Search results for "GAL"
showing 10 items of 9260 documents
Indium Selenide Solar Cells
1981
Indium selenide photovoltaic devices are described. Transport and photovoltaic properties are discussed. Efficiencies of 6% are reported and ways of improvement are proposed.
X-ray absorption near-edge structure of GaN with high Mn concentration grown on SiC.
2009
By means of x-ray absorption near-edge structure (XANES) several Ga(1-x)Mn(x)N (0.03x0.09) layers have been analyzed. The Mn-doped GaN samples consisted of different epilayers grown by molecular beam epitaxy on [0001] SiC substrates. The low mismatch between GaN and SiC allows for a good quality and homogeneity of the material. The measurements were performed in fluorescence mode around both the Ga and Mn K edges. All samples studied present a similar Mn ionization state, very close to 2+, and tetrahedral coordination. In order to interpret the near-edge structure, we have performed ab initio calculations using the full potential linear augmented plane wave method as implemented in the Wien…
Bisfunctionalized Janus Molecules
2004
[reaction: see text] Bisfunctionalized dendritic multiester molecules were synthesized by combined protection-deprotection and divergent-convergent-divergent sequences in high yields leading to dendritic molecules that combine two functionally different surfaces, polar aliphatic arborol and nonpolar gallate ether moieties, resulting in a two-faced Janus molecule.
Comprehensive valorisation of technically relevant organosolv lignins via anodic oxidation
2021
Lignin represents the largest renewable feedstock of aromatic moieties in nature. However, its valorisation towards organic chemicals poses a challenging task. We herein report the selective electrochemical depolymerisation of several technically relevant organosolv lignins to aromatic fine chemicals with a simple two-electrode arrangement using caustic soda as electrolyte. Vanillin, syringaldehyde, the corresponding ketones and guaiacol were obtained with a combined maximum of 7.8 wt% isolated yield. Deeper insight in the process was provided by FT-IR, HSQC NMR and 31P NMR analyses of the lignins.
Temperature-Induced Structural Transitions in the Gallium-Based MIL-53 Metal–Organic Framework
2013
We report a structural and thermodynamic investigation of the phase behavior of Ga(OH,F)-MIL-53, a gallium-based metal–organic framework (MOF) having the MIL-53 topology containing 0.7 wt % fluorine bonded to the metal. Despite some small structural differences, especially for the hydrated form, the overall physical chemistry behavior of Ga(OH,F)-MIL-53 is very similar to standard fluorine free Ga-MIL-53 material. A combination of in situ X-ray diffraction, in situ Fourier transform infrared spectroscopy, differential scanning calorimetry, and heat capacity measurements allowed us to establish that Ga(OH,F)-MIL-53 under vacuum (i.e., the empty material) exhibits two stable phases: a nonporo…
Maturation of a Key Resource – The Germanium-68/Gallium-68 Generator: Development and New Insights
2011
(68)Ge/(68)Ga radionuclide generators have been investigated for almost fifty years, since the cyclotron-independent availability of positron emitting (68)Ga via the (68)Ge/(68)Ga system had always attracted researches working in basic nuclear chemistry as well as radiopharmaceutical chemistry. However, it took decades and generations of research (and researchers) to finally reach a level of (68)Ge/(68)Ga radionuclide generator designs adequate to the modern requirements of radiometal labelling chemistry. Nevertheless, most of the existing commercial generator systems address aspects of (68)Ge breakthrough and safe synthesis of (68)Ga radiopharmaceuticals by adopting eluate post-processing …
SUSPECTED CHILD ABUSE: UNUSUAL DEATH IN WESTERN COUNTRY. SUICIDE OR HOMICIDE?
2012
This case report describes a particular case of carbonized corpse, found in his burnt-out car in an isolated Palermo’s west suburban zone. The goal of this case report is to describe the shame and the social stigma related with suspicious of pedophilia and how it led a man to suicide by fire, considering that is an unusual way to die in western countries
Volonté de ne pas engendrer et modernité
2018
International audience
Effect of nanoaquacitrates on physiological parameters of Fodder Galega infected with phytoplasma
2018
The laboratory experiments have been found that so aking seeds Galega orientalis L. (Fodder galega) in nanoaquacitrates solutions of Mn (10 and 20 mg/dm 3), Mo (4 mg/dm3) and Mg (2 and 4 mg/dm3), has been lead to germination energy rise, while Mn( 10 and 20 mg/dm3) and Mo (4 mg/dm3) concentrations has been influenced germinating ability. At the same time, the soaking seeds in solution of nanoaquacitrates Mn (20 mg/dm3) had the biggest stimulatory effect on the accumulation 7 daily sprouts mass (on 18%). It has been shown that s oaking seeds in nanoparticles Mn and Mo solutions leads to the increase of catalase activities (especially under the influence of manganese) and peroxidase activitie…
Phenazine antibiotics produced by fluorescent pseudomonads contribute to natural soil suppressiveness to Fusarium wilt
2009
Natural disease-suppressive soils provide an untapped resource for the discovery of novel beneficial microorganisms and traits. For most suppressive soils, however, the consortia of microorganisms and mechanisms involved in pathogen control are unknown. To date, soil suppressiveness to Fusarium wilt disease has been ascribed to carbon and iron competition between pathogenic Fusarium oxysporum and resident non-pathogenic F. oxysporum and fluorescent pseudomonads. In this study, the role of bacterial antibiosis in Fusarium wilt suppressiveness was assessed by comparing the densities, diversity and activity of fluorescent Pseudomonas species producing 2,4-diacetylphloroglucinol (DAPG) (phlD+) …