Search results for "Excess"
showing 10 items of 225 documents
Natural eutectogels: sustainable catalytic systems for C–C bond formation reactions
2021
Natural eutecto gels were prepared combining properties of amino acids with the ones of deep eutectic solvents. Soft materials obtained were fully characterised determining the gel-sol transition temperatures and analysing mechanical and morphological features through rheological measurements and polarised optical microscopy. All eutecto gels were tested as catalytic reaction media for the enantioselective aldol reaction and, the best performing one was also used to carry out the Michael addition. In both cases, eutecto gels proved to have a great potential as sustainable reaction media, allowing to perform processes under mild conditions, obtaining excellent yields and, in some cases, also…
Concise asymmetric synthesis of Linezolid through catalyzed Henry reaction
2013
A new asymmetric synthesis of the antibiotic Linezolid was performed through a copper-catalyzed Henry reaction as the key step. The use of camphor-derived aminopyridine ligands helped to improve the yields of the chiral precursor and to obtain Linezolid in good overall yield and enantiomeric excess.
Elliptically Symmetric Distributions: A Review of Achieved Results and Open Issues
2005
The spherically and elliptically symmetrical distributions are used in different statistical areas for different purposes such as the description of multivariate data, in order to find alternatives to the normal distribution in multinormality tests and in the creation of statistical models in which the usual assumption of normality is not realistic. Some achieved results, open issues and some proposals for their use in applications, especially in the financial area, are here presented.
$Q$-value of the superallowed $\beta$ decay of 62Ga
2006
Masses of the radioactive isotopes 62Ga, 62Zn and 62Cu have been measured at the JYFLTRAP facility with a relative precision of better than 18 ppb. A Q_EC value of (9181.07 +- 0.54) keV for the superallowed decay of 62Ga is obtained from the measured cyclotron frequency ratios of 62Ga-62Zn, 62Ga-62Ni and 62Zn-62Ni ions. The resulting Ft-value supports the validity of the conserved vector current hypothesis (CVC). The mass excess values measured were (-51986.5 +-1.0) keV for 62Ga, (-61167.9 +- 0.9) keV for 62Zn and (-62787.2 +- 0.9) keV for 62Cu.
Direct mass measurements above uranium bridge the gap to the island of stability
2010
The mass of an atom incorporates all its constituents and their interactions. The difference between the mass of an atom and the sum of its building blocks (the binding energy) is a manifestation of Einstein's famous relation E = mc(2). The binding energy determines the energy available for nuclear reactions and decays (and thus the creation of elements by stellar nucleosynthesis), and holds the key to the fundamental question of how heavy the elements can be. Superheavy elements have been observed in challenging production experiments, but our present knowledge of the binding energy of these nuclides is based only on the detection of their decay products. The reconstruction from extended d…
Study of excited states of [sup 31]S through beta-decay of [sup 31]Cl for nucleosynthesis in ONe novae
2011
We have produced an intense and pure beam of 31Cl with the MARS Separator at the Texas A&M University and studied β‐decay of 31Cl by implanting the beam into a novel detector setup, capable of measuring β‐delayed protons and γ‐rays simultaneously. From our data, we have established decay scheme of 31Cl, found resonance energies with 1 keV precision, have measured its half‐life with under 1% accuracy, found its Isobar Analog State decay and by using the IMME obtained an improved mass excess for its ground state. In this contribution, a description of the used method along with selected preliminary experimental results are given and their relevance for novae nucleosynthesis discussed.
Variable masses in fission and heavy-ion collisions
1972
With the use of the cranking formula, the coordinate-dependent mass parameters of the kinetic-energy operator in fission processes and heavy-ion collisions are calculated in the two-center oscillator model. It is shown that the reduced mass and also the classical moment of inertia are obtained for large separations of the fragments. For small separations, however, the mass parameter for the motion of the centers of mass of the fragments is larger than the reduced mass by an order of magnitude.
Pricing Policies of Excess Capacity in Make to Order Production Systems
2014
The research concerns a make to order manufacturing environment and two classes of customers who submit orders. The core customers have a contract with the firm at fixed services level (price and due date). The short-term customers submit the orders based on the price set by the firm. In this paper, it is proposed a pricing policy based on fuzzy logic to set the price for the short-term customers. The fuzzy approach captures the state of the manufacturing systems in terms of congestion in order to set the price. The policy proposed is compared to a fixed price, and to a state-dependent policy based on three levels of price. A discrete event simulation environment is used to test the propose…
Conservation of optical purity of amino acids: a principal problem in biochemical and proto-biochemical systems.
1981
Dor L-amino acids, regardless of their state (peptide-bound or free, in the solid state or in aqueous solution), tend to racemize. In a living cell this racemization is usually compensated by specific degradation and replacement of the unwanted polypeptides that contain the wrong enantiomers. But a few long-lived proteins that are synthesized at or near birth are never replaced. Well investigated is the racemization of L-aspartic acid at a rate of 0.1 to 1.14 per cent per year in proteins from lenses and dentine. Increased racemization of eye lens proteins has been related to a form of human eye disease known as brunescent cataracts. Also quite well investigated is the racemization of amino…
Synthesis of 2-isoxazolines: enantioselective and racemic methods based on conjugate additions of oximes.
2010
The formation of 3-unsubstituted 2-isoxazolines by means of condensation reactions between α,β-unsaturated aldehydes and oximes proceeds readily in the presence of catalytic amounts of anilinium salts. Mechanistically, the process involves a fast conjugate addition of the oxime and a slower intramolecular oxime-transfer reaction. The rate of oxime transfer was found to correlate with the acidity of the catalyst. This finding enabled us to discover an enantioselective process in which the fragile conjugate-addition product generated in the first stage is rapidly cyclized into the stable isoxazoline under acidic conditions, with conservation of enantiomeric excess. In summary, herein we descr…