Search results for "Figur"
showing 10 items of 1122 documents
Resolution of β-aminophosphines with chiral cyclopalladated complexes
2005
Abstract Resolution of the racemic chiral β-aminophosphines Ph 2 PCH 2 CH(Ph)NH(Ar) ( L 1 for Ar = C 6 H 5 and L 2 for Ar = 2,6-C 6 H 3 i Pr 2 ) has been investigated by use of different cyclopalladated complexes as chiral agents. The resulting complexes afford diastereomeric adducts in a 1:1 ratio. After successive crystallizations from ethanol, a d.e. of 98% was achieved for one aminophosphine palladium complex, while no significant d.e. was obtained after crystallizations from chlorinated solvents. The X-ray structure analysis has pointed out intermolecular hydrogen interactions N–H⋯Cl between the P,N ligand and the chloride ion, which are responsible for the formation and stabilization …
Preparation and structure of the 17-electron (η5-C5R5)Mo(OH)2(dppe) (R=Me, Et) organometallic compounds containing two gem-terminal hydroxide ligands
2000
International audience; Oxidation of (η5-C5R5)MoH3(dppe) (R=Me, Et) by Cp2Fe+ in wet THF leads to the formation of the corresponding (η5-C5R5)Mo(OH)2(dppe). These compounds show a low-potential reversible oxidation wave. The structure of the C5Et5 complex has been confirmed by X-ray diffraction methods: triclinic; space group ; a=11.030(1); b=12.533(1); c=16.241 (1) Å; α=68.585(7); β=75.197(5); γ=83.991(7)°; V=2020.6(3) Å3; Z=2; Dcalc=1.324 g cm−3, μ(Mo–Kα)=0.441 mm−1; R1=0.0325; wR2=0.0875 for 415 parameters and 6823 independent reflections [Rint=0.0177] with I=2σ(I). The molecule shows a four-legged piano-stool geometry with two terminal OH ligands in a relative trans configuration. The c…
An MDE Approach for Rapid Prototyping and Implementation of Dynamic Reconfigurable Systems
2015
This article presents a co-design methodology based on RecoMARTE, an extension to the well-known UML MARTE profile, which is used for the specification and automatic generation of Dynamic and Partially Reconfigurable Systems-on-Chip (DRSoC). This endeavor is part of a larger framework in which Model-Driven Engineering (MDE) techniques are extensively used for modeling and via model transformations, generating executable models, which are exploited by implementation tools to create reconfigurable systems. More specifically, the methodological aspects presented in this article are concerned with expediting the conception and implementation of the hardware platform and the integration of corre…
ITIL rīki IT pārvaldībā
2020
Maģistra darbā tiek apskatīti nosacījumi labas IT pārvaldības nodrošināšanai, vadoties pēc ITIL pamatprincipiem. Darbā tiek praktiski analizēti IT pārvaldības nodrošināšanas paņēmieni trīs reālos uzņēmumos. Analīzes rezultātā tiek veidoti un ieviesti pielāgojumi uzņēmumos esošajiem rīkiem, lai nodrošinātu IT pārvaldības atbilstību ITIL labajai praksei, un praktiski izstrādāti pielāgojumi, kuru ieviešanu var plānot nākotnē. Pielāgojumu plānošanas un ieviešanas rezultāti darba noslēgumā pamato ITIL rīku nepieciešamību un to pielāgošanu veiksmīgas IT pārvaldības nodrošināšanai uzņēmumos. Gan darba teorētiskās, gan praktiskās daļas pamatā ir izmantotas ITIL labās prakses vadlīnijas.
MEMORIE DAGLI SCAVI PER UN'ARCHEOLOGIA DELLA LETTERATURA IN GESUALDO BUFALINO
2022
The essay reflects on the lexical dissemination of terms belonging to the metaphorical area of 'recovery,' 'rebirth,' and 'rediscovery' in Bufalino's work beginning with Diceria dell'untore, in order to try to demonstrate the legacy of a private experience, the one related to the writing of his dissertation during the years of war and illness, in the transfigured one of literary reworking.
Promuovere negli uomini la scelta di prepararsi all’esercizio della professione di maestro di scuola primaria
2022
The sixth principle of the Charte de la Ligue Internationale de l’Education Nouvelle of 1921 emphasizes the concept of coeducation. The definition of this concept provides interesting insights to launch a proactive debate on the need to increase the male presence in primary school teaching staff. First of all, some results of empir- ical research that support the request to increase the number of male teachers in the primary school are displayed. Secondly, the most significant measures adopted by some States to promote the figure of the male primary school teacher are described. Finally, a few proposals are made on what could be done in Italy.
<title>Achieving high performances at lower cost for real-time image rotation by using dynamic reconfiguration</title>
2001
FPGA components are widely used today to perform various algorithms (digital filtering) in real time. The emergence of Dynamically Reconfigurable (DR) FPGAs made it possible to reduce the number of necessary resources to carry out an image processing application (tasks chain). We present in this article an image processing application (image rotation) that exploits the FPGA's dynamic reconfiguration feature. A comparison is undertaken between the dynamic and static reconfiguration by using two criteria, cost and performance criteria. For the sake of testing the validity of our approach in terms of Algorithm and Architecture Adequacy , we realized an AT40K40 based board ARDOISE.
Experimental design method to the weld bead geometry optimization for hybrid laser-MAG welding in a narrow chamfer configuration
2017
International audience; The work presented in this paper relates to the optimization of operating parameters of the welding by the experimental design approach. The welding process used is the hybrid laser-MAG welding, which consists in combining a laser beam with an MAG torch, to increase the productivity and reliability of the chamfer filling operation in several passes over the entire height of the chamfer. Each pass, providing 2 mm deposited metal and must provide sufficient lateral penetration of about 0.2 mm. The experimental design method has been used in order to estimate the operating parameters effects and their interactions on the lateral penetration on one hand, and to provide a…
Theoretical approaches for geometric optimization of urban forms : towards a fractal development of the city
2017
This thesis aims to establish a urban structure that optimizes inhabitant's preferences. In other words, we want to find out which city shape answers the best the residents' aspirations, according to their consumption preferences for urban and green amenities. By considering a theoretical field of study and by characterizing the population by a Cobb-Douglas behavioral pattern, we will build step by step a city, assuming successive arrivais of new individuals, in order to find out which geometric shape gives the most suitable answer. The final goal of this thesis is there to suggest a city with a fractal shape as an appro- priate answer to the resident's expectations. We will show that this …
Indole Diterpenoids from an Endophytic Penicillium sp.
2019
A chemical investigation of the endophyte Penicillium sp. (strain ZO-R1-1), isolated from roots of the medicinal plant Zingiber officinale, yielded nine new indole diterpenoids (1-9), together with 13 known congeners (10-22). The structures of the new compounds were elucidated by 1D and 2D NMR analysis in combination with HRESIMS data. The absolute configuration of the new natural products 1, 3, and 7 was determined using the TDDFT-ECD approach and confirmed for 1 by single-crystal X-ray determination through anomalous dispersion. The isolated compounds were tested for cytotoxicity against L5178Y, A2780, J82, and HEK-293 cell lines. Compound 1 was the most active metabolite toward L5178Y ce…