Search results for "Farmaceutica"

showing 10 items of 582 documents

Composizione e attività biologica di “idrolati” di agrumi

Gli idrolati, o acque aromatiche, sono prodotti naturali ricavati dalla distillazione di piante o parti di piante fresche che conservano intatte le loro proprietà e possono essere utilizzati a diverso scopo1. Essi sono comunemente considerati un sottoprodotto degli oli essenziali, ma in realtà, data la diversa composizione e la conseguente maggiore delicatezza, hanno un loro apprezzabile utilizzo, legato comunque al mantenimento delle proprietà delle piante da cui derivano. Nell’industria agrumaria gli idrolati sono il risultato della produzione degli oli essenziali attraverso spremitura a freddo delle bucce degli agrumi e sono considerati un rifiuto da smaltire. Lo studio della composizion…

Settore CHIM/10 - Chimica Degli AlimentiIdrolatiMIC.Settore AGR/13 - Chimica AgrariaGC-MSArancia di RiberaSettore BIO/19 - Microbiologia GeneraleSettore CHIM/08 - Chimica FarmaceuticaLC-MS
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Atractyligenin chemistry. Part 4: Synthesis of the 15β-ol epimer of atractyligenin

1996

The oxidation with PCC of atractyligenin 3, the aglicone of the toxic glycoside 1 isolated from Atractylis gummifera L., led to the 15-oxo-derivative 6, together with a small amount of 2,15-dioxoderivative 5, with a selective oxidation of the allylic 15-OH group of the molecule. Further reduction with NaBH4 and KOH hydrolysis gave stereoselectively the 15β-ol epimer of atractiligenin 9.

Settore CHIM/10 - Chimica Degli Alimentiatractyligenin-15β-OH epimerSettore CHIM/08 - Chimica Farmaceutica19-nor-kaurene compound
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Biocompatibility and biodegradability of electrospun phea-pla scaffolds: Our preliminary experience in a murine animal model

2012

We obtained a nano-fibrillar scaffold starting from a polymeric solution which, through electrospinning, gave a biodegradable material with optimal mechanical features and the capacity to allow cell adhesion. In this paper we report the in-vivo application on a murine animal model of two electrospun biodegradable materials, specifically designed to create tubular structures. In one case PHEA-PLA was co-spun with silk fibroin (Fibro-PHEAPLA) by a parallel electrospinning process to obtain a scaffold with two different polymeric fibers. In the other case, PHEA-PLA was mixed with polycaprolactone (PCLPHEA-PLA) to obtain a hybrid fibers scaffold. The in-vitro assay showed fibroblast colonizatio…

Settore MED/18 - Chirurgia GeneralePHEA-PLAElectrospinningThree-dimensional scaffoldElectrospinning; Three-dimensional scaffolds; PHEA-PLASettore CHIM/08 - Chimica Farmaceutica
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CONTRIBUTO ALLA CONOSCENZA DELLE VERDURE SELVATICHE RACCOLTE E CONSUMATE IN SICILIA: LE CICORIE

2011

SiciliaSettore BIO/15 - Biologia Farmaceuticacicorie
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Studio fitochimico delle popolazioni italiane di Artemisia alba Turra (Asteraceae) con particolare riferimento a quelle della Sicilia.

2011

Sicilia.Artemisia alba Turra (Asteraceae)studio fitochimicoSettore BIO/15 - Biologia Farmaceutica
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Phytochemical characterization and antioxidant activity of the aerial part extracts from two species of Matthiola wild in Sicily: Matthiola sinuata a…

2022

As part of a project aimed at investigating the specific and intraspecific taxa of Matthiola which grow spontaneously in Sicily (Italy), in this work our research has been focused on Matthiola tricuspidata and Matthiola sinuata. The phenolic and volatile compounds of the hydroalcoholic extracts from the aerial parts of the selected species have been characterized by HPLC-PDA/ESI-MS and SPME-GC/MS analyses. Moreover, the antioxidant capacity in vitro (1,1-diphenyl-2-picrylhydrazil (DPPH), reducing power and Fe2+ chelating activity assays) and the toxicity (Artemia salina lethality bioassay) of the extracts were investigated. The phytochemical analyses highlighted quite different phenolic and…

Sicilian vascular floraArtemia salina bioassaySettore BIO/02 - Botanica Sistematicaantioxidant propertiePlant ScienceSettore BIO/15 - Biologia FarmaceuticaMatthiolabioactive compoundEcology Evolution Behavior and Systematics
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4,5,6,7-Tetrahydro-isoxazolo-[4,5-c]-pyridines as a new class of cytotoxic Hsp90 inhibitors.

2014

Hsp90 is considered an interesting therapeutic target for anticancer drug development. Here we describe a new class of 4,5,6,7-tetrahydro-isoxazolo-[4,5-c]-pyridine compounds. A small library of derivatives has been synthesized and investigated. Some reported compounds show interesting properties combining both notable binding to Hsp90 and potent cell growth inhibitory activity. N-5 substitution with a 2,4 resorcinol carboxamide appears crucial for activity. Moreover, a derivative bearing a hydroxamic acid residue bound to C-3 amide portion was found to inhibit both Hsp90 and HDAC6.

Spectrometry Mass Electrospray IonizationMagnetic Resonance Spectroscopymedicine.drug_classStereochemistryPyridinesCarboxamideApoptosisResorcinolAnti-cancer drugschemistry.chemical_compoundResidue (chemistry)AmideDrug DiscoveryHeat shock protein 90 Anti-cancer drugs 4567-Tetrahydro-isoxazolo-[45-c]- pyridinesmedicineCytotoxic T cellHumansHeat shock protein 90HSP90 Heat-Shock ProteinsPharmacologyHydroxamic acidChemistryCell growthOrganic ChemistryGeneral MedicineNuclear magnetic resonance spectroscopy4 5 6 7-Tetrahydro-isoxazolo-[4 5-c]-pyridinesFlow CytometrySettore CHIM/08 - Chimica Farmaceuticahsp90Settore BIO/14 - Farmacologia4 5 6 7-Tetrahydro-isoxazolo-[4 5-c]-pyridines; Anti-cancer drugs; Heat shock protein 90;K562 CellsCell DivisionEuropean journal of medicinal chemistry
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ANALISI ECONOMICA RETROSPETTIVA SULLE MISURE DI CONTENIMENTO DELLA SPESA FARMACEUTICA DELL’ASP 1 DI AGRIGENTO RELATIVE AL TRIENNIO 2010/2011/2012

2013

Introduzione. Le misure di contenimento della spesa farmaceutica sono state le principali prerogative previste dal Piano di Rientro della Regione Sicilia ( adempimento A.1.2), in tal senso le realtà delle singole ASP si sono adeguate alle direttive regionali mostrando una classifica tra le Asp siciliane che vedono come protagonista virtuosa l’Asp di Agrigento, prima in classifica. La disamina dei dati fa riferimento al triennio 2010/2011/2012. Materiali e metodi. La rilevazione concerne farmaci rimborsati dal SSN ed erogati tramite canale convenzionale privato, farmaci distribuiti direttamente e quelli utilizzati in ambito ospedaliero nel triennio 2010/2011/2012, attraverso report sulla spe…

Spesa FarmaceuticaASP 1 AgrigentoSettore BIO/14 - Farmacologia
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Novel chemical countermeasures against staphylococcal biofilms

2010

Some natural and synthetic related pyrrolomycins, a family of halogenated pyrrole antibiotics, showed anti-biofilm properties in vitro at low concentration (0.045μg/mL) against preformed staphylococcal biofilms. Moreover, considering the human cell toxicity, the selectivity indexes (ratio of cytotoxicity to antibiofilm activity) of some of them were very interesting. The present study aims to investigate if the pyrrolomycins could also prevent staphylococcal biofilm formation. The evaluation of S.aureus ATCC 25923 biofilm formation inhibition was conducted by safranin staining method. At tested concentrations of 0.18, 0.09, 0.045 μg/mL (concentrations much lower than MIC value determined on…

Staphylococcus aureus biofilm antimicrobial agentsSettore BIO/19 - Microbiologia GeneraleSettore CHIM/08 - Chimica Farmaceutica
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Pyrrolomycins as antimicrobial agents. Microwave-assisted organic synthesis and insights into their antimicrobial mechanism of action

2019

Abstract New compounds able to counteract staphylococcal biofilm formation are needed. In this study we investigate the mechanism of action of pyrrolomycins, whose potential as antimicrobial agents has been demonstrated. We performed a new efficient and easy method to use microwave organic synthesis suitable for obtaining pyrrolomycins in good yields and in suitable amount for their in vitro in-depth investigation. We evaluate the inhibitory activity towards Sortase A (SrtA), a transpeptidase responsible for covalent anchoring in Gram-positive peptidoglycan of many surface proteins involved in adhesion and in biofilm formation. All compounds show a good inhibitory activity toward SrtA, havi…

Staphylococcus aureusClinical BiochemistryPharmaceutical ScienceMicrobial Sensitivity Testsmedicine.disease_causeSettore BIO/19 - Microbiologia Generale01 natural sciencesBiochemistrychemistry.chemical_compoundBacterial ProteinsDrug DiscoverymedicinePyrrolesEnzyme InhibitorsMicrowavesMolecular BiologyEnzyme Assays010405 organic chemistryChemistryOrganic ChemistryBiofilmN-Acetylmuramoyl-L-alanine AmidaseAntimicrobialAminoacyltransferasesAntimicrobial resistance Pyrrolomycins Sortase A Staphylococcus aureus In-silico docking studies MAOS Pharmacokinetics studies Murein hydrolase activitySettore CHIM/08 - Chimica Farmaceutica0104 chemical sciencesAnti-Bacterial AgentsMolecular Docking Simulation010404 medicinal & biomolecular chemistryCysteine EndopeptidasesBiochemistryMechanism of actionDocking (molecular)Staphylococcus aureusSettore CHIM/03 - Chimica Generale E InorganicaSortase ABiofilmsPseudomonas aeruginosaMolecular MedicineOrganic synthesisPeptidoglycanmedicine.symptom
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