Search results for "FRAM"

showing 10 items of 2142 documents

Amide functionalized aminobisphenolato MoO2 and WO2 complexes: Synthesis, characterization, and alkene epoxidation catalysis

2023

The use of dioxidomolybdenum(vi) and -tungsten(vi) complexes supported by a variety of structurally different tri- and tetradentate aminobisphenolato ligands as pre-catalysts in the epoxidation of alkenes is well established. However, under the widely used standard 1 mol-% catalyst loadings these types of complexes generally show modest activity only. Recently, amide functionalities in the ligand design of various aminomonophenolato MoO2 complexes have been shown to lead to heightened catalytic activity in alkene epoxidation. In this paper we show that similar ligand amide functionalization can lead to significant enhancement in the alkene epoxidation activity of aminobisphenolato MoO2 comp…

Historyhapetusdioxidotungsten(VI)Polymers and PlasticsProcess Chemistry and TechnologyvolframikompleksiyhdisteetIndustrial and Manufacturing Engineeringdioxidomolybdenum(VI)Catalysiskatalyytitalkene epoxidationBusiness and International ManagementalkeenitPhysical and Theoretical Chemistrymolybdeeniaminobisphenolato ligandsMolecular Catalysis
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INTERPRETARE ORAZIO CON ORAZIO? A PROPOSITO DI CARMINA, LIBRO IV

2011

In the work “Mutat terra vices. Identità, cambiamento e memoria culturale nell’ultimo Orazio” (Palermo 2010), I focused my attention on interpretative and methodological questions concerning the last Horatian book of carmina. In this paper the aim is to demonstrate how the topic of change and discontinuity points out, on the surface of these poems, the presence of conspicuous interferences between the execution of a role by authorial "persona", and the expression, at the same time, of role distance. I mean here especially to describe how gift, reciprocity and exchange in patronage frames contributed to the definition of Horace’s self and of his official duties as interpreter of common memor…

Horace fourth book of Carmina identity frames role distanceSettore L-FIL-LET/04 - Lingua E Letteratura Latina
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Innovation Activities in Baltic Countries

2013

Abstract Article discusses a research framework which brings together variety of related factors to innovation process on the basis of systemic review of theoretical and empirical studies. Aim – investigate human capital, R&D, cooperation with external environment, on innovation oriented organizational culture, and market orientation, state policy relation to the process of innovation creation in Latvian, Lithuanian and Estonian innovative enterprises. Main research methods used. Monographs method - information collection and compilation of the influential factors on innovation creation. This method makes it possible to carry out a detailed study of the object, based on scientific literatur…

Human CapitalKnowledge managementR&Dbusiness.industryMarket OrientationCultureGeneral EngineeringEnergy Engineering and Power TechnologyOrganizational cultureLatvianLithuanianScientific literatureCompetitive advantagelanguage.human_languageCooperationEmpirical researchConceptual frameworkMarket orientationlanguageState PolicyBusinessMarketingInnovationProcedia Economics and Finance
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HUMAN SMUGGLING AND IRREGULAR IMMIGRATION IN THE EU: FROM COMPLICITY TO EXPLOITATION?

2016

The paper provides a comparative analysis of the EU and the UN to the fight against smuggling. The two approaches are considerably different; and, since the one in the UN documents is more respectful of the smuggled migrants' rights, the paper suggests that a similar approach should also be embraced by the EU documents.

Human smuggling - Irregular migration - EU Facilitation Framework Decision - EU Facilitation Directive - UN Protocol against smugglingSettore IUS/17 - Diritto Penale
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Problemi di giurisdizione nel contrasto al traffico di migranti via mare

2018

I trafficanti di esseri umani si avvalgono con sempre più insistenza di ben collaudati protocolli operativi. Questi ultimi consentono loro di sottrarsi alla giurisdizione penale italiana che non si radica qualora – in ossequio ai criteri di cui all’art. 6 c.p.ed in conformità alla Convenzione sull’Alto Mare– l’azione illecita avvenga in acque internazionali.Così, premesse alcune linee concettuali sui limiti spaziali alla efficacia della legge penale, l’indagine si sofferma sulla soluzione ermeneutica offerta dallaCassazione che, apparentemente in modo sbrigativo e per esigenze di effettività della risposta punitiva, ha fatto ricorso alla controversa figura dell’autore mediato per sanzionare condott…

Human traffickers frequently take advantage of operative protocols that make them unpunishable pursuant the Italian Criminal Law because according to Art. 6 of the Italian Penal Code and International Convention on the High Sea jurisdictional powers cannot be exercised when the conduct is committed on the High Sea. So illustrating the territorial limitations of the efficacy of Criminal Law the research focuses on the hermeneutical solution given by the Court of Cassation that apparently with the intent of pursuing a more effectivity of the Criminal response recurred to the controversial category of the indirect offender in order to sanction smuggling conducts that enjoy the rescue intervention of the Italian authorities to reach their criminal aims. In turn in order to better identify the Italian jurisdiction in the crime of Art. 12 T.U. imm. I propose to correctly apply the concorso di persone (art. 110 c.p.) and the reato eventualmente permanente. The difficulties of a dogmatic framing together with the trend towards a universalistic validity of the jurisdictional powers when human rights are involved may recommend an interpretation of Art. 7 of the Italian Penal Code to cover a wider protection of human rights according to interpretive solutions of § 6 of the German Penal Code.Settore IUS/17 - Diritto Penale
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Synthesis of New Materials

2013

Hybrid materials catalysis polyoxometalates metal organic frameworks carbon nanoformsSettore CHIM/06 - Chimica Organica
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Hybrid Observer for Indoor Localization with Random Time-of-Arrival Measurments

2018

In this work an indoor position estimation algorithm will be proposed. The position will be measured by means of a sensor network composed by fixed beacons placed on the indoor environment and a mobile beacon mounted on the object to be tracked. The mobile beacon communicates with all the fixed beacons by means of ultra wide-band signals, and the distance between them is computed by means of time of flight techniques. Moreover, inertial measurements will be used when the position measurements are not available. Two main problems will be considered in the proposed architecture: the fact that the beacons work with a lower update rate than the IMU, and that the mobile beacon can comunicate wit…

Hybrid observerInertial frame of referenceComputer scienceComputerSystemsOrganization_COMPUTER-COMMUNICATIONNETWORKSReal-time computingObserver (special relativity)BeaconTime of flightindoor localizationTime of arrivalSettore ING-INF/04 - AutomaticaInertial measurement unitsampled measurements.ComputerSystemsOrganization_SPECIAL-PURPOSEANDAPPLICATION-BASEDSYSTEMSWireless sensor network
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Stabilized Ru[(H2O)(6)](3+) in Confined Spaces (MOFs and Zeolites) Catalyzes the lmination of Primary Alcohols under Atmospheric Conditions with Wide…

2018

[EN] Imines are ubiquitous intermediates in organic synthesis, and the metal-mediated imination of alcohols is one of the most direct and simple methods for their synthesis. However, reported protocols lack compatibility with many other functional groups since basic supports/media, pure oxygen atmospheres, and/or released hydrogen gas are required during reaction. Here we show that, in contrast to previous metal-catalyzed methods, hexa-aqueous Ru(III) catalyzes the imination of primary alcohols with very wide functional group tolerance, at slightly acid pH and under low oxygen atmospheres. The inorganic metal complex can be supported and stabilized, integrally, within either faujasite-type …

HydrogenMetal-organic frameworkIminechemistry.chemical_element02 engineering and technology010402 general chemistryHeterogeneous catalysis01 natural sciencesRutheniumCatalysisCatalysischemistry.chemical_compoundQUIMICA ORGANICAImineZeoliteZeoliteGeneral Chemistry021001 nanoscience & nanotechnologyCombinatorial chemistry0104 chemical sciencesRutheniumchemistryMetal-organic frameworkOrganic synthesis0210 nano-technology
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Application of the new multimetric MMI_PL index for biological water quality assessment in reference and human-impacted streams (Poland, the Slovak R…

2014

Abstract A new multimetric MMI_PL index, which is based on the macroinvertebrate composition and combines six single key metrics, has already been implemented in Poland according to the requirements of the EU Water Framework Directive. The objectives of our survey were to assess the biological water quality using the new multimetric MMI_PL index in both reference and human-impacted streams, to analyze whether the values of the new multimetric index properly reflect the ecological status of the water in upland and mountain streams as well as to determine which environmental factors influence the distribution of benthic macroinvertebrates and the values of the metrics. The study was carried o…

HydrologyEcoregionWater Framework DirectiveBenthic zoneCanonical correspondence analysisSampling (statistics)Environmental scienceSTREAMSWater qualityAquatic ScienceMacrophyteLimnologica
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Assessing uncertainties in urban drainage models

2012

The current state of knowledge regarding uncertainties in urban drainage models is poor. This is in part due to the lack of clarity in the way model uncertainty analyses are conducted and how the results are presented and used. There is a need for a common terminology and a conceptual framework for describing and estimating uncertainties in urban drainage models. Practical tools for the assessment of model uncertainties for a range of urban drainage models are also required to be developed. This paper, produced by the International Working Group on Data and Models, which works under the IWA/IAHR Joint Committee on Urban Drainage, is a contribution to the development of a harmonised framewor…

HydrologyInternational working groupField (geography)Terminologylaw.inventionWater resourcesGeophysicsConceptual frameworkGeochemistry and PetrologyMultidisciplinary approachlawCLARITYDrainageEnvironmental planningPhysics and Chemistry of the Earth, Parts A/B/C
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