Search results for "FRAMEWORK"
showing 10 items of 942 documents
Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets
2012
Increasing dimensionality [from 2D (1) to 3D (2)] and T(C) [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic Mn(II)(2)Cu(II)(3) open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.
Lanthanide Discrimination with Hydroxyl-Decorated Flexible Metal–Organic Frameworks
2018
We report two new highly crystalline metal-organic frameworks (MOFs), derived from the natural amino acids serine (1) and threonine (2), featuring hexagonal channels densely decorated with hydroxyl groups belonging to the amino acid residues. Both 1 and 2 are capable of discriminating, via solid-phase extraction, a mixture of selected chloride salts of lanthanides on the basis of their size, chemical affinity, and/or the flexibility of the network. In addition, this discrimination follows a completely different trend for 1 and 2 because of the different locations of the hydroxyl groups in each compound, which is evocative of steric complementarity between the substrate and receptor. Last bu…
Tunable Spin-Crossover Behavior of the Hofmann-like Network {Fe(bpac)[Pt(CN) 4 ]} through Host-Guest Chemistry
2013
A study of the spin-crossover (SCO) behavior of the tridimensional porous coordination polymer {Fe(bpac)[Pt(CN)4]} (bpac=bis(4-pyridyl) acetylene) on adsorption of different mono- and polyhalobenzene guest molecules is presented. The resolution of the crystal structure of {Fe(bpac)[Pt(CN) 4]}A?G (G=1,2,4-trichlorobenzene) shows preferential guest sites establishing I?A?A?A?I? stacking interactions with the host framework. These host-guest interactions may explain the relationship between the modification of the SCO behavior and both the chemical nature of the guest molecule (electronic factors) and the number of adsorbed molecules (steric factors). Copyright © 2013 WILEY-VCH Verlag GmbH & …
The strategy formation process in the EFQM Excellence Model: a critical review and new perspectives
2011
The adoption of an integrative strategy formation process becomes a way of developing a strategic capability that contributes to generating positive results and sustainable competitive advantages. In today's environments, many companies are also using the EFQM Excellence Model (EEM) to try to develop such a strategic capability. This paper presents an exhaustive review of the literature on the strategic process debate and on the strategic capability of the EEM. As a result, we offer to practitioners a conceptual framework which shows the EEM as a useful driver to facilitate the development of an integrative strategy formation process, and we propose a set of dimensions and variables (the le…
Customer Environmental Values and Their Contribution to Loyalty in Industrial Markets
2015
Concern over the effect of industries on the natural environment is growing on a multitude of levels. This study examines the effects of how perceptions of (a) environmental values, (b) green image and (c) perceived value of industrial customers influence their loyalty towards suppliers in existing relationships, and how the length of B2B relationships may moderate these linkages. A conceptual framework is developed and data are collected from a global sample (N =121) of B2B customers. We find that both green image and perceived value have a direct positive link with customer loyalty and that environmental values are positively linked to the green image of the supplier. Moreover, the effect…
Process Modeling and Planning for Robotic Cold Spray Based Additive Manufacturing
2020
Cold spray (CS) is a solid-state coating deposition technology that has recently been applied as an additive manufacturing (AM) process to fabricate individual components. This potential AM process is attracting more and more attention because of its advantages: high-forming efficiency, low temperature, and no phase changing of materials. These advantages make CS able to form large-volume objects to become an efficient and effective AM process. Nowadays, new advances in cold spray additive manufacturing (CSAM) call for new process implementation to improve the manufacturing accuracy and flexibility. Therefore, the purpose of this study is to enhance CS-based AM through the modeling and plan…
The integration of information technologies in the knowledge based organizations
2016
Relations between the users' expertise, complexity of tasks to be solved by knowledge-based organizations and mission of smart information systems, is a multi-dimensional structure that should provide the necessary conceptual framework of sustainable integrated smart development. The users of smart information systems face a variety of problems, such as: system access, data recovery, identifying and retrieving a specific document and its contents, and difficulties associated with understanding and interpreting of the used system on stages and methods following to be used, respectively problems on understanding the meaning of information provided. Using smart information systems and smart da…
Polyoxometalate Metal–Organic Frameworks: Keggin Clusters Encapsulated into Silver-Triazole Nanocages and Open Frameworks with Supercapacitor Perform…
2019
To investigate the relationship between the structures of polyoxometalate host–guest materials and their energy-storage performance, three novel polyoxometalate-based metal–organic compounds, [Ag10...
Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene
2017
Covalent Organic Frameworks (COFs) based on polyimine with several metal ions (FeIII, CoII and NiII) adsorbed into their cavities have shown the ability to generate N-doped porous graphene from their pyrolysis under controlled conditions. These highly corrugated and porous graphene sheets exhibit high values of specific capacitance, which make them useful as electrode materials for supercapacitors.
The modes of supply net management: a capability view
2007
Purpose – The purpose of this paper is to identify the key capabilities required in supply net management.Design/methodology/approach – Uses the Management Capability Framework to break down supply net management into different modes and identify capabilities required in them.Findings – Reveals that the supply activity of companies increasingly takes place in intentionally developed strategic networks called supply nets. These networks pose distinctive challenges for supply chain management. Identifies four diverse but simultaneously extant modes of management in the supply net context, and discusses the key managerial capabilities in each mode.Originality/value – Provides a conceptual fram…