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showing 10 items of 24643 documents
Bibendum semper vivat !
2012
International audience
Towards Robust Adaptive Least-Squares Parameter Estimation with Internal Feedback
1998
Abstract The new concepts of the ‘covariance matrix normalization’ and the ‘cascade’ structure of the adaptive least-squares estimator are shown to generalize and extend the use of internal information feedback in various robustness/alertness-oriented modifications to the standard ALS estimation algorithm. In the cascade estimation structure it is possible to ‘naturally’ stabilize, rather than maximize, the information matrix so that the covariance windup and blowup are effectively eliminated and the celebrated square root update of the covariance matrix is no longer needed Consequently, a new, ‘single-loop/cascade’ ALS MIMO estimation algorithm, enabling to effectively track both slow and …
Rotational collisional line broadening at high temperatures in the N2 fundamental Q-branch studied with stimulated Raman spectroscopy
1986
Self broadened N 2 Q-branch spectra are measured by high resolution stimulated Raman spectroscopy in the pressure region 0.25-1.9 atm. and in the temperature range 295-1310 K. Non additivity of the Q(J) components due to line overlap arising in the highest pressure range explored is carefully taken into account. Excellent fit of the whole spectra is thus obtained for each pressure with linearly density-dependent line widths. Semi-classical calculations of the line-broadening coefficients lead to consistent values with all the measured ones. These calculations are extended to higher J values and to higher temperatures (up to 2500 K). At last, a simple phenomenological model based on a polyno…
ChemInform Abstract: Assignment of the Absolute Configuration and Total Synthesis of (+)-Caripyrin.
2015
The antifungal secondary metabolite (+)-caripyrin was studied by vibrational circular dichroism spectroscopy. Analysis of the recorded data, with the Boltzmann weighted-average of the spectra calculated at the B3LYP/6-311G(d,p) level of theory for all relevant conformers, unequivocally proved the (R,R)-configuration for the dextrorotatory natural product. Based on this finding, a short enantioselective synthesis of (+)-caripyrin was developed.
On the Influence of Walking People on the Doppler Spectral Characteristics of Indoor Channels
2017
Author´s accepted manuscript © 2017 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works. When modelling mobile radio channels with moving scatterers, it is generally assumed that the angles of departure (AODs), angles of arrival (AOAs), and the speed of the scatterers are time-invariant. However, this assumption is violated as the AODs and AOAs vary with the positions of t…
Complex objects classified by morphological shape analysis and elliptical Fourier descriptors
2005
This chapter deals with the classification of complex objects by morphological shape analysis and elliptical Fourier descriptors. An unsupervised method has been proposed to identify components with specific shapes by a simple edge detector and to classify them via the description of their contours. A particular application has been arranged in order to evaluate the goodness of this approach when discriminating between normal and pathological human megakaryocytes. Alterations in these cells can occur in many pathological processes and in such cases the pattern, size and shape of the cytoplasm and/or of the nucleus are extremely varied.
A New Family of Deformations of Darboux-Pöschl-Teller Potentials
2004
The aim of this Letter is to present a new family of integrable functional-difference deformations of the Schrodinger equation with Darboux–Poschl–Teller potentials. The related potentials are labeled by two integers m and n, and also depend on a deformation parameter h. When h→ 0 the classical Darboux–Poschl–Teller model is recovered.
High Resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) Of O 2 And CO 2
1988
With the help of high spectral quality (linewidth , 6 MHz) injection-locked flashlamp-pumped dye lasers, high resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) has been applied to the study of the Q-branches of 0 2 and CO 2 . The Q-branch linewidths of 02 were obtained from the first nine transitions (J 2 = 1 to 17) recorded at pressures from 0.094 to 1 atm at room temperature. A least squares program was employed to fit calculated spectra to experimental spectra by adjusting different parameters. The collisional broadening coefficients we have obtained are consistent with available Raman data. We have also studied the Q-branch of the fundamental v1 band of CO 2 in the Fermi resonan…
Phonon Deformation Potentials from Raman Measurements on Semiconductor Membranes
1997
Carleson's counterexample and a scale of Lorentz-BMO spaces on the bitorus
2005
We introduce a full scale of Lorentz-BMO spaces BMO L p,q on the bidisk, and show that these spaces do not coincide for different values ofp andq. Our main tool is a detailed analysis of Carleson's construction in [C].