Search results for "Furnace"
showing 10 items of 44 documents
Alkali-Activated Adsorbents from Slags: Column Adsorption and Regeneration Study for Nickel(II) Removal
2021
Alkali-activated adsorbents were synthesized by mixing three different slags from the steel industry: blast furnace slag (BFS), ladle slag (LS), and Lintz–Donawitz converter slag (LD). These powdered slag-based geopolymers (GP) were used to remove nickel(II) from aqueous solutions in fixed-bed column studies. The experiments were conducted in pH 6 using a phosphate buffer with initial nickel(II) concentration of 50 mg/L. Samples were taken at time intervals of between 5 and 90 min. Three adsorption–desorption cycles were implemented with a flow rate of 5 mL/min. The geopolymers were characterized by Fourier-Transform Infrared Spectroscopy (FTIR), X-ray powder diffraction (XRD), Field Emissi…
Tailoring the microstructure and mechanical properties of Ti–Al alloy using a novel electromagnetic stirring method
2006
The effect of melt convection during the solidification of Ti45Al55 alloys was investigated in terms of microstructure evolution and the resulting mechanical properties. The samples were subjected to conventional induction melting as well as enhanced melt stirring by an external magnetic field using a specially designed floating zone arrangement. The stirred samples showed a significant improvement of plastic deformability. A strong change in the morphology from dendritic to spherical and an increased properitectic phase fraction were observed after stirring.
Low melting Metal Catalysed Growth of Tin Disulfide Nanotubes
2009
AbstractWe report here the synthesis of tin disulfide nanotubes by a vapour liquid solid growth using bismuth, a low melting metal, as a catalyst. The reaction was carried out in a single step process by heating SnS2 and bismuth in a horizontal tube furnace at 800oC. TEM analysis allowed proposing a plausible mechanism for the formation of SnS2 nanotubes. Pure material could be obtained by optimizing the reaction based on a product analysis using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) combined with energy dispersive X-ray spectroscopy (EDX).
Improvement of the butyl methacrylate-paraffin embedment.
1983
The excellent butyl methacrylate-paraffin method as an embedment for light microscopy has been technically improved. More uniform and reproducible polymerization has been obtained by using a vacuum oven to degas the polymerizing mixture and to replace the air with nitrogen at 650 Torr. The amount of benzoyl peroxide required must be determined for each batch of butyl methacrylate. A teflon lined, reusable metal mold and a method of one-step blocking of tissues in preparation for sectioning are also described.
Influence of resin viscosity and vacuum level on mechanical performance of sandwich structures manufactured by vacuum bagging
2010
The choice of process parameters is critical in optimizing the mechanical properties of sandwich structures produced using the vacuum bagging technique. The aim of this paper is to analyze how the viscosity of the resin/curing agent system and the vacuum level influence the morphology and the mechanical behavior of sandwich beams with composite faces (epoxy resin and glass fiber fabric named COMBI 900) and a PVC foam core. Four different sandwich structures were produced by varying the viscosity of the epoxy resin/curing agent at constant maximum vacuum pressure. Three further structures were manufactured by varying the strength of the vacuum with the resin viscosity maintained constant at …
Nanostructuring thin Au films on transparent conductive oxide substrates
2013
Fabrication processes of Au nanostructures on indium-tin-oxide (ITO) surface by simple, versatile, and low-cost bottom-up methodologies are investigated in this work. A first methodology exploits the patterning effects induced by nanosecond laser irradiations on thin Au films deposited on ITO surface. We show that after the laser irradiations, the Au film break-up into nanoclusters whose mean size and surface density are tunable by the laser fluence. A second methodology exploits, instead, the patterning effects of standard furnace thermal processes on the Au film deposited on the ITO. We observe, in this case, a peculiar shape evolution from pre-formed nanoclusters during the Au deposition…
Synthesis of Fullerene- and Nanotube-Like SnS2 Nanoparticles and Sn/S/Carbon Nanocomposites
2009
SnS2 nested fullerene-type (IF) nanoparticles, nanotubes, and SnS2/C hybrid nanostructures were obtained by vapor transport starting from elemental tin and CS2. The reaction was carried out in a single-step process by heating elemental tin metal powder in a horizontal tube furnace at 800−1000 °C. TEM analysis allowed proposing a plausible mechanism for the formation of fullerene-like particles of SnS2 as well as tubes and scrolls from nanosheets of SnS2. Pure material could be obtained by optimizing the reaction based on a product analysis using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) combined with energy-dispersive X-ray spectroscopy (EDX…
Luminescence Properties of ZnO Nanocrystals and Ceramics
2008
The luminescence excitation spectra, luminescence spectra and the nanosecond-scale decay kinetics were studied. The ZnO and ZnO:Al nanopowders were prepared by vaporization-condensation in a solar furnace using different raw powders: commercial, hydrothermal and those obtained by plasma synthesis. Exciton-phonon as well as exciton-exciton interaction processes in nanopowders, a bulk crystal and ZnO ceramics were studied and compared. The fast decay and low afterglow intensity of ZnO nanopowders and ceramics support these materials for scintillators.
Solidification of ion exchange resins saturated with Na+ ions: Comparison of matrices based on Portland and blast furnace slag cement
2017
International audience; Ion exchange resins (IERs) are widely used by the nuclear industry to decontaminate radioactive effluents. After use, they are usually stabilized and solidified by encapsulation in cementitious materials. However, for certain combinations of cement and resins, the solidified waste forms can exhibit strong expansion, possibly leading to cracking of the matrix. In this work, the behaviour of cationic resins in the Na$^+$ form is investigated in Portland cement (CEM I) or blast furnace slag cement (CEM III/C) pastes at early age in order to have a better understanding of the swelling process. The results show that during the hydration of the CEM I paste, the resins exhi…
Synthesis and processing of nanocrystalline tungsten carbide: Towards cemented carbides with optimal mechanical properties
2011
Abstract Nanocrystalline tungsten carbide has been obtained by reduction/carburization at low temperature from precursors obtained by freeze-drying of aqueous solutions. Nanocrystalline WC powders with a adequate content of carbon were mixed with submicrometric Cobalt powder (12 wt.%), obtained by same synthesis method, and sintered in vacuum furnace. The cemented carbides fabricated from experimental powders were compared with both commercial ultrafine and nanocrystalline WC-12Co mixtures consolidated by the same route. The synthesised powders were characterized by X-ray powder diffraction, elemental analysis and scanning and high resolution transmission electron microscopy. On the other h…