Search results for "Flow Rate"
showing 10 items of 166 documents
Correction of the deviations in the retention times with Chromolith columns associated to the flow rate: Implications in the modelling of the retenti…
2011
In a previous work (J. Sep. Sci. 2009, 32, 2793-2803), we reported an interpretive optimisation approach to achieve maximal resolution in minimal analysis time, based on models describing the retention and peak shape as a function of mobile phase composition and flow rate. The method was applied to the separation of a group of basic drugs in a Chromolith column. In that work, we found that the retention factors were sensitive to the flow rate. The reason of the observed deviations in retention times is the increase in the column volume at the applied pressure, which decreases the linear velocity inside the column. This behaviour forced to include a correction term in the model that describe…
Conical Two-Phase Swirl Flow Atomizers—Numerical and Experimental Study
2021
This paper presents the results of numerical simulations for the developed and discussed conical two-phase atomizers with swirl flow, differing in the ratio of the height of the swirl chamber to its diameter. Experiments were carried out for SAN-1 with HS/DS = 1 and SAN-2 with HS/DS = 4 atomizers. The study was conducted over a range of Reynolds number for liquid ReL = (1400
Natural Convection Cooling of a Hot Vertical Wall Wet by a Falling Liquid Film
2008
Abstract The system studied is a plane channel in which one of the two vertical walls is kept at an arbitrary temperature profile and may be partially or completely wet by a falling liquid film, while the opposite wall is adiabatic. Air from the environment flows along the channel with a mass flow rate which depends on the balance between hydraulic resistances and buoyancy forces. These latter, in their turn, depend on the distribution of temperature and humidity (hence, density) along the channel and eventually on the heat and mass transferred from wall and film to the humid air. A simplified computational model of the above system was developed and applied to the prediction of relevant qu…
Using CFD to derive reduced order models for heat transfer in particle curtains
2015
3–D Eulerian–Eulerian CFD is used to simulate convective heat transfer in free falling particle curtains. Total heat loss for curtaining particles is compared to heat loss for isolated single particles. Spherical silica particles with density of 2,634 kg/m³ at 400 K (200 µm, 400 µm and 600 µm) flow at approximately 0.041 kg/s to 0.2 kg/s through a narrow slot in a rectangular box (0.45 m × 0.9 m × 0.225 m) filled with ambient air. The slot sizes through which the particles enter the rectangular box were 10 to 80 mm wide. Modifying the slot size at 0.041 kg/s for 400 µm particles can lead to 13% increases in rates of convective heat transfer per unit mass. A reduced order model was developed…
Mixed MHD convection and Tritium transport in fusion-relevant configurations
2005
Mixed MHD flow and Tritium transport were computed for a slender poloidal duct, representative of a DEMO HCLL blanket element. 2-D flow and temperature fields were computed in the duct's cross section under the assumption of parallel, fully developed flow, while Tritium concentration C was found by solving a fully 3-D problem with simplifying assumptions at the duct's ends. The spatial distribution of C depended on the intensity and direction of the forced flow. Significant peak factors were obtained if the net flow rate was so low that re-circulation occurred; C maxima were attained near the walls for upward flow, in the core region for downward flow.
Cathodic reduction of hexavalent chromium coupled with electricity generation achieved by reverse-electrodialysis processes using salinity gradients
2014
Abstract A new approach for the simultaneous generation of electric energy and the treatment of waters contaminated by recalcitrant pollutants using salinity gradients was proposed. Reverse electrodialysis allows for the generation of electric energy from salinity gradients. Indeed, the utilization of different salt concentrations gives a potential difference between the electrodes which allows the generation of electric energy by using suitable electrolytes and an external circuit. The simultaneous generation of electric energy and the treatment of waters contaminated by Cr(VI) was successfully achieved for the first time by reverse electrodialysis processes using salinity gradients and pr…
Non-specific bronchial hyper-responsiveness in children with allergic rhinitis: relationship with the atopic status
2003
An increased prevalence of bronchial hyper-responsiveness (BHR) has been demonstrated in children from a general population, and in non-asthmatic adults with allergic rhinitis. Thus, also children with allergic rhinitis are expected to be at higher risk of BHR. We evaluated the prevalence of BHR in a sample of non-asthmatic children with allergic rhinitis by means of the methacholine (Mch) bronchial challenge, and by monitorizing the airway patency using the daily peak expiratory flow variability (PEFv). Fifty-one children (ranged 6-15 years of age) with allergic rhinitis, ascertained by skin prick test to inhalant allergens, underwent a 14-day peak expiratory flow monitoring, and a Mch bro…
Development and characterization of a thermal inkjet-based aerosol generator for micro-volume sample introduction in analytical atomic spectrometry
2011
A novel system for the introduction of liquid samples into analytical plasmas for atomic spectrometric analysis is presented in this manuscript for the first time. The proposed “drop-on-demand” (DOD) aerosol generator is based on the use of a modified thermal inkjet cartridge. This system employs a lab-built microcontroller, which allows accessing all parameters important for driving the dosing cartridge for the generation of pL-droplets from sample volumes in the μL range. The droplet generation frequency, thus the resulting liquid flow rate, is variable over a wide range from the generation of isolated droplets up to a theoretical flow rate of approximately 2 mL min−1, with parallel opera…
Sequential injection spectrophotometric determination of oxybenzone in lipsticks
2001
A sequential injection (SI) procedure for the spectrophotometric determination of oxybenzone in lipsticks is reported. The colorimetric reaction between nickel and oxybenzone was used. SI parameters such as sample solution volume, reagent solution volume, propulsion flow rate and reaction coil length were studied. The limit of detection was 3 microg ml(-1). The sensitivity was 0.0108+/-0.0002 ml microg(-1). The relative standard deviations of the results were between 6 and 12%. The real concentrations of samples and the values obtained by HPLC were comparable. Microwave sample pre-treatment allowed the extraction of oxybenzone with ethanol, thus avoiding the use of toxic organic solvents. E…
Determination of total arsenic in soft drinks by hydride generation atomic fluorescence spectrometry
2007
Abstract A highly sensitive and simple method has been developed for the determination of total arsenic, by continuous hydride generation and atomic fluorescence spectrometry (HGAFS), in refreshing drink samples as colas, teas and fruit juices. Samples were mixed with concentrated HCl and KI to obtain final concentrations of 2 mol l−1 and 1%, respectively. These solutions were aspirated and merged with a reducing NaBH4 3% (m/v) solution, with sample and NaBH4 flow rates of 12.5 and 1.5 ml min−1, respectively. The hydride generated in a 170 cm reaction coil was transported to the detector with an Ar flow of 400 ml min−1. The recovery values of added concentrations, from 0.1 to 0.9 ng ml−1, o…