Search results for "FRAM"
showing 10 items of 2142 documents
Inside Cover: Bidirectional Chemo-Switching of Spin State in a Microporous Framework (Angew. Chem. Int. Ed. 26/2009)
2009
Bidirectional chemo-switching of magnetism occurs in a microporous coordination polymer containing spin-crossover subunits, as described by M. Ohba, J. A. Real, S. Kitagawa, and co-workers in their Communication on page 4767 ff. In situ magnetic measurements reveal that most guest molecules transform the framework spin state from diamagnetic low spin (red) to paramagnetic high spin (yellow), whereas the guest CS2 stabilizes the low-spin state. These induced spin states are retained as a memory effect after the release of the guest.
A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
2012
A quasielastic neutron scattering and solid-state 2H NMR spectroscopy study of the polymeric spin-crossover compound {Fe(pyrazine)[Pt(CN) 4]} shows that the switching of the rotation of a molecular fragment-the pyrazine ligand-occurs in association with the change of spin state. The rotation switching was examined on a wide time scale (10 -13-10 -3 s) by both techniques, which clearly demonstrated the combination between molecular rotation and spin-crossover transition under external stimuli (temperature and chemical). The pyrazine rings are seen to perform a 4-fold jump motion about the coordinating nitrogen axis in the high-spin state. In the low-spin state, however, the motion is suppres…
The Molecular Basis of X-Linked Spondyloepiphyseal Dysplasia Tarda
2001
The X-linked form of spondyloepiphyseal dysplasia tarda (SEDL), a radiologically distinct skeletal dysplasia affecting the vertebrae and epiphyses, is caused by mutations in the SEDL gene. To characterize the molecular basis for SEDL, we have identified the spectrum of SEDL mutations in 30 of 36 unrelated cases of X-linked SEDL ascertained from different ethnic populations. Twenty-one different disease-associated mutations now have been identified throughout the SEDL gene. These include nonsense mutations in exons 4 and 5, missense mutations in exons 4 and 6, small (2–7 bp) and large (>1 kb) deletions, insertions, and putative splicing errors, with one splicing error due to a complex deleti…
Guest-dependent single-ion magnet behaviour in a cobalt(ii) metal-organic framework.
2015
Single-ion magnets (SIMs) are the smallest possible magnetic devices for potential applications in quantum computing and high-density information storage. Both, their addressing in surfaces and their organization in metal-organic frameworks (MOFs) are thus current challenges in molecular chemistry. Here we report a two-dimensional 2D MOF with a square grid topology built from cobalt(ii) SIMs as nodes and long rod-like aromatic bipyridine ligands as linkers, and exhibiting large square channels capable to host a large number of different guest molecules. The organization of the cobalt(ii) nodes in the square layers improves the magnetic properties by minimizing the intermolecular interaction…
WHERE DOES CORPORATE SOCIAL RESPONSIBILITY STAND IN RELATION TO SUSTAINABILITY?
2018
The business competitive landscape of today is shaped by new challenges. In order to outperform their peers, companies seek to seize opportunities and manage the risks associated with the challenges that arise. To this adds the pressure of societies on organizations to be more transparent, ethical and responsible. Corporate Social Responsibility (CSR) and sustainability come in response to this increasing demand of societies by being a pivotal tool in the business area. Organizations of the 21st century can no longer ignore CSR and sustainability and should follow the steps of integrating them across all departments as part of their strategic policy. Sustainable organizations are required t…
INTER-ORGANIZATIONAL NETWORKS FOR INNOVATIONS AND SUSTAINABILITY
2021
The present Thesis is structured as a collection of three essays linked by one core idea: contributing to research knowledge on inter-organizational network dynamics in the context of innovation and the promotion of sustainability. In this Thesis, the author takes a systemic perspective and analyses the interactions between diverse groups of stakeholders, aiming to identify and interpret the logic underlying the formation of inter-organizational partnerships to promote innovation and sustainability. The dynamics of inter-organizational networks are influenced by several internal and external factors, such as strategic cooperation with stakeholders, structural changes (such as an R&I policy …
The Psychological Science Accelerator’s COVID-19 rapid-response dataset
2023
Funder: Amazon Web Services (AWS) Imagine Grant
Spatio-temporal modelling of COVID-19 incident cases using Richards’ curve: An application to the Italian regions
2021
Abstract We introduce an extended generalised logistic growth model for discrete outcomes, in which spatial and temporal dependence are dealt with the specification of a network structure within an Auto-Regressive approach. A major challenge concerns the specification of the network structure, crucial to consistently estimate the canonical parameters of the generalised logistic curve, e.g. peak time and height. We compared a network based on geographic proximity and one built on historical data of transport exchanges between regions. Parameters are estimated under the Bayesian framework, using Stan probabilistic programming language. The proposed approach is motivated by the analysis of bot…
Coupled Susy, pseudo-bosons and a deformed su(1, 1) Lie algebra
2021
Abstract In a recent paper a pair of operators a and b satisfying the equations a † a = bb † + γ 1 and aa † = b † b + δ 1 , has been considered, and their nature of ladder operators has been deduced and analyzed. Here, motivated by the spreading interest in non self-adjoint operators in quantum mechanics, we extend this situation to a set of four operators, c, d, r and s, satisfying dc = rs + γ 1 and cd = sr + δ 1 , and we show that they are also ladder operators. We show their connection with biorthogonal families of vectors and with the so-called D -pseudo bosons. Some examples are discussed.
Gabor-like systems in ${cal L}^2({bf R}^d)$ and extensions to wavelets
2008
In this paper we show how to construct a certain class of orthonormal bases in starting from one or more Gabor orthonormal bases in . Each such basis can be obtained acting on a single function with a set of unitary operators which operate as translation and modulation operators in suitable variables. The same procedure is also extended to frames and wavelets. Many examples are discussed.