Search results for "Excess"
showing 10 items of 225 documents
Measure differential inclusions: existence results and minimum problems
2020
AbstractWe focus on a very general problem in the theory of dynamic systems, namely that of studying measure differential inclusions with varying measures. The multifunction on the right hand side has compact non-necessarily convex values in a real Euclidean space and satisfies bounded variation hypotheses with respect to the Pompeiu excess (and not to the Hausdorff-Pompeiu distance, as usually in literature). This is possible due to the use of interesting selection principles for excess bounded variation set-valued mappings. Conditions for the minimization of a generic functional with respect to a family of measures generated by equiregulated left-continuous, nondecreasing functions and to…
Dynamical block analysis in a non-equilibrium system
1991
Abstract We present molecular dynamics simulation results of quenches into the unstable region of a two-dimensional Lennard-Jones system. The evolution of the system from the non-equilibrium state into equilibrium was analyzed with a dynamical block analysis. This can lead to a new approach in the study of non-equilibrium phenomena. We show that with such an analysis one can obtain results on the dynamic evolution as the system evolves, consistent with those obtained from and analysis of the pair-distribution function, structure factor and excess energy. The simulations were carried out on the parallel computer of the condensed matter theory group at the University of Mainz.
Market efficiency and the long-memory of supply and demand: is price impact variable and permanent or fixed and temporary?
2016
In this comment we discuss the problem of reconciling the linear efficiency of price returns with the long-memory of supply and demand. We present new evidence that shows that efficiency is maintained by a liquidity imbalance that co-moves with the imbalance of buyer vs. seller initiated transactions. For example, during a period where there is an excess of buyer initiated transactions, there is also more liquidity for buy orders than sell orders, so that buy orders generate smaller and less frequent price responses than sell orders. At the moment a buy order is placed the transaction sign imbalance tends to dominate, generating a price impact. However, the liquidity imbalance rapidly incre…
Enantioselective Friedel-Crafts reaction of hydroxyarenes with nitroenynes to access chiral heterocycles via sequential catalysis
2021
Naphthols, hydroxyindoles and an activated phenol are reacted with differently substituted (E)-nitrobut-1-en-3-ynes using the commercially available Rawal's chiral squaramide. The corresponding β-nitroalkynes were obtained with good yields and excellent enantioselectivities. Moreover, dihydronaphthofurans can be accessed via silver catalysed cyclization in a tandem one-pot procedure, with high preservation of the optical purity.
La Seconda Vita dell'Ambiente Costruito
2021
Il contributo inquadra i saggi, gli studi, le ricerche e progetti pubblicati sul numero 9 di AGATHÓN su ‘La Seconda Vita dell’Ambiente Costruito’, tema di interesse per il mondo accademico, delle professioni e dell’industria. Cambiamenti climatici, eccessivo consumo di suolo e di risorse non rinnovabili, produzione sempre crescente di rifiuti, emergenza pandemica e crisi socio-economica globale sono entrati di fatto nel nostro quotidiano: seppur drammatiche, per certi versi, tali questioni possono essere colte come un’opportunità per ripensare il modo e il mondo in cui viviamo. In questo contesto di ‘rivoluzione’(Floridi, 2020) e di ‘policrisi’ (Losasso, 2020), e con riferimento specifico a…
Volume change characteristics of fine-grained soils due to sequential thermo-mechanical stresses
2019
Know-how of volume change characteristics, VCC, of the fine-grained soils, exposed to thermal stresses, is essential for design of various thermo-active structures. These stresses are known to induce excess pore-water pressure, Δu θ , in the saturated state of such soils, which in turn affects their compression and shear strength characteristics. In this context, through several experimental studies, the effect of thermo-mechanical stress-path, the over-consolidation ratio (OCR) and degree of saturation on VCC (viz., thermally induced volumetric strain, ε vθ , compression and re-compression indices, c c and c r ) of the fine-grained soils has been demonstrated by earlier researchers. Howeve…
Synthesis and characterization of chiral azobenzene dye functionalized Janus dendrimers
2008
Abstract Eight bischromophoric bisMPA based polyester Janus dendrimers emanating from a pentaerythritol core were synthesized and their properties evaluated. 4-((4-(Ethyl(2-(2-(6-methoxynaphthalen-2-yl)propanoyloxy)ethyl)amino)-phenyl)diazenyl)-benzoic acid and 4-((4-(ethyl(2-(2-(6-methoxynaphthalen-2-yl)propanoyloxy)-ethyl)-amino)phenyl)diazenyl)-3-nitrobenzoic acid were attached to the dendritic polyester skeleton to make chiral dendrimers up to the second generation. The structures and the purity of the molecules were verified with 1H NMR, 13C NMR, ESI TOF mass spectrometry, and elemental analysis. Spectral properties were evaluated with UV–vis and CD spectrometer. The compounds displaye…
Topiramate and Metabolic Acidosis in Infants and Toddlers
2002
Summary: Purpose: Topiramate (TPM) inhibits carbonic anhydrase, with metabolic acidosis as a possible side effect, although this has been reported in only two adult cases. We investigated the acid–base metabolism in infants and toddlers treated with TPM. Methods: Nine infants and toddlers aged 5 months to 2.3 years (median, 6 months) were treated with TPM at maximal doses of 8.2–26 mg/kg/day (median, 11 mg/kg/day). The maximal TPM dose was achieved after 8–35 days (median, 17 days). TPM was given in addition to other antiepileptic drugs (AEDs) in five cases and as a sole AED in four patients with refractory epilepsy resistant to multiple AEDs. The diagnoses were infantile spasms (n = 5), e…
Iron Regulatory Mechanisms in Saccharomyces cerevisiae
2020
Iron is an essential micronutrient for all eukaryotic organisms because it participates as a redox cofactor in many cellular processes. However, excess iron can damage cells since it promotes the generation of reactive oxygen species. The budding yeast Saccharomyces cerevisiae has been used as a model organism to study the adaptation of eukaryotic cells to changes in iron availability. Upon iron deficiency, yeast utilizes two transcription factors, Aft1 and Aft2, to activate the expression of a set of genes known as the iron regulon, which are implicated in iron uptake, recycling and mobilization. Moreover, Aft1 and Aft2 activate the expression of Cth2, an mRNA-binding protein that limits t…
Combination of Searches for Invisible Higgs Boson Decays with the ATLAS Experiment
2019
Dark matter particles, if sufficiently light, may be produced in decays of the Higgs boson. This Letter presents a statistical combination of searches for H → invisible decays where H is produced according to the standard model via vector boson fusion, Z(ℓℓ)H, and W/Z(had)H, all performed with the ATLAS detector using 36.1 fb⁻¹ of pp collisions at a center-of-mass energy of √s = 13 TeV at the LHC. In combination with the results at √s = 7 and 8 TeV, an exclusion limit on the H → invisible branching ratio of 0.26(0.17-0.05+0.07) at 95% confidence level is observed (expected).