Search results for "Fuel Technology"

Interference of EDTA in the treatment of metal plating wastewater by biosorption

2012

Double cross-linked polyetheretherketone proton exchange membrane for fuel cell

2012

Abstract The proton exchange membrane based on polyetheretherketone was prepared via two steps of cross-linking. The properties of the double cross-linked membrane (water uptake, proton conductivity, methanol permeability and thermal stability) have been investigated for fuel cell applications. The prepared membrane exhibited relatively high proton conductivity, 3.2 × 10 −2  S cm −1 at room temperature and 5.8 × 10 −2  S cm −1 at 80 °C. The second cross-linking significantly decreased the water uptake of the membrane. The performance of direct methanol fuel cell was slightly improved as compared to Nafion ® 117 due to its low methanol permeability. The results indicated that the double cros…

Catalytic performance of CoAlZn and NiAlZn mixed oxides in hydrogen production by bio-ethanol partial oxidation

2013

CoAlZn and NiAlZn mixed oxides were prepared by sol-gel method and tested in partial oxidation of bio-ethanol (POE). At lower temperatures, CoAlZn showed higher ethanol conversion and higher selectivity to H2 and CO than NiAlZn. At higher temperatures, ethanol conversion on both catalysts reached 100%, while selectivity (S) to H2 and CO became higher on NiAlZn. At 750 C, NiAlZn showed S(H2) of 95%, S(CO) of 90%, while for CoAlZn these values were 90% and 83% respectively. Both catalysts were resistant to coking, but the amount of carbon deposits was still lower on NiAlZn. During 50 h on-stream, ethanol conversion and selectivity to H2 and CO on NiAlZn remained unchanged demonstrating stable…

Riga experience in spallation neutron target related investigations

2002

Abstract Mercury has awakened interest as a potential material for spallation neutron source targets. Institute of Physics, University of Latvia has a 30 years experience of investigations in mercury. As specially projected building includes a 350 m2 experimental hall. The largest loop, containing 5×103 kg of Hg, can be transferred for solution of different tasks. As the first example results are presented when integral developed pressure and local (distribution of void fraction) characteristics of a two-phase mercury/gas riser were investigated. Second example – investigation of velocity fields and heat transfer conditions close to the beam entrance window in the SINQ target thermohydrauli…

Methanol and proton transport through chitosan-phosphotungstic acid membranes for direct methanol fuel cell

2020

Composite chitosan-phosphotungstic acid membranes were synthesized by ionotropic gelation. Their liquid uptake is higher for thin membranes (23 ± 2 μm), while it is lower (~70%) for thicker membranes (50-70 μm). Polarization curves recorded using single module fuel cell at 70°C allowed to estimate a peak power density of 60 mW cm−2 by using 1 M as methanol and low Pt and Pt/Ru loadings (0.5 and 3 mg cm−2) at the cathode and at the anode, respectively. Electrochemical impedance spectroscopy was used to estimate the membrane conductivity and to model the electrochemical behavior of methanol electrooxidation inside the fuel cell revealing a two-step mechanism mainly responsible of overall kine…

Regulating feeding and increasing methane yield from co-digestion of C5 molasses and cattle manure

2014

Abstract The paper investigated the mesophilic (∼35 °C) and thermophilic (∼50 °C) co-digestion of cattle manure and C5 molasses for a variable organic loading rate (OLR). The small scale continuous reactor experiment revealed that thermophilic treatment yielded a maximum 313 ± 16 L/kg VS methane for the feeding ranged between 50% and 70% C5 (v/v). Mesophilic co-digestion, on the other hand, produced maximum 232 ± 32 L/kg VS methane when feeding was ranged between 31% and 47% C5 (v/v). The feeding strategy of this study was sophistically adjusted owing to the unstable volatile fatty acids (VFA) pattern, developed at different stages of the experiment. Attainable molasses feeding for both the…

Cross-linked PEEK-WC proton exchange membrane for fuel cell

2009

Abstract The low cost proton exchange membrane was prepared by cross-linking water soluble sulfonated-sulfinated poly(oxa- p -phenylene-3,3-phthalido- p -phenylene-oxa- p -phenylene-oxy-phenylene) (SsPEEK-WC). The prepared cross-linked membrane became insoluble in water, and exhibited high proton conductivity, 2.9 × 10 −2  S/cm at room temperature. The proton conductivity was comparable with that of Nafion ® 117 membrane (6.2 × 10 −2  S/cm). The methanol permeability of the cross-linked membrane was 1.6 × 10 −7  cm 2 /s, much lower than that of Nafion ® 117 membrane.

Ethylbenzene removal under mesophilic conditions in a biofilter withMacadamia ternifolianutshells as a carrier material

2012

BACKGROUND Biofilters are suitable to treat industrial emissions polluted with volatile organic compounds (VOCs), responsible for photochemical smog and depletion of the ozone layer. This study analyzes the performance of a biofilter with Macadamia ternifolia nutshells as a carrier material treating air streams contaminated with ethylbenzene under mesophilic conditions with continuous feeding. RESULTS The biofilter was operated continuously for 5 months applying several inlet loads (IL), empty bed residence times (EBRT) and temperatures. At a temperature of 303 ± 1 K removal efficiencies (RE) higher than 90% were obtained for ILs lower than 85.6 g m−3 h−1 and 70.6 g m−3 h−1 at an EBRT of 15…

Biofiltration of toluene in the absence and the presence of ethyl acetate under continuous and intermittent loading

2008

BACKGROUND: Two peat biofilters were used for the removal of toluene from air for one year. One biofilter was fed with pure toluene and the other received 1:1 (by weight) ethyl acetate:toluene mixture. RESULTS: The biofilters were operated under continuous loading: the toluene inlet load (IL) at which 80% removal occurred was 116 g m−3 h−1 at 57 s gas residence time. Maximum elimination capacity of 360 g m−3 h−1 was obtained at an IL of 745 g m−3 h−1. The elimination of toluene was inhibited by the presence of ethyl acetate. Intermittent loading, with pollutants supplied for 16 h/day, 5 days/week, did not significantly affect the removal efficiency (RE). Biomass was fully activated in 2 h a…

Adsorption of Heavy Metals from Aqueous Solutions onto Activated Carbon in Single Cu and Ni Systems and in Binary Cu-Ni, Cu-Cd and Cu-Zn Systems

1997

Single copper and nickel adsorption from aqueous solutions onto a granular activated carbon is reported. Metal removals increase on raising pH and temperature, and decrease on raising the initial metal concentration at constant carbon dose. The adsorption processes are modelled using the surface complex formation (SCF) Triple Layer Model (TLM) with an overall surface bidentate species. A dependence of the SCF constant on pH, initial molar metal/carbon ratio and temperature is observed, and a correlation for log Kads is determined. The SCF model successfully predicts copper and nickel removals in single metal solutions. Adsorption in the binary metal systems copper–nickel, copper–cadmium and…