Search results for "FH"
showing 10 items of 171 documents
Iodide-Photocatalyzed Reduction of Carbon Dioxide to Formic Acid with Thiols and Hydrogen Sulfide.
2016
The photolysis of iodide anions promotes the reaction of carbon dioxide with hydrogen sulfide or thiols to quantitatively yield formic acid and sulfur or disulfides. The reaction proceeds in acetonitrile and aqueous solutions, at atmospheric pressure and room temperature by irradiation using a low-pressure mercury lamp. This transition-metal-free photocatalytic process for CO2 capture coupled with H2 S removal may have been relevant as a prebiotic carbon dioxide fixation.
Of Thiols and Disulfides: Methods for Chemoselective Formation of Asymmetric Disulfides in Synthetic Peptides and Polymers.
2018
In protein or peptide chemistry, thiols are frequently chosen as a chemical entity for chemoselective modification reactions. Although it is a well-established methodology to address cysteines and homocysteines in aqueous media to form S-C bonds, possibilities for the chemoselective formation of asymmetric disulfides have been less approached. Focusing on bioreversibility in conjugation chemistry, the formation of disulfide bonds is highly desirable for the attachment of thiol-containing bioactive agents to proteins or in cross-linking reactions, because disulfide bonds can combine stability in blood with degradability inside cells. In this Concept article, recent approaches in the field of…
Determining Soil Hydraulic Properties Using Infiltrometer Techniques: An Assessment of Temporal Variability in a Long-Term Experiment under Minimum- …
2020
Conservation agriculture is increasingly accepted by farmers, but the modeling studies on agro-environmental processes that characterize these agricultural systems require accurate information on the temporal variability of the soil&rsquo
Comparison of thiol subproteome of the vent mussel Bathymodiolus azoricus from different Mid-Atlantic Ridge vent sites
2012
Deep-sea hydrothermal mussels Bathymodiolus azoricus live in the mixing zone where hydrothermal fluid mixes with bottom seawater, creating large gradients in the environmental conditions and are one of the most studied hydrothermal species as a model of adaptation to extreme conditions. Thiol proteins, i.e. proteins containing a thiol or sulfhydryl group (SH) play major roles in intracellular stress defense against reactive oxygen species (ROS) and are especially susceptible to oxidation. However, they are not particularly abundant, representing a small percentage of proteins in the total proteome and therefore are difficult to study by proteomic approaches. Activated thiol sepharose (ATS) …
HL7 FHIR with SNOMED-CT to Achieve Semantic and Structural Interoperability in Personal Health Data: A Proof-of-Concept Study
2022
Heterogeneity is a problem in storing and exchanging data in a digital health information system (HIS) following semantic and structural integrity. The existing literature shows different methods to overcome this problem. Fast healthcare interoperable resources (FHIR) as a structural standard may explain other information models, (e.g., personal, physiological, and behavioral data from heterogeneous sources, such as activity sensors, questionnaires, and interviews) with semantic vocabularies, (e.g., Systematized Nomenclature of Medicine—Clinical Terms (SNOMED-CT)) to connect personal health data to an electronic health record (EHR). We design and develop an intuitive health coaching (eCoach…
Polymethacrylate monoliths with immobilized poly-3-mercaptopropyl methylsiloxane film for high-coverage surface functionalization by thiol-ene click …
2014
In this work, new polythiol-functionalized macroporous monolithic polymethacrylate-polysiloxane composite materials are presented which can be useful substrates for highly efficient immobilization of (chiral) catalysts, chromatographic ligands, and other functional moieties by thiol-ene click reaction. Poly(glycidyl methacrylate-co-ethylene dimethacrylate) (poly(GMA-co-EDMA)) monoliths were coated with a poly-3-mercaptopropyl methylsiloxane (PMPMS) film and subsequently the polymer was covalently immobilized by formation of crosslinks via nucleophilic substitution reaction with pendent 2,3-epoxypropyl groups on the monolith surface. This monolith, though, showed similar levels of surface co…
Soil hydraulic properties determined by infiltration experiments and different heights of water pouring
2014
Abstract Establishing the dependence of the soil hydraulic characterization carried out by an infiltration experiment on the procedure used to apply water on the confined soil surface may help to better interpret the collected data and also to develop more accurate strategies for soil hydraulic characterization. Soil was sampled at four Sicilian sites with both the Simplified Falling Head (SFH) technique and the Beerkan Estimation of Soil Transfer parameters (BEST) procedure and two heights of water application (0.03 and 1.5 m). The most appropriate BEST algorithm to analyze the data was determined and the effect of the height of water pouring on the measured soil hydraulic properties was e…
SNOMED on FHIR Transmission of clinical data with the Fast Healthcare Interoperability Resources protocol (HL7-FHIR) utilizing Systematized Nomenclat…
2019
Master's thesis Information- and communication technology IKT590 - University of Agder 2019 The exchange of information at the level of semantic interoperability needs some infor-mation model and clinical terminology work together. Electronic records of the patientmust include the terminologies in order to give the decision support to the practitionerwhen needed. Due to the lack of common standards for data structure and data sharingcreates the problem to interact and share information with different applications.Our main goal in this thesis is transferring the SNOMED-CT (Systematized Nomenclatureof Medicine Clinical Terms) terminologies using HL7 FHIR (Fast Healthcare Interoper-ability Res…
Easy Route to Functionalize Iron Oxide Nanoparticles via Long-Term Stable Thiol Groups
2009
International audience; The functionalization of superparamagnetic iron oxide nanoparticles (SPIOs) by meso-2,3-dimercaptosuccinic acid (DMSA) was investigated. Under ambient conditions, the thiol groups from DMSA are not stable and do not allow a direct functionalization without storage in stringent conditions or a chemical regeneration of free thiols. In this study, we have developed a protocol based on poly(ethylene glycol) (PEG) grafting of SPIO prior to DMSA anchoring. We have observed that PEG helps to increase the stability of thiol groups under ambient conditions. The thiol functionalized SPIOs were stable under physiological pH and ionic strength as determined by Ellman's essay and…
creación de relatos digitales no lineales como herramienta intercultural en el ámbito de la filología francesa
2021
Este artículo aborda la importancia de la gamificación como forma de innovación docente en contextos universitarios, concretamente en la docencia de lengua y literatura francesas, para nuestro alumnado nativo digital. La creación de serious games pueden incentivarlo, generando una participación activa en la materia y mejores resultados académicos. Concretamente, la creación de ficciones interactivas basadas en hipertextos a través de una herramienta bastante novedosa llamada Twine, nos ha llevado a realizar talleres en clase de TICE en el Grado de LML de la UV con asombrosos resultados. Vamos a analizarlos y a ofrecer ejemplos didácticos para implementar esta herramienta en el aula en conte…