Search results for "General Energy"
showing 10 items of 644 documents
Kinetic and Mechanistic Aspects of a Poly(o-Toluidine)-Modified Gold Electrode. 2. Alternating Current Electrogravimetry Study in H2SO4 Solutions
2012
International audience; Electrodeposited poly(o-toluidine) (POT) on gold electrodes was investigated in 0.5 M H2SO4 aqueous solutions using alternating current electrogravimetry (simultaneous electrochemical impedance and mass transfer functions). The kinetic aspects of the three different redox transitions proposed for this polymer (leucoemeraldine-polaron transition, polaron-bipolaron transition, and bipolaron-pernigraniline transition) and the species involved, cation (hydrated proton), anion (bisulfate ion), and free solvent (water), are studied by means of the mass impedance technique. An ionic transfer model is proposed with coherent results where anion transfer is the fastest process…
Pricing of electricity futures based on locational price differences : The case of Finland
2018
We find that the pricing of Finnish electricity market futures has been inefficient during the latest 10 years, when the trading volumes of Electricity Price Area Differentials (EPADs) have more than doubled. Even though the calculated futures premium on EPADs is related to some risk measures and the variables capturing the demand and supply conditions in the spot electricity markets, there has been a significant positive excess futures premium in the Finnish market, and financial market participants should have been able to utilize this also in economic terms. This finding is new and relevant for the participants of the Nordic electricity markets also in the future, because both the specul…
EUA and sCER Phase II Price Drivers: Unveiling the reasons for the existence of the EUA-sCER spread
2011
International audience; This article studies the price relationships between EU emissions allowances (EUAs) - valid under the EU Emissions Trading Scheme (EU ETS) - and secondary Certified Emissions Reductions (sCERs)--established from primary CERs generated through the Kyoto Protocol's Clean Development Mechanism (CDM). Given the price differences between EUAs and sCERs, financial and industrial operators may benefit from arbitrage strategies by buying sCERs and selling EUAs (i.e. selling the EUA-sCER spread) to cover their compliance position as industrial operators are allowed to use sCERs towards compliance with their emissions cap within the European system up to 13.4%. Our central res…
Artificial neural network decision support tool for assessment of the energy performance and the refurbishment actions for the non-residential buildi…
2017
The public buildings sector represents one of the most intensive items of EU energy consumption; the application of retrofit solutions in existing buildings is a crucial way to reduce its impact. To facilitate the knowledge of the energy performance of existing non-residential buildings and the choice of the more adequate actions, Public Administrations (PA) should have the availability of proper tools. Within the Italian project "POI 2007-13", a database and a decision support tool, for easy use, even to a non-technical user, have been developed. A large set of data, obtained from the energy audits of 151 existing public buildings located in four regions of South Italy have been analysed, …
On the impact of safety requirements, energy prices and investment costs in street lighting refurbishment design
2018
Abstract Street lighting is an indispensable feature for the night landscape of cities. It is important for road safety, users visual comfort, crime prevention and to augment the perceived personal safety. Realize and maintain an adequate street lighting service is very expensive for municipalities with significant impact on their budgets. For this reason, special attention should be paid to the design of new street lighting systems and to the refurbishment of existing ones, since many of them are inadequate. In light of this it is very important to implement street lighting designs that fulfil lighting requirements avoiding energy waste and light pollution and, at the same time, result eco…
O2 Diffusion in Amorphous SiO2 Nanoparticles Probed by Outgassing
2012
An experimental study of the O2 diffusion process in nanoparticles of amorphous SiO2 in the temperature range from 98 to 157 °C was carried out by Raman and photoluminescence techniques. We studied O2 diffusion in high purity silica nanoparticles with a mean diameter of 14, 20, and 40 nm detecting the outgassing of molecules trapped during the manufacturing. The kinetics of diffusion is well described for all the investigated nanoparticles by the Fick’s equation proving its applicability to nanoscale systems. The diffusion coefficient features an Arrhenius law temperature dependence in the explored temperature range, and the diffusion coefficient values are in good agreement with extrapolat…
Quasi-elastic Neutron Scattering Investigation of the Hydrogen Surface Self-Diffusion on Polymer Electrolyte Membrane Fuel Cell Catalyst Support
2008
International audience; Quasi-elastic neutron scattering (QENS) measurements have been performed to investigate the surface selfdiffusion of hydrogen molecules. A monolayer of molecular hydrogen was adsorbed on a carbon material commonly used in polymer electrolyte membrane fuel cells, called XC-72. QENS spectra were recorded at the time-of-flight spectrometer IN5 at Institut Laue-Langevin (ILL) in Grenoble at 40, 50, 60, and 70 K. By using the Chudley & Elliott model for jump diffusion, we found the diffusion coefficient at each temperature. The logarithm of the diffusion coefficient was plotted versus the inverse of the temperature to give the coefficient in the Arrhenius equation. From t…
Application of optimized artificial intelligence algorithm to evaluate the heating energy demand of non-residential buildings at European level
2019
Abstract A reliable preliminary forecast of heating energy demand of a building by using a detailed dynamic simulation software typically requires an in-depth knowledge of the thermal balance, several input data and a very skilled user. The authors will describe how to use Artificial Neural Networks to predict the demand for thermal energy linked to the winter climatization of non-residential buildings. To train the neural network it was necessary to develop an accurate energy database that represents the basis of the training of a specific Artificial Neural Networks. Data came from detailed dynamic simulations performed in the TRNSYS environment. The models were built according to the stan…
Electron Transfer from Organic Aminophenyl Acid Sensitizers to Titanium Dioxide Nanoparticle Films
2009
Electron transfer from three conjugated amino-phenyl acid dyes to titanium and aluminum oxide nanocrystalline films was studied by using transient absorption spectroscopy with sub 20 fs time-resolution over the visible spectral region. All the dyes attached to TiO2 showed long-lived ground state bleach signals indicative of formation of new species. Global analysis of the transient kinetics of the dyes on TiO2 revealed stimulated emission decays of about 40 fs and less than 300 fs assigned to electron injection. The same dyes on Al2O3 substrates displayed long stimulated emission decays (ns) suggesting that electron transfer is blocked in this high band gap semiconductor. For two of the dye…
GEOCHEMICAL CONSTRAINTS ON THE ORIGIN OF CALCALKALINE AND ALKALINE MAGMAS OF THE EASTERN TRANS-MEXICAN VOLCANIC BELT
1988
Se presentan datos de elementos mayores, elementos trazas y tierras raras de rocas calco-alcalinas y alcalinas de la parte este del cinturón volcánico transmexicano (TMVB), así como conclusiones acerca de su origen y de su significado tectónico. Las andesitas y dacitas muestran características geoquímicas que descartan su derivación de los magmas basálticos por el proceso de cristalización fraccionada. Las distribuciones gráficas de los elementos LIL y HFS son interpretadas como indicadoras de la formación de magmas en el manto superior modificado por procesos de subducción. Las riolitas se interpretan como resultado de la fusión parcial de la corteza continental.