Search results for "FFR"
showing 10 items of 1798 documents
Time-resolved X-ray powder diffraction on a three-way catalyst at the GILDA beamline
2003
Time-resolved X-ray diffraction experiments carried out at the beamline BM08-GILDA of ESRF allowed a study of the structural modifications taking place in a Pt/ceria-zirconia catalyst while the CO oxidation reaction was in progress. The capillary tube in which the sample is stored acts effectively as a chemical microreactor that ensures homogeneity of the sample treatments and minimization of diffusion effects. During the flowing of the reactant CO/He mixture, the investigated catalyst undergoes a fast Ce(IV)-Ce(III) partial reduction that involves the release of one O atom for every two reduced Ce cations. Because Ce(III) has a larger ionic radius than Ce(IV), the structural modification p…
Effect of gamma radiation on thermostimulated exoelectron emission from Gd2O3 films
2020
Abstract The effect of gamma irradiation on Gd2O3 films was studied using the thermostimulated exoelectron emission (TSEE) technique. The films were deposited on a glass and Si/SiO2 substrates using an extraction-pyrolytic method. Crystalline structure, chemical composition, film thickness and surface morphology were characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The films were irradiated by 10 MeV gamma photons and TSEE was measured from the irradiated films. It was found that gamma irradiation decreases TSEE intensity and the area below TSEE spectral curves. A linear correlati…
X-ray study of the light-induced metastable state of a spin-crossover compound
2000
Iron(II) complexes exhibiting thermal spin crossover may be converted from the1A1low-spin (LS) state to the5T2high-spin (HS) state by irradiation with green light (light-induced excited spin-state trapping, LIESST). The lifetime of the metastable LIESST state may be sufficiently long for X-ray diffraction study. The lattice parameters of a single crystal of [Fe(ptz)6](BF4)2(ptz = propyltetrazole) were measured between 300 and 10 K, while the crystal changed from the HS to the LS state near 135 K. Using the green light (514 nm) of an argon-ion laser, the crystal was quantitatively converted to the metastable LIESST state at 10 K; its lattice parameters were measured up to 50 K, at which poin…
Levels of 188Re nucleus populated in thermal neutron capture reaction
2016
Abstract Levels of 188 Re populated in thermal neutron capture reaction with enriched 187 Re targets have been studied. Single γ -ray spectrum of 188 Re, measured with the high-resolution crystal diffraction spectrometer GAMS5, as well as γγ -coincidence experiments performed with high efficiency Ge detectors, allowed to develop model-independent level scheme of the doubly-odd 188 Re nucleus up to ∼ 1.5 MeV excitation energy. Analysis of the established 188 Re level scheme in terms of the quasiparticle-plus-rotor model indicates coexistence of axially-deformed and triaxial structures in the energy range above 400 keV.
Measuring Inaccessible Residual Stresses Using Multiple Methods and Superposition
2010
The traditional contour method maps a single component of residual stress by cutting a body carefully in two and measuring the contour of the cut surface. The cut also exposes previously inaccessible regions of the body to residual stress measurement using a variety of other techniques, but the stresses have been changed by the relaxation after cutting. In this paper, it is shown that superposition of stresses measured post-cutting with results from the contour method analysis can determine the original (pre-cut) residual stresses. The general superposition theory using Bueckner’s principle is developed and limitations are discussed. The procedure is experimentally demonstrated by determini…
Fractal-structured multifocal intraocular lens
2017
[EN] In this work, we present a new concept of IOL design inspired by the demonstrated properties of reduced chromatic aberration and extended depth of focus of Fractal zone plates. A detailed description of a proof of concept IOL is provided. The result was numerically characterized, and fabricated by lathe turning. The prototype was tested in vitro using dedicated optical system and software. The theoretical Point Spread Function along the optical axis, computed for several wavelengths, showed that for each wavelength, the IOL produces two main foci surrounded by numerous secondary foci that partially overlap each other for different wavelengths. The result is that both, the near focus an…
Fractal zone plates with variable lacunarity.
2009
Fractal zone plates (FZPs), i.e., zone plates with fractal structure, have been recently introduced in optics. These zone plates are distinguished by the fractal focusing structure they provide along the optical axis. In this paper we study the effects on this axial response of an important descriptor of fractals: the lacunarity. It is shown that this parameter drastically affects the profile of the irradiance response along the optical axis. In spite of this fact, the axial behavior always has the self-similarity characteristics of the FZP itself.
Fabrication of Diffractive Optics: Surface Reliefs and Artificial Dielectrics
1997
After a period of fundamental theoretical research, the field of diffractive optics is now reaching a time of assessment, when we can define the useful limits of each design procedure. Selecting a suitable procedure derives from a compromise between several factors, including design time, desired optical efficiency, and precision. A major consideration in finding such a compromise has been, and still is today, the availability of technologies which can realize the design by generating the diffracting structure with assigned tolerances.
Experimental observation of temporal dispersion gratings in fiber optics
2017
We experimentally demonstrate a temporal analog to the diffraction optical grating in the Fraunhofer formalism. Using amplitude and phase temporal periodic modulations, we show that the accumulation of dispersion in fiber optics induces the development of temporally well-separated sidebands similar to the spatial orders of diffraction that are commonly observed in an optical grating operating in the far field.
Devil’s vortex-lenses
2009
In this paper we present a new kind of vortex lenses in which the radial phase distribution is characterized by the "devil's staircase" function. The focusing properties of these fractal DOEs coined Devil's vortex-lenses are analytically studied and the influence of the topological charge is investigated. It is shown that under monochromatic illumination a vortex devil's lens give rise a focal volume containing a delimited chain of vortices that are axially distributed according to the self-similarity of the lens.