Search results for "Fins"

Protection of high-density polyethylene-silicon composites from ultraviolet-visible photodegradation

2017

[EN] The extent of the ultraviolet¿visible (UV¿vis) photoirradiation effect on high-density polyethylene (HDPE) and HDPE¿sili-con (Si) composites is reported in terms of the addition of Si microparticles at contents of 0.1, 1, and 5 wt %. A standard acceleratedUV-vis exposure was applied over 2750 h, corresponding to 22 months in Florida. Thermogravimetry, differential scanning calorimetry,and Fourier transform infrared spectroscopy were used as reliable techniques for monitoring the quality of the HDPE-Si composites. Theincreasing addition of Si microparticles delayed the photodegradation of the HDPE¿Si composites. Because of their strong light-scattering effects, Si microparticles blocked…

Sub-Finsler Geodesics on the Cartan Group

2018

This paper is a continuation of the work by the same authors on the Cartan group equipped with the sub-Finsler $\ell_\infty$ norm. We start by giving a detailed presentation of the structure of bang-bang extremal trajectories. Then we prove upper bounds on the number of switchings on bang-bang minimizers. We prove that any normal extremal is either bang-bang, or singular, or mixed. Consequently, we study mixed extremals. In particular, we prove that every two points can be connected by a piecewise smooth minimizer, and we give a uniform bound on the number of such pieces.

Infinitesimal Hilbertianity of Weighted Riemannian Manifolds

2018

AbstractThe main result of this paper is the following: anyweightedRiemannian manifold$(M,g,\unicode[STIX]{x1D707})$,i.e., a Riemannian manifold$(M,g)$endowed with a generic non-negative Radon measure$\unicode[STIX]{x1D707}$, isinfinitesimally Hilbertian, which means that its associated Sobolev space$W^{1,2}(M,g,\unicode[STIX]{x1D707})$is a Hilbert space.We actually prove a stronger result: the abstract tangent module (à la Gigli) associated with any weighted reversible Finsler manifold$(M,F,\unicode[STIX]{x1D707})$can be isometrically embedded into the space of all measurable sections of the tangent bundle of$M$that are$2$-integrable with respect to$\unicode[STIX]{x1D707}$.By following the…

Universal infinitesimal Hilbertianity of sub-Riemannian manifolds

2019

We prove that sub-Riemannian manifolds are infinitesimally Hilbertian (i.e., the associated Sobolev space is Hilbert) when equipped with an arbitrary Radon measure. The result follows from an embedding of metric derivations into the space of square-integrable sections of the horizontal bundle, which we obtain on all weighted sub-Finsler manifolds. As an intermediate tool, of independent interest, we show that any sub-Finsler distance can be monotonically approximated from below by Finsler ones. All the results are obtained in the general setting of possibly rank-varying structures.

Lasten media-arjen valot ja varjot : Mediamuffinssi lasten mediasuhteen kuvastajana

2008

Design, synthesis, and biological evaluation of nonsteroidal cycloalkane[d]isoxazole-containing androgen receptor modulators.

2012

We report here the design, preparation, and systematic evaluation of a novel cycloalkane[d]isoxazole pharmacophoric fragment-containing androgen receptor (AR) modulators. Cycloalkane[d]isoxazoles form new core structures that interact with the hydrophobic region of the AR ligand-binding domain. To systematize and rationalize the structure-activity relationship of the new fragment, we used molecular modeling to design a molecular library containing over 40 cycloalkane[d]isoxazole derivatives. The most potent compound, 4-(3a,4,5,6,7,7a-hexahydrobenzo[d]isoxazol-3-yl)-2-(trifluoromethyl)benzonitrile (6a), exhibits antiandrogenic activity significantly greater than that of the most widely used …

Finely Tuned Temperature-Controlled Cargo Release Using Paraffin-Capped Mesoporous Silica Nanoparticles

2011

[EN] Trapped: Mesoporous silica nanoparticles were loaded with a fluorescent guest and functionalized with octadecyltrimethoxysilane. The alkyl chains interact with paraffins, which build a hydrophobic layer around the particle (see picture). Upon melting of the paraffin, the guest molecule is released, as demonstrated in cells for the guest doxorubicin. The release temperature can be tuned by choosing an appropriate paraffin. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Carbon nanorings: A challenge to theoretical chemistry

2006

High-level quantum-chemical methods show that the binding in the inclusion complex of hexamethylbenzene (HMB) in 6-cycloparaphenilacetylene (6-CPPA) cannot be explained only in terms of electrostatic interactions - caused by the polarization associated to curved π-conjugated systems - and the inclusion of dispersion forces is definitely needed. The theoretical description of van der Waals interactions is notoriously complicated and in fact some DFT methods cannot even predict the existence of the relatively small supramolecular nanoring studied here. However, ab initio MP2 calculations agree with experimental data and show that, in the considered complex, the HMB fragment is placed at the …

Traumets rom : En analyse av Sofi Oksanens Utrenskning

2019

Masteroppgave nordisk språk og litteratur NO500 - Universitetet i Agder 2019 This thesis is an analysis of Sofi Oksanen’s novel Utrenskning [Purge] (2011), with a particular focus on what significance the various rooms convey in the narrative of trauma. Utrenskning relates stories of occupation, violence and abuse through three generations of Estonian women, and how this has led totrauma, fear, and damaged relationships. The study’s primary theory is that the novel interprets aspects of traumatic experiences through a spatial point of view. One distinctive feature of Utrenskning is that almost all of the action plays out within different rooms. The rooms have different functions for the nov…

Synthesis and olefin homo- and copolymerization behavior of new vanadium complexes bearing [OSSO]-type ligands

2017

Novel vanadium complexes bearing [OSSO]-type ligands having two phenolato units linked through the –CH2S(CH2)4SCH2– (1V) or –CH2S(CH2)2SCH2– (2V) bridge are synthesized with good yields by reacting a deprotonated ligand with VCl4. They are then used in ethylene (co)polymerization after activation with EtAlCl2 and Et2AlCl. In the presence of EtAlCl2, both complexes promote ethylene polymerization with very high activities, over 4 × 107 g/(mol h), leading to PEs with high molecular weight and narrow molecular weight distribution. The prepared complexes exhibit lower activity for ethylene/1-octene copolymerization. It is also revealed that the catalyst based on the –CH2S(CH2)4SCH2– bridged com…