Search results for "Fuel Cell"
showing 10 items of 260 documents
Electrode–Electrolyte Compatibility in Solid-Oxide Fuel Cells: Investigation of the LSM–LNC Interface with X-ray Microspectroscopy
2015
Ca:LaNbO4 (LNC) constitutes the last real breakthrough in high-temperature proton conductors, with better chemical and mechanical stability with respect to cerate and zirconate perovskites. However, the low amount of bivalent dopant that can be hosted in the LaNbO4 matrix poses a limit to the proton concentration in the electrolyte. Using synchrotron X-ray microspectroscopy, we investigated the compatibility of annealed LNC/LSM electrolyte/cathode bilayers for proton-conducting SOFCs. The element maps are complemented by microEXAFS and microXANES, giving information on the fate of different cations after diffusion. The X-ray microspectroscopy approach described here is applied for the first…
Étude par microscopie électronique et spectroscopie de films minces catalytiques pour micro piles à combustibles
2016
Předložená dizertační práce se zabývá studiem nových katalyzátorů na bázi kov-oxid vhodných pro použití v palivových článcích na straně anody. Platinou dopovaný oxid ceru připravený magnetronovým naprašováním ve formě tenkých vrstev na uhlíkových mezivrstvách nesených křemíkovým substrátem byl zkoumán prostřednictvím mikroskopických a spektroskopických metod. Vliv složení uhlíkového nosiče (a-C a CNx filmy), depozičního času CeOx vrstvy a dalších depozičních parametrů, např. depoziční rychlosti, složení pracovní atmosféry a Pt koncentrace na morfologii Pt-CeOx vrstev byl studován převážně pomocí transmisní elektronové mikroskopie (TEM). Získané výsledky ukazují, že vhodnou kombinací depozič…
Improvements in H2/O2 thin film fuel cell working with Porous Anodic Alumina-supported electrolytes
2009
Review of gas diffusion cathodes for alkaline fuel cells
2009
Abstract This paper gives a technical background to alkaline fuel cells (AFCs), introducing the advantages and drawbacks of the technology. AFCs offer the potential for low cost, mass producible fuel cells, without the dependency on platinum based catalysts and (currently) expensive membrane electrolytes. The AFC uses relatively low cost electrolytes based on aqueous bases such as potassium hydroxide. The inherent CO 2 sensitivity of the electrolyte can be addressed by filtering out the CO 2 from the air intake using a simple scrubber and periodically replacing the liquid electrolyte. A review of the state-of-the-art in gas diffusion cathode development is given. The overall cell performanc…
High Accuracy Modelling of Hybrid Power Supplies
2011
This chapter proposes a modelling approach based on the PSIM/Simulink co-simulation toolbox for hybrid power supplies, featuring high accuracy. Hybrid source performances are fully tested during behavioural simulations. The importance of high-accuracy modelling is investigated and modelling guidelines for both power sources and load are given for further applications. The Simulink model is analyzed and the efficiency of the proposed approach is verified by the comparison between simulation and experimental results. In the last few years, hybrid power supplies are investigated for a wide variety of application areas: two primary sources are coupled to take advantages of both, overcoming thei…
Fuel cells for household appliances: Experimental test of power management algorithms
2013
In this paper, fuel cell - based hybrid power supplies for household appliances are addressed. The profile of residential power consumption is evaluated during working, non-working days in both summer and winter periods. The worst-case load power demand is therefore highlighted. A 5kW Nuvera PowerFlow proton exchange membrane fuel cell for household appliances is tested. On the basis of the characterization of the fuel cell stack under test, stand-alone and fuel cell - battery active hybrid power supply architectures are both considered. Experimental validation of three power management algorithms is proposed in terms of hydrogen consumption, cost and energy saving. Power management algorit…
A review of fuel cell based hybrid power supply architectures and algorithms for household appliances
2014
Abstract Nowadays, renewable power system solutions are widely investigated for residential applications. Grid-connected systems including energy storage elements are designed. Advanced research is actually focused on improving the reliability and energy density of renewable systems reducing the whole utility cost. Source and load modeling, power architectures and algorithms are only a few topics to be addressed. Designers have to carefully deal with each subtopic prior to design efficient renewable energy systems. In the literature, each topic is separately discussed and the lack of a unique reference guide is clear to power electronics designers. In this paper, each design step including …
A Deep Insight into Different Acidic Additives as Doping Agents for Enhancing Proton Conductivity on Polybenzimidazole Membranes
2020
[EN] The use of phosphoric acid doped polybenzimidazole (PBI) membranes for fuel cell applications has been extensively studied in the past decades. In this article, we present a systematic study of the physicochemical properties and proton conductivity of PBI membranes doped with the commonly used phosphoric acid at different concentrations (0.1, 1, and 14 M), and with other alternative acids such as phytic acid (0.075 M) and phosphotungstic acid (HPW, 0.1 M). The use of these three acids was reflected in the formation of channels in the polymeric network as observed by cross-section SEM images. The acid doping enhanced proton conductivity of PBI membranes and, after doping, these conducti…
Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Significantly Enhanced Proton Conductivity unde…
2018
The preparation and characterization of composite polybenzimidazole (PBI) membranes containing zeolitic imidazolate framework 8 (ZIF-8) and zeolitic imidazolate framework 67 (ZIF-67) is reported. The phosphoric acid doped composite membranes display proton conductivity values that increase with increasing temperatures, maintaining their conductivity under anhydrous conditions. The addition of ZIF to the polymeric matrix enhances proton transport relative to the values observed for PBI and ZIFs alone. For example, the proton conductivity of PBI@ZIF-8 reaches 3.1 10&minus