6533b82efe1ef96bd1293c9a

RESEARCH PRODUCT

Bisfunctionalized Janus Molecules

S. NummelinKari RissanenJarmo Ropponen

subject

chemistry.chemical_compoundchemistryStereochemistryOrganic ChemistryMoleculeEtherJanusGallatePhysical and Theoretical ChemistryBiochemistryCombinatorial chemistry

description

[reaction: see text] Bisfunctionalized dendritic multiester molecules were synthesized by combined protection-deprotection and divergent-convergent-divergent sequences in high yields leading to dendritic molecules that combine two functionally different surfaces, polar aliphatic arborol and nonpolar gallate ether moieties, resulting in a two-faced Janus molecule.

https://doi.org/10.1021/ol049555f