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Metal-Controlled Magnetoresistance at Room Temperature in Single-Molecule Devices

2017

The appropriate choice of the transition metal complex and metal surface electronic structure opens the possibility to control the spin of the charge carriers through the resulting hybrid molecule/metal spinterface in a single-molecule electrical contact at room temperature. The single-molecule conductance of a Au/molecule/Ni junction can be switched by flipping the magnetization direction of the ferromagnetic electrode. The requirements of the molecule include not just the presence of unpaired electrons: the electronic configuration of the metal center has to provide occupied or empty orbitals that strongly interact with the junction metal electrodes and that are close in energy to their F…

Magnetoresistance02 engineering and technologyElectronic structure010402 general chemistry01 natural sciencesBiochemistryCatalysisMetal L-edgesymbols.namesakeColloid and Surface ChemistryTransition metalMagnetoresistènciaSurface statesDensity functionalsCondensed matter physicsChemistryMagnetoresistanceFermi levelTeoria del funcional de densitatGeneral ChemistryEspintrònicaSpintronics021001 nanoscience & nanotechnology0104 chemical sciencesFerromagnetismsymbolsCondensed Matter::Strongly Correlated ElectronsElectron configuration0210 nano-technology
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