinThermodynamicsMolecular MedicineCyclooxygenaseDrug Screening Assays AntitumorHydrophobic and Hydrophilic InteractionsJournal of Medicinal Chemistry
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Occurrence of two rare species from order Lampriformes: Crestfish Lophotus lacepede (Giorna, 1809) and scalloped ribbonfish Zu cristatus(Bonelli, 181…

2017

The bony fish Lophotus lacepede (Giorna, 1809) and Zu cristatus (Bonelli, 1819) are the two species rarely recorded within the Mediterranean basin, usually reported as accidentally captured in depth (mesopelagic) fishing operations. In the current work, we present the first record of L. lacepede and Z. cristatus in fishing catches from southwestern Tyrrhenian Sea. Moreover, in order to improve existent biological/ ecological knowledge, some bio-related aspects such as feeding aspect, sexual maturity and age estimate have been discussed.

Meristic features0106 biological sciencesLampriformesCrestfishVertebraebiology010604 marine biology & hydrobiologyRare speciesLophotus lacepedeZoology02 engineering and technologyScalloped ribbonfish021001 nanoscience & nanotechnologyOceanographybiology.organism_classification01 natural sciencesScalloped ribbonfishCrestfishGeographyGrowth ring0210 nano-technologyActa Adriatica
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The International Guideline Evaluation Screening Tool (IGEST): development and validation.

2022

Abstract Background Guideline adaptation provides an important alternative to de novo guideline development by making the process more efficient and reducing unnecessary duplication. The quality evaluation of international guidelines is an essential part of the adaptation process. The study aims at describing the development and validation of a new tool to screen trustworthy Clinical Practice Guidelines (CPGs) for their adoption/adaption: the International Guideline Evaluation Screening Tool (IGEST). Methods The process of developing the IGEST involved two main phases: 1) tool development and 2) content validation. The tool development phase comprised three stages, where the scope of the IG…

EpidemiologyResearchToolHumansHealth InformaticsNursingAssessmentDevelopmentClinical guidelineSettore MED/45 - Scienze Infermieristiche Generali Cliniche E PediatricheDelivery of Health CareValidityBMC medical research methodology
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Trans-to-cis photoisomerization of cyclocurcumin in different environments rationalized by computational photochemistry

2020

International audience; Cyclocurcumin is a turmeric component that attracted much less attention compared to the well known curcumin. In spite of the less deep charcaterization of its properties, cyclocurcumin has shown promising anticancer effects when used in combination with curcumin. Especially, due to its peculiar molecular structure, cyclocurcumin can be regarded as an almost ideal photoswitch, whose capabilities can also be exploited for relevant biological applications. Here, by means of state-of-the-art computational methods for electronic excited-state calculations (TD-DFT, MS-CASPT2, XMS-CASPT2) we analyze in detail the absorption and photoisomerization pathways leading from the …

PhotoswitchPhotoisomerizationChemistryGeneral Physics and Astronomy02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciencesFluorescence0104 chemical sciencesExcited state[CHIM]Chemical SciencesMoleculePhysical and Theoretical ChemistrySolvent effects0210 nano-technologyGround stateCis–trans isomerismPhysical Chemistry Chemical Physics
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Attraction to male pheromones and sexual behaviour show different regulatory mechanisms in female mice.

2004

In rodents, female sexual behaviour is under hormonal control. The attraction females show for male-derived nonvolatile chemicals (pheromones) can be regarded as the first step of this behaviour, but it is unknown whether this attraction is also modulated by sexual steroids. To test this possibility, ovariectomized adult female mice with no experience of chemical signals from adult males were randomly assigned to four groups that received oil (control), progesterone, estradiol (E) or estradiol+progesterone (E+P) injections, respectively. Females were then tested for their attraction to male-soiled bedding and, subsequently, for their proceptive behaviour when confronted to adult males. Fema…

Malemedicine.medical_specialtyAgingsteroid hormonesVomeronasal organExperimental and Cognitive PsychologyProceptive phaseBiologyPheromonesvomeronasal systemBehavioral NeuroscienceMiceSexual Behavior AnimalInternal medicinemedicineAnimalsEstrous cycleSex CharacteristicsamygdalaAttractionSexual intercourseEndocrinologySex pheromoneExploratory BehaviorPheromoneFemaleSteroidsfemale sexual behaviourpheromonesattractionSex characteristicsPhysiologybehavior
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Diastereo- and enantioselective synthesis of orthogonally protected 2,4-diaminocyclopentanecarboxylates: a flip from beta-amino- to beta,gamma-diamin…

2007

Conformationally restricted, orthogonally protected 2,4-diaminocarboxylates with a cyclopentane skeleton were efficiently synthesized from beta-lactam 6, the syntheses involving strategies of diastereoselective epoxidation of the beta-lactam and the corresponding monoprotected amino esters with opposite selectivities followed by regioselective opening of the oxirane ring with sodium azide. The enantiomers were also prepared. This new class of compounds can be regarded not only as conformationally constrained beta,gamma-diamino acid derivatives but also as potential functionalized carbocyclic nucleoside precursors.

Ethylene OxideAmino estersChemistryStereochemistryOrganic ChemistryEnantioselective synthesisCarboxylic AcidsMolecular ConformationEpoxideRegioselectivityEstersStereoisomerismCyclopentanesbeta-LactamsChemical synthesischemistry.chemical_compoundDiamineLactamSodium azideSodium AzideThe Journal of organic chemistry
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Inequalities in mortality in small areas of eleven Spanish cities (the multicenter MEDEA project)

2009

The objectives of this study are to identify inequalities in mortality among census tracts of 11 Spanish cities in the period 1996-2003 and to analyse the relationship between these geographical inequalities and socioeconomic deprivation. It is a cross-sectional ecological study where the units of analysis are census tracts. We obtained an index of socioeconomic deprivation and estimated SMR by each census tract using hierarchical Bayesian models which take into account the spatial structure. In the majority of the cities geographical patterns in total mortality were found in both sexes, which were similar to those for the index of socioeconomic deprivation. Among men, four specific causes …

EmploymentMaleHealth (social science)InequalityCross-sectional studymedia_common.quotation_subjectGeography Planning and DevelopmentAge DistributionInternational Classification of DiseasesResidence CharacteristicsCause of DeathPoverty AreasHumansRegistriesMortalitySex DistributionSocioeconomic statusSmall-Area Analysismedia_commonCause of deathAnalysis of VariancePrincipal Component AnalysisUrban HealthPublic Health Environmental and Occupational HealthEcological studyHealth Status DisparitiesCensusCross-Sectional StudiesGeographySocioeconomic FactorsSpainPopulation SurveillanceSmall-Area AnalysisEducational StatusRegression AnalysisFemaleGeographical inequalitiesDemographyHealth & Place
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Potential of human serum albumin as chiral selector of basic drugs in affinity electrokinetic chromatography-partial filling technique

2006

The enantiomeric resolution of compounds using HSA by means of affinity EKC (AEKC)-partial filling technique is the result of a delicate balance between different experimental variables such as protein concentration, running pH (background electrophoretic buffer (BGE), protein, and compound solutions), and plug length. In this paper, the possibility of using HSA as chiral selector for enantioseparation of 28 basic drugs using this methodology is studied. The effect of the physicochemical parameters, the structural properties of compounds, and compound-HSA protein binding percentages over their chiral resolution with HSA is outlined. Based on the results obtained, a decision tree is proposed…

Resolution (mass spectrometry)Clinical BiochemistryPlasma protein bindingBuffersBiochemistryChromatography AffinityAnalytical ChemistryElectrokinetic phenomenaMolar volumemedicineHumansSerum AlbuminChromatography Micellar Electrokinetic CapillaryChromatographyMolecular StructureChemistryStereoisomerismHydrogen-Ion ConcentrationHuman serum albuminChiral resolutionbody regionsElectrophoresisPharmaceutical Preparationsembryonic structuresEnantiomerHydrophobic and Hydrophilic Interactionsmedicine.drugELECTROPHORESIS
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α,β-Dehydroamino acids in naturally occurring peptides

2014

α,β-Dehydroamino acids are naturally occurring non-coded amino acids, found primarily in peptides. The review focuses on the type of α,β-dehydroamino acids, the structure of dehydropeptides, the source of their origin and bioactivity. Dehydropeptides are isolated primarily from bacteria and less often from fungi, marine invertebrates or even higher plants. They reveal mainly antibiotic, antifungal, antitumour, and phytotoxic activity. More than 60 different structures were classified, which often cover broad families of peptides. 37 different structural units containing the α,β-dehydroamino acid residues were shown including various side chains, Z and E isomers, and main modifications: meth…

Dehydroamino acidsStereochemistryClinical BiochemistryPeptideReview ArticleHeterocyclesBiochemistryMethylationResidue (chemistry)IsomerismDepsipeptidesSide chainPeptide bondAmino AcidsDepsipeptidechemistry.chemical_classificationNatural productsbiologyChemistryDehydropeptidesOrganic ChemistryBiological activitybiology.organism_classificationAmino acidBiochemistryZ/E isomerisationPeptidesBacteriaAmino Acids
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