Search results for "FRAMEWORK"
showing 10 items of 942 documents
‘Cheaters and Stalkers’: Accusations in a classroom
2014
This article explores accusations as collaboratively accomplished in classroom peer interactions in the absence of a teacher. The analysis shows how the children use local classroom rules and teacher authority as resources and warrants to invoke multi-layered moral orders and identities, and hold one child accountable through accusations about their behavior. The accused children are categorized in a duplicative way with morally degrading descriptions and as out-group members. This article argues that understanding children’s accusations requires understanding of how such interactions compose and reflect the school context that is co-produced through the implementation of accountable ways …
Una propuesta didáctica para la implementación de la atenuación en español para los negocios
2018
El objetivo de este estudio es presentar una propuesta didáctica sobre la enseñanza de la atenuación en el ámbito de Español para los negocios, en Español como Lengua Extranjera. El diseño de esta propuesta tiene dos pilares: el análisis de materiales didácticos de E/LE de acuerdo con el Marco Común Europeo de Referencia en el nivel B1 y también se elabora un estudio de manuales. El resultado del análisis nos sirve para ver la frecuencia con la que se lleva al aula el fenómeno de la atenuación. Después, se propone una secuencia didáctica implementada en la Universitat de València. The aim of this study is to offer a didactic proposal for teaching mitigation in Spanish Business, in Spanish a…
Integrability Conditions: Recent Results in the Theory of Integrable Models
1990
This paper reports various results achieved recently in the theory of integrable models. These are summarised in the Fig.1! At the Chester meeting [1] two of the authors were concerned [1] with the local Riemann-Hilbert problem (double-lined box in the centre of Fig.1), its limit as a non-local Riemann-Hilbert problem used to solve classical integrable models in 2+1 dimensions (two space and one time dimensions) [2,3], and the connection of this Riemann-Hilbert problem with Ueno’s [4] Riemann-Hilbert problem associated with the representation of the algebra gl(∞) in terms of Z⊗Z matrices (Z the integers) and the solution of the K-P equations in 2+1. We were also concerned [1] with the const…
Triplet–Triplet Annihilation Upconversion in a MOF with Acceptor‐Filled Channels
2019
Abstract Photon upconversion has enjoyed increased interest in the last years due to its high potential for solar‐energy harvesting and bioimaging. A challenge for triplet–triplet annihilation upconversion (TTA‐UC) processes is to realize these features in solid materials without undesired phase segregation and detrimental dye aggregation. To achieve this, we combine a palladium porphyrin sensitizer and a 9,10‐diphenylanthracene annihilator within a crystalline mesoporous metal–organic framework using an inverted design. In this modular TTA system, the framework walls constitute the fixed sensitizer, while caprylic acid coats the channels providing a solventlike environment for the mobile a…
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework
2018
"Breathing" metal-organic frameworks (MOFs) that involve changes in their structural and physical properties upon an external stimulus are an interesting class of crystalline materials due to their range of potential applications including chemical sensors. The addition of redox activity opens up a new pathway for multifunctional "breathing" frameworks. Herein, we report the continuous breathing behavior of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, showing a reversible swelling (up to ca. 40% of the volume cell) upon solvent adsorption. Importantly, the planarity of the TTF linkers is influenced by the breathing behavior of the MOF, directly impacting on its electrochemical proper…
Present and Perspectives of Photoactive Porous Composites Based on Semiconductor Nanocrystals and Metal-Organic Frameworks
2021
This review focuses on the recent developments in synthesis, properties, and applications of a relatively new family of photoactive porous composites, integrated by metal halide perovskite (MHP) nanocrystals and metal-organic frameworks (MOFs). The synergy between the two systems has led to materials (MHP@MOF composites) with new functionalities along with improved properties and phase stability, thus broadening their applications in multiple areas of research such as sensing, light-harvesting solar cells, light-emitting device technology, encryption, and photocatalysis. The state of the art, recent progress, and most promising routes for future research on these photoactive porous composit…
Coordination networks incorporating halogen-bond donor sites and azobenzene groups
2016
Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a gues…
The Determinants of the Volatility of Fiscal Policy Discretion
2014
We investigate the determinants of the volatility of fiscal policy discretion. Using a linear dynamic panel dataset model for 104 countries from 1980 to 2006 and a system-GMM estimator,we find that more government instability, less democracy and presidentialist systems increase the volatility of the discretionary component of fiscal policy. Additionally, we show that countries with a larger size, a smaller degree of financial openness, and a stable exchange rate system are more insured against the uncertainty about the conduct of fiscal policy. Our results are robust to various regional dummy variables, diferent sub-sets of countries and the presence of high inflation and crisis episodes.
Enantiospecific Response in Cross-Polarization Solid-State Nuclear Magnetic Resonance of Optically Active Metal Organic Frameworks.
2020
We report herein on a NMR-based enantiospecific response for a family of optically active metal-organic frameworks. Cross-polarization of the 1H-13C couple was performed, and the intensities of the 13C nuclei NMR signals were measured to be different for the two enantiomers. In a direct-pulse experiment, which prevents cross-polarization, the intensity difference of the 13C NMR signals of the two nanostructured enantiomers vanished. This result is due to changes of the nuclear spin relaxation times due to the electron spin spatial asymmetry induced by chemical bond polarization involving a chiral center. These experiments put forward on firm ground that the chiral-induced spin selectivity e…
Stimuli-responsive hybrid materials: breathing in magnetic layered double hydroxides induced by a thermoresponsive molecule
2014
[EN] A hybrid magnetic multilayer material of micrometric size, with highly crystalline hexagonal crystals consisting of CoAl-LDH ferromagnetic layers intercalated with thermoresponsive 4-(4-anilinophenylazo)benzenesulfonate (AO5) molecules diluted (ratio 9 : 1) with a flexible sodium dodecylsulphate (SDS) surfactant has been obtained. The resulting material exhibits thermochromism attributable to the isomerization between the azo (prevalent at room temperature) and the hydrazone (favoured at higher temperatures) tautomers, leading to a thermomechanical response. In fact, these crystals exhibited thermally induced motion triggering remarkable changes in the crystal morphology and volume. In…