Search results for "FUNCTIONAL"
showing 10 items of 4822 documents
Instead of an Editorial: Mission Statements by Representatives of Both Fields
2012
The following mission statements by linguists and literary scholars working in different institutional and cultural contexts and at different stages of their careers are intended to map out the terrain covered by this journal. They tell similar stories about how these scholars came to cross the disciplinary boundary that too often divides their two fields, and they reveal a number of shared interests and emphases. But they also highlight the diversity of methodologies to which this journal is open – from metrics and stylistics to the cognitive sciences and Systemic Functional Grammar. The hopes and expectations voiced by the authors are partly pragmatic, expressing the wish that the journal…
Instability of the faecal microbiota in diarrhoea-predominant irritable bowel syndrome
2013
The irritable bowel syndrome (IBS) is a functional gastrointestinal disorder with a largely unknown aetiology and a wide range of symptoms. Most cross-sectional studies carried out so far suggest subtle alterations in the structure of the intestinal microbiota that are barely reproduced, partly because of the high inter-subject variation in the community composition and disorder-specific features. We performed a longitudinal study to explore the within-subject variation in the faecal microbiota in two patients with IBS classified into the diarrhoea subtype and the healthy spouse of one of them. Faecal communities were monitored over 6-8 weeks and analysed through metagenomic and metatranscr…
Diastereoselective Synthesis of Dialkylated Bis(phosphino)ferrocenes: Their Use in Promoting Silver-Mediated Nucleophilic Fluorination of Chloroquino…
2017
International audience; The diastereoselective synthesis of dialkylated ferrocenyl bis(phosphane)s bearing aryl, alkyl, and hetero- or polycyclic substituents on the phosphino groups is reported, together with their characterization in the solid state by X-ray structure analysis and in solution by multinuclear NMR spectroscopy. Introduction of various alkyl groups on the ferrocene backbone, namely, tert-butyl, isopropyl, and trimethylsilyl, has a significant influence on the stereoselectivity of the ensuing lithiation/phosphination reactions. Only the introduction of the tert-butyl groups ensures both a high yield and perfect diastereoselectivity, which leads to the exclusive formation of t…
Electronic fluxes during diels-alder reactions involving 1,2-benzoquinones: mechanistic insights from the analysis of electron localization function …
2012
By means of the joint use of electron localization function (ELF) and Thom's catastrophe theory, a theoretical analysis of the energy profile for the hetero-Diels-Alder reaction of 4-methoxy-1,2-benzoquinone 1 and methoxyethylene 2 has been carried out. The 12 different structural stability domains obtained by the bonding evolution theory have been identified as well as the bifurcation catastrophes (fold and cusp) responsible for the changes in the topology of the system. This analysis permits finding a relationship between the ELF topology and the evolution of the bond breaking/forming processes and electron pair rearrangements through the reaction progress in terms of the different ways o…
Nutrients associated with diseases related to aging: a new healthy aging diet index for elderly population
2018
espanolIntroduccion: suelen usarse diversos indices dieteticos para medir la calidad de la nutricion en edades avanzadas. Sin embargo, ninguno de ellos fue disenado para evaluar la nutricion con el objetivo de evitar discapacidades en la poblacion anciana. Objetivos: identificar en la literatura cientifica los “nutrientes e ingestas” involucrados en el envejecimiento, asi como proponer un nuevo indice, considerando esta informacion, que sirva para evaluar la calidad de la nutricion con objeto de prevenir enfermedades relacionadas con el envejecimiento. Metodos: se realizo una revision bibliografica, obteniendo informacion sobre los nutrientes asociados con el envejecimiento. Todos estos nut…
Effect of Supplementation with Wheat Bran Aqueous Extracts Obtained by Ultrasound-Assisted Technologies on the Sensory Properties and the Antioxidant…
2015
Phenolic compounds have antioxidant properties and activate endogenous detoxification defense systems able to scavenge the reactive species of oxygen. The external layers of wheat caryopsis, largely constituting by-products of the milling industry such as bran and various middlings, contain relevant amounts of phenolic compounds. The aim of the research has been to evaluate the effect of supplementation with wheat bran aqueous extracts, obtained by ultrasound-assisted technologies, on the sensory properties and antioxidant activity of dry pasta. The HPLC-DAD characterization of the extract evidenced the presence of ferulic and p-coumaric acids. The supplemented pasta showed significantly h…
Isolation and Functional Analysis of Organelles
2006
Matemātika
1994
Precise Characterization of the Rich Structural Landscape Induced by Pressure in Multifunctional FeVO4
2020
We have studied the high-pressure behavior of FeVO4 by means of single-crystal X-ray diffraction (XRD) and density functional theory (DFT) calculations. We have found that the structural sequence o...
Defect interaction and local structural distortions in Mg-doped LaGaO3: A combined experimental and theoretical study
2017
A combined experimental and theoretical study of Mg-doped LaGaO3 electrolyte was carried out, with the aim to unveil the interaction between oxygen vacancy (Vo) and perovskite B site cations. LaGaO3 (LG) and LaGa0.875Mg0.125O2.938 (LGM0125) samples were comprehensively characterized by X-ray absorption spectroscopy (XAS) and X-ray diffraction, in order to investigate short- and long-range structures of both undoped and Mg-doped materials. XAS analysis evidenced a preferential Ga-Vo interaction in LGM0125, confirmed by periodic hybrid density functional theory calculations, which were combined with a symmetry-independent classes (SICs) approach in order to (a) obtain a detailed picture of th…