Search results for "Fourier transform"
showing 10 items of 1138 documents
Recent progress on the superconducting ion source VENUS.
2012
The 28 GHz Ion Source VENUS (versatile ECR for nuclear science) is back in operation after the superconducting sextupole leads were repaired and a fourth cryocooler was added. VENUS serves as an R&D device to explore the limits of electron cyclotron resonance source performance at 28 GHz with its 10 kW gryotron and optimum magnetic fields and as an ion source to increase the capabilities of the 88-Inch Cyclotron both for nuclear physics research and applications. The development and testing of ovens and sputtering techniques cover a wide range of applications. Recent experiments on bismuth demonstrated stable operation at 300 eμA of Bi31+, which is in the intensity range of interest for hig…
Weathering of low-density polyethylene grafted with itaconic acid in laboratory tests
2011
Polyethylene grafted with itaconic acid was subjected to weathering under laboratory accelerated conditions. The course of the photo-oxidative degradation process of that material was studied by FTIR spectroscopy both through quantitative measurements of changes in absorbance values at selected wave numbers and through measurements of surface area values for absorption bands which were separated by means of deconvolution. The use of both those procedures of quantitative determinations resulted in a general conclusion that the oxidation process was initiated from the very first moment of irradiation, and it produced ketones, acids, esters (intramolecular and of acetate type), peracids, peres…
MbCo in Saccharide Solid Amorphous Systems: A Combined FTIR and SAXS Study
2011
Saccharides, and in particular trehalose, are known for their efficiency in protecting biostructures against environmental stress [1], although the preservation mechanism is still debated. Experiments and simulations [2,3] on carboxy-myoglobin (MbCO) showed that the protein dynamics is highly inhibited in dry trehalose matrices, the inhibition being dependent on the water content. In these conditions, a mutual protein-matrix structural and dynamic influence is observed.Here we report a combined FTIR and SAXS study on MbCO embedded in dry amorphous matrices of trehalose and sucrose. FTIR measurements were performed at different protein/sugar ratios, focussing on the stretching band of the bo…
Detecting clusters in spatially correlated waveforms
2017
Seismic networks often record signals characterized by similar shapes that provide important information according to their geographic positions. We propose an approach to identify homogeneous clusters of seismic waves, combining analysis of waveforms with metadata and spectrogram information. In waveforms clustering, cross-correlation measures between signals may presents some limitations, so we refer to more recent contributes relating data-depth based clustering analysis. The mechanism for alignment is also an important topic of the analysis: warping (or aligning) procedures identify nuisance effects in phase variation, that, if ignored, may result in a possible loss of information and t…
Spectroscopic studies of semiconducting single-walled carbon nanotubes
2010
The unique nature of optical properties of single-walled carbon nanotubes (SWCNT), together with their promising potential applications, have created enormous interest towards the photophysics of SWCNT. Many aspects of carbon nanotubes originate from the electronic structure of carbon honeycomb lattice and one-dimensionality. SWCNTs exist in various chiral structures and diameters, which the optical and electrical properties are dependent on. It has been discovered that SWCNT excited states are excitonic with strong Coulomb interaction between the electron and the hole. However, many features of excitons are not yet well defined, such as absorption cross-sections, fluorescence quantum yield…
Copper-hydride nanoclusters with enhanced stability by N-heterocyclic carbenes
2021
AbstractCopper-hydrides have been intensively studied for a long time due to their utilization in a variety of technologically important chemical transformations. Nevertheless, poor stability of the species severely hinders its isolation, storage and operation, which is worse for nano-sized ones. We report here an unprecedented strategy to access to ultrastable copper-hydride nanoclusters (NCs), namely, using bidentate N-heterocyclic carbenes as stabilizing ligands in addition to thiolates. In this work, a simple synthetic protocol was developed to synthesize the first large copper-hydride nanoclusters (NCs) stabilized by N-heterocyclic carbenes (NHCs). The NC, with the formula of Cu31(RS)2…
ChemInform Abstract: Cyclic SiS2: A New Perspective on the Walsh Rules.
2012
Cyclic SiS2 is detected in the low-current dc discharge products of a mixture of SiH4 and H2S by Fourier transform microwave spectroscopy.
The Radon-Wigner Transform and Its Application to First-order Optical Systems
2009
The Radon-Wigner transform is presented as a tool for the description of 1st-order optical systems. The input/output relationships for this phase-space representation are obtained and their application in analysis and design tasks is pointed out.
Complex objects classified by morphological shape analysis and elliptical Fourier descriptors
2005
This chapter deals with the classification of complex objects by morphological shape analysis and elliptical Fourier descriptors. An unsupervised method has been proposed to identify components with specific shapes by a simple edge detector and to classify them via the description of their contours. A particular application has been arranged in order to evaluate the goodness of this approach when discriminating between normal and pathological human megakaryocytes. Alterations in these cells can occur in many pathological processes and in such cases the pattern, size and shape of the cytoplasm and/or of the nucleus are extremely varied.
An Improved Method for Estimating the Time ACF of a Sum of Complex Plane Waves
2010
Time averaging is a well-known technique for evaluating the temporal autocorrelation function (ACF) from a sample function of a stochastic process. For stochastic processes that can be modelled as a sum of plane waves, it is shown that the ACF obtained by time averaging can be expressed as a sum of auto-terms (ATs) and cross-terms (CTs). The ATs result from the autocorrelation of the individual plane waves, while the CTs are due to the cross-correlation between different plane wave components. The CTs cause an estimation error of the ACF. This estimation error increases as the observation time decreases. For the practically important case that the observation time interval is limited, we pr…