Search results for "Fourier analysis"
showing 10 items of 113 documents
Electron Microscopy of Human Erythrocyte Catalase: New Two-Dimensional Crystal Forms
1993
Abstract Using the mica-spreading "negative staining-carbon film" procedure, human erythrocyte catalase has been shown to create a number of different periodic or crystalline two-dimensional (2-D) arrays which differ in the arrangement of molecules in the repeating units and the lattice type. Digital image processing has been performed with a 2-D array which contains regularly arranged "undulating" rows of molecules and also with a 2-D crystal form, exhibiting pgg (p22 1 2 1 ) symmetry and lattice parameters of a = 12.7 nm, b = 44 nm, and γ= 92°. The data are compared with our previous analysis of a different human erythrocyte catalase 2-D crystal, and the effect of partial-depth negative s…
DOTASQ as a prototype of nature-inspired G-quadruplex ligand
2011
DOTASQ (for DOTA-templated Synthetic G-quartet) is the first prototype of nature-inspired G-quadruplex ligand: its design, founded on a possible intramolecular G-quartet formation, enables it to interact with G-quadruplex DNA via an unprecedented nature-mimicking binding mode, based on the association between two G-quartets, one being native (quadruplex) and the other one artificial (ligand).
Dynamic Effects on Reaction Rates in a Michael Addition Catalyzed by Chalcone Isomerase. Beyond the Frozen Environment Approach
2008
We present a detailed microscopic study of the dynamics of the Michael addition reaction leading from 6'-deoxychalcone to the corresponding flavanone. The reaction dynamics are analyzed for both the uncatalyzed reaction in aqueous solution and the reaction catalyzed by Chalcone Isomerase. By means of rare event simulations of trajectories started at the transition state, we have computed the transmission coefficients, obtaining 0.76 +/- 0.04 and 0.87 +/- 0.03, in water and in the enzyme, respectively. According to these simulations, the Michael addition can be seen as a formation of a new intramolecular carbon-oxygen bond accompanied by a charge transfer essentially taking place from the nu…
Alkali metal mediated resorcarene capsules: An ESI-FTICRMS study on gas-phase structure and cation binding of tetraethyl resorcarene and its per-meth…
2002
AbstractElectrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) with additional ab initio calculations were used to examine the alkali metal cation binding selectivity (i.e., molecular recognition) and host properties of tetraethyl resorcarene (1) and its per-methylated derivative (2). The significance of intramolecular hydrogen bonding for the crown conformation was demonstrated. The presence of intramolecular flip-flop hydrogen bonding in 1 was confirmed both with calculations and in ND3-exchange experiments. All the alkali metal cations formed host–guest complexes by docking inside the cavity of the host. Complexation with the larger cations, esp…
Mass spectrometric studies on small open-chain piperazine-containing ligands and their transition metal complexes
2001
Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry was used to characterize the complexes formed between open-chain piperazine-containing ligands and transition metal salts (Cobalt, Copper, Zinc, and Cadmium as chlorides, nitrates, and acetates). Only single-charged complexes were observed, formed of one ligand (L) and mainly one metal ion (M). Since the net charge of the complexes was one, a counterion (X) was attached to some of the complexes, with formation of [L + M + X]+ complexes, and a proton was lost from others, as in [L − H + M]+ complexes. In most cases the composition of the complexes was more dependent on the ligand than the metal salt. Collisio…
An analytical model to evaluate the radiated power spectrum of a multipactor discharge in a parallel-plate region
2008
This paper is aimed at studying the electromagnetic radiation pattern of a multipactor discharge occurring in a parallel-plate waveguide. The proposed method is based on the Fourier expansion of the multipactor current in terms of time-harmonic currents radiating in the parallel-plate region. Classical radiation theory combined with the frequency domain Green's function of the problem allows the calculation of both the electric and the magnetic radiated fields. A novel analytical formula for the total radiated power of each multipactor harmonic has been derived. This formula is suitable for predicting multipactor with the third-harmonic technique. The proposed formulation has been successfu…
On coefficients of vector-valued Bloch functions
2004
High-speed, low-complexity fir filter using multiplier block reduction and polyphase decomposition
2005
In this paper we discuss the design and implementation of a highspeed FIR filter for both interpolation and decimation of the sample frequency. Several FIR filter structures are compared and various schemes for simplifying the implementation of the multiplications are evaluated. Carry-save adders with carryoverflow correction are used in the implementation. The results in terms of chip area and power consumption are compared using a standard 0.8 pm 3.3 V CMOS process.
Remarks on p-summing multipliers.
2001
Let X and Y be Banach spaces and 1 ≤ p < ∞, a sequence of operators (Tn) from X into Y is called a p-summing multiplier if (Tn(xn)) belongs to lp(Y) whenever (xn) satisfies that ((x*, xn)) belongs to lp for all x* ∈ X*. We present several examples of p-summing multipliers and extend known results for p-summing operators to this setting. We get, using almost summing and Rademacher bounded operators, some sufficient conditions for a sequence to be a p-summing multiplier between spaces with some geometric properties.
Nonlinear analysis of classical phase-locked loops in signal's phase space
2014
Abstract Discovery of undesirable hidden oscillations, which cannot be found by the standard simulation, in phase-locked loop (PLL) showed the importance of consideration of nonlinear models and development of rigorous analytical methods for their analysis. In this paper for various signal waveforms, analytical computation of multiplier/mixer phase-detector characteristics is demonstrated, and nonlinear dynamical model of classical analog PLL is derived. Approaches to the rigorous nonlinear analysis of classical analog PLL are discussed.